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This textbook presents an exposition of stochastic dynamics and irreversibility. It comprises the principles of probability theory and the stochastic dynamics in continuous spaces, described by Langevin and Fokker-Planck equations, and in discrete spaces, described by Markov chains and master equations. Special concern is given to the study of irreversibility, both in systems that evolve to equilibrium and in nonequilibrium stationary states. Attention is also given to the study of models displaying phase transitions and critical phenomena both in thermodynamic equilibrium and out of equilibrium. These models include the linear Glauber model, the Glauber-Ising model, lattice models with absorbing states such as the contact process and those used in population dynamic and spreading of epidemic, probabilistic cellular automata, reaction-diffusion processes, random sequential adsorption and dynamic percolation. A stochastic approach to chemical reaction is also presented.The textbook is intended for students of physics and chemistry and for those interested in stochastic dynamics. It provides, by means of examples and problems, a comprehensive and detailed explanation of the theory and its applications.
This textbook presents an exposition of stochastic dynamics and irreversibility. It comprises the principles of probability theory and the stochastic dynamics in continuous spaces, described by Langevin and Fokker-Planck equations, and in discrete spaces, described by Markov chains and master equations. Special concern is given to the study of irreversibility, both in systems that evolve to equilibrium and in nonequilibrium stationary states. Attention is also given to the study of models displaying phase transitions and critical phenomena both in thermodynamic equilibrium and out of equilibrium. These models include the linear Glauber model, the Glauber-Ising model, lattice models with absorbing states such as the contact process and those used in population dynamic and spreading of epidemic, probabilistic cellular automata, reaction-diffusion processes, random sequential adsorption and dynamic percolation. A stochastic approach to chemical reaction is also presented.The textbook is intended for students of physics and chemistry and for those interested in stochastic dynamics. It provides, by means of examples and problems, a comprehensive and detailed explanation of the theory and its applications.
The problem of deriving irreversible thermodynamics from the re versible microscopic dynamics has been on the agenda of theoreti cal physics for a century and has produced more papers than can be digested by any single scientist. Why add to this too long list with yet another work? The goal is definitely not to give a gen eral review of previous work in this field. My ambition is rather to present an approach differing in some key aspects from the stan dard treatments, and to develop it as far as possible using rather simple mathematical tools (mainly inequalities of various kinds). However, in the course of this work I have used a large number of results and ideas from the existing literature, and the reference list contains contributions from many different lines of research. As a consequence the reader may find the arguments a bit difficult to follow without some previous exposure to this set of problems.
The monograph is devoted to one of the most important trends in contemporary mathematical physics, the investigation of evolution equations of many-particle systems of statistical mechanics. The book systematizes rigorous results obtained in this field in recent years, and it presents contemporary methods for the investigation of evolution equations of infinite-particle systems. The book is intended for experts in statistical physics, mathematical physics, and probability theory and for students of universities specialized in mathematics and physics.
Leading research, perspectives, and analysis of dynamical systems and irreversibility Edited by Nobel Prize winner Ilya Prigogine and renowned authority Stuart A. Rice, the Advances in Chemical Physics series provides a forum for critical, authoritative evaluations in every area of the discipline. In a format that encourages the expression of individual points of view, experts in the field present comprehensive analyses of subjects of interest. Volume 122 collects papers from the XXI Solvay Conference on Physics, dedicated to the exploration of "Dynamical Systems and Irreversibility." Ioannis Antoniou, Deputy Director of the International Solvay Institutes for Physics and Chemistry, edits and assembles this cutting-edge research, including articles such as "Non-Markovian Effects in the Standard Map," "Harmonic Analysis of Unstable Systems," "Age and Age Fluctuations in an Unstable Quantum System," and discussion of many more subjects. Advances in Chemical Physics remains the premier venue for presentations of new findings in its field.
The monograph is devoted to one of the most important trends in contemporary mathematical physics, the investigation of evolution equations of many-particle systems of statistical mechanics. The book systematizes rigorous results obtained in this field in recent years, and it presents contemporary methods for the investigation of evolution equations of infinite-particle systems. The book is intended for experts in statistical physics, mathematical physics, and probability theory and for students of universities specialized in mathematics and physics.
The first comprehensive graduate-level introduction to stochastic thermodynamics Stochastic thermodynamics is a well-defined subfield of statistical physics that aims to interpret thermodynamic concepts for systems ranging in size from a few to hundreds of nanometers, the behavior of which is inherently random due to thermal fluctuations. This growing field therefore describes the nonequilibrium dynamics of small systems, such as artificial nanodevices and biological molecular machines, which are of increasing scientific and technological relevance. This textbook provides an up-to-date pedagogical introduction to stochastic thermodynamics, guiding readers from basic concepts in statistical physics, probability theory, and thermodynamics to the most recent developments in the field. Gradually building up to more advanced material, the authors consistently prioritize simplicity and clarity over exhaustiveness and focus on the development of readers’ physical insight over mathematical formalism. This approach allows the reader to grow as the book proceeds, helping interested young scientists to enter the field with less effort and to contribute to its ongoing vibrant development. Chapters provide exercises to complement and reinforce learning. Appropriate for graduate students in physics and biophysics, as well as researchers, Stochastic Thermodynamics serves as an excellent initiation to this rapidly evolving field. Emphasizes a pedagogical approach to the subject Highlights connections with the thermodynamics of information Pays special attention to molecular biophysics applications Privileges physical intuition over mathematical formalism Solutions manual available on request for instructors adopting the book in a course
A dominant feature of our ordinary experience of the world is a sense of irreversible change: things lose form, people grow old, energy dissipates. On the other hand, a major conceptual scheme we use to describe the natural world, molecular dynamics, has reversibility at its core. The need to harmonize conceptual schemes and experience leads to several questions, one of which is the focus of this book. How does irreversibility at the macroscopic level emerge from the reversibility that prevails at the molecular level? Attempts to explain the emergence have emphasized probability, and assigned different probabilities to the forward and reversed directions of processes so that one direction is far more probable than the other. The conclu sion is promising, but the reasons for it have been obscure. In many cases the aim has been to find an explana tion in the nature of probability itself. Reactions to that have been divided: some think the aim is justified while others think it is absurd.