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The report was prepared to document the recent finding that the Ti-6Al-4V alloy is susceptible to stress-corrosion cracking in some grades of nitrogen tetroxide, and to describe briefly the work that is now going on to define the critical parameters involved in this phenomenon. Previously titanium and its alloys were believed to be compatible with nitrogen tetroxide. In the absence of stress, titanium shows almost no corrosion in liquid or gaseous nitrogen tetroxide in tests to 165 deg F. Although titanium is impact sensitive at high impact levels, no propagation of the reaction is reported.
Factors affecting stress-corrosion cracking of Ti-6Al-4V alloy in methanol.
The Science, Technology and Application of Titanium contains the proceedings of an International Conference organized by the Institute of Metals, The Metallurgical Society of AIME, and the American Society for Metals in association with the Japan Institute of Metals and the Academy of Sciences of the USSR and held at the Royal Festival Hall in London, on May 21-24, 1968. The papers explore scientific and technological developments as well as applications of titanium and cover topics ranging from processing of titanium to its chemical and environmental behavior, physics, thermodynamics, and kinetics. Deformation and fracture, phase transformations and heat treatment, and alloying are also discussed. This book is comprised of 114 chapters and begins with an overview of the titanium industry in Europe and the United States. The reader is then introduced to primary and secondary fabrication of titanium; corrosion and oxidation; physical properties of titanium alloys; interaction of titanium with elements of the periodic system; and elastic interactions between dislocations and twin and grain boundaries in titanium. The crystallography of deformation twinning in titanium is also examined, along with superplasticity and transformation plasticity in titanium. The remaining chapters focus on interstitial strengthening of titanium alloys; mechanism of martensitic transformation in titanium and its alloys; phase relationships in titanium-oxygen alloys; strengthening of titanium alloys by shock deformation; and titanium hot forming. This monograph will be of interest to chemists and metallurgists.
This SpringerBrief discusses the determination and classification of the ambient temperature corrosion and stress corrosion properties of aerospace structural alloys, with emphasis on (1) aluminium alloys, modern (3rd generation) aluminium‒lithium alloys, stainless steels and titanium alloys and (2) some of the issues involved. Standard /reference data on environmental properties, including corrosion and stress corrosion, are mandatory for the qualification and certification of materials for aerospace vehicles, and also for the design of actual structures and components. Recommendations for further testing and evaluation are given at appropriate points in the text. The book concludes with a summary of the main topics.