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Statistical mechanics has been proven to be successful at describing physical systems at thermodynamic equilibrium. Since most natural phenomena occur in nonequilibrium conditions, the present challenge is to find suitable physical approaches for such conditions: this book provides a pedagogical pathway that explores various perspectives. The use of clear language, and explanatory figures and diagrams to describe models, simulations and experimental findings makes the book a valuable resource for undergraduate and graduate students, and also for lecturers organizing teaching at varying levels of experience in the field. Written in three parts, it covers basic and traditional concepts of nonequilibrium physics, modern aspects concerning nonequilibrium phase transitions, and application-orientated topics from a modern perspective. A broad range of topics is covered, including Langevin equations, Levy processes, directed percolation, kinetic roughening and pattern formation.
This undergraduate textbook provides a statistical mechanical foundation to the classical laws of thermodynamics via a comprehensive treatment of the basics of classical thermodynamics, equilibrium statistical mechanics, irreversible thermodynamics, and the statistical mechanics of non-equilibrium phenomena. This timely book has a unique focus on the concept of entropy, which is studied starting from the well-known ideal gas law, employing various thermodynamic processes, example systems and interpretations to expose its role in the second law of thermodynamics. This modern treatment of statistical physics includes studies of neutron stars, superconductivity and the recently developed fluctuation theorems. It also presents figures and problems in a clear and concise way, aiding the student’s understanding.
The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.
A comprehensive and pedagogical text on nonequilibrium statistical physics, covering topics from random walks to pattern formation.
Kinetic Theory, Volume 2: Irreversible Processes deals with the kinetic theory of gases and the irreversible processes they undergo. It includes the two papers by James Clerk Maxwell and Ludwig Boltzmann in which the basic equations for transport processes in gases are formulated, together with the first derivation of Boltzmann's "H-theorem" and a discussion of this theorem, along with the problem of irreversibility. Comprised of 10 chapters, this volume begins with an introduction to the fundamental nature of heat and of gases, along with Boltzmann's work on the kinetic theory of gases and statistical mechanics. Energy dissipation, the statistical nature of the second law of thermodynamics, and the eternal return and the recurrence paradox are also considered. The first chapter examines the dynamical theory of gases and its application to the explanation of various properties of gases; the known chemical relation between the density of a gas and its equivalent weight, commonly called the Law of Equivalent Volumes; and the diffusion of one gas through another. Subsequent chapters focus on the thermal equilibrium of gas molecules; the three-body problem and the equations of dynamics; the mechanical theory of heat; and the relation of a general mechanical theorem to the second law of thermodynamics. A mechanical explanation of irreversible processes is also offered. This book will be useful for students of physics at the advanced undergraduate or beginning postgraduate level.
Groundbreaking monograph by Nobel Prize winner for researchers and graduate students covers Liouville equation, anharmonic solids, Brownian motion, weakly coupled gases, scattering theory and short-range forces, general kinetic equations, more. 1962 edition.
The first six chapters of this volume present the author's 'predictive' or information theoretic' approach to statistical mechanics, in which the basic probability distributions over microstates are obtained as distributions of maximum entropy (Le. , as distributions that are most non-committal with regard to missing information among all those satisfying the macroscopically given constraints). There is then no need to make additional assumptions of ergodicity or metric transitivity; the theory proceeds entirely by inference from macroscopic measurements and the underlying dynamical assumptions. Moreover, the method of maximizing the entropy is completely general and applies, in particular, to irreversible processes as well as to reversible ones. The next three chapters provide a broader framework - at once Bayesian and objective - for maximum entropy inference. The basic principles of inference, including the usual axioms of probability, are seen to rest on nothing more than requirements of consistency, above all, the requirement that in two problems where we have the same information we must assign the same probabilities. Thus, statistical mechanics is viewed as a branch of a general theory of inference, and the latter as an extension of the ordinary logic of consistency. Those who are familiar with the literature of statistics and statistical mechanics will recognize in both of these steps a genuine 'scientific revolution' - a complete reversal of earlier conceptions - and one of no small significance.
University Physics is designed for the two- or three-semester calculus-based physics course. The text has been developed to meet the scope and sequence of most university physics courses and provides a foundation for a career in mathematics, science, or engineering. The book provides an important opportunity for students to learn the core concepts of physics and understand how those concepts apply to their lives and to the world around them. Due to the comprehensive nature of the material, we are offering the book in three volumes for flexibility and efficiency. Coverage and Scope Our University Physics textbook adheres to the scope and sequence of most two- and three-semester physics courses nationwide. We have worked to make physics interesting and accessible to students while maintaining the mathematical rigor inherent in the subject. With this objective in mind, the content of this textbook has been developed and arranged to provide a logical progression from fundamental to more advanced concepts, building upon what students have already learned and emphasizing connections between topics and between theory and applications. The goal of each section is to enable students not just to recognize concepts, but to work with them in ways that will be useful in later courses and future careers. The organization and pedagogical features were developed and vetted with feedback from science educators dedicated to the project. VOLUME II Unit 1: Thermodynamics Chapter 1: Temperature and Heat Chapter 2: The Kinetic Theory of Gases Chapter 3: The First Law of Thermodynamics Chapter 4: The Second Law of Thermodynamics Unit 2: Electricity and Magnetism Chapter 5: Electric Charges and Fields Chapter 6: Gauss's Law Chapter 7: Electric Potential Chapter 8: Capacitance Chapter 9: Current and Resistance Chapter 10: Direct-Current Circuits Chapter 11: Magnetic Forces and Fields Chapter 12: Sources of Magnetic Fields Chapter 13: Electromagnetic Induction Chapter 14: Inductance Chapter 15: Alternating-Current Circuits Chapter 16: Electromagnetic Waves
This text presents the two complementary aspects of thermal physics as an integrated theory of the properties of matter. Conceptual understanding is promoted by thorough development of basic concepts. In contrast to many texts, statistical mechanics, including discussion of the required probability theory, is presented first. This provides a statistical foundation for the concept of entropy, which is central to thermal physics. A unique feature of the book is the development of entropy based on Boltzmann's 1877 definition; this avoids contradictions or ad hoc corrections found in other texts. Detailed fundamentals provide a natural grounding for advanced topics, such as black-body radiation and quantum gases. An extensive set of problems (solutions are available for lecturers through the OUP website), many including explicit computations, advance the core content by probing essential concepts. The text is designed for a two-semester undergraduate course but can be adapted for one-semester courses emphasizing either aspect of thermal physics. It is also suitable for graduate study.
This important volume describes the wide-ranging scientific activities of Léon Van Hove, through commentaries by his colleagues and a selection of his most influential papers and documents. The reprinted papers are grouped by topic, starting from his early work in mathematics and theoretical and statistical physics, up to his very last contributions in elementary particle physics and multiparticle dynamics. Van Hove's career as teacher, director and science advisor in many European institutions is presented in sketches by friends and coworkers. A selection of his speeches and documented thoughts on science completes the volume.