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This book describes in detail the main concepts of theoretical spectroscopy of transition metal and rare-earth ions. It shows how the energy levels of different electron configurations are formed and calculated for the ions in a free state and in crystals, how group theory can help in solving main spectroscopic problems, and how the modern DFT-based methods of calculations of electronic structure can be combined with the semi-empirical crystal field models. The style of presentation makes the book helpful for a wide audience ranging from graduate students to experienced researchers. Performance of optical materials crucially depends on the impurity ions intentionally introduced into the crystalline host materials. The color of these materials, their emission and absorption spectra can be understood by analyzing the relations between the electronic properties of impurity ions and host crystal structure, which constitutes the main content of this book. It describes in detail the main concepts of theoretical spectroscopy of transition metal and rare earth ions.
The second edition of this classic book provides an updated look at crystal field theory and its applications.
Multiplets of Transition-Metal Ions in Crystals provides information pertinent to ligand field theory. This book discusses the fundamentals of quantum mechanics and the theory of atomic spectra. Comprised of 10 chapters, this book starts with an overview of the qualitative nature of the splitting of the energy level as well as the angular behavior of the wavefunctions. This text then examines the problem of obtaining the energy eigenvalues and eigenstates of the two-electron systems, in which two electrons are accommodated in the t2g and eg shells in a variety of ways. Other chapters discuss the ligand-field potential, which is invariant to any symmetry operation in the group to which symmetry of the system belongs. This book discusses as well the approximate method of expressing molecular orbitals (MO) by a suitable linear combination of atomic orbitals (AO). The final chapter discusses the MO in molecules and the self-consistent field theory of Hartree–Fock. This book is a valuable resource for research physicists, chemists, electronic engineers, and graduate students.
Chemical industries are based on catalytic processes as both bulk and fine chemicals are often produced with heterogeneous catalysts. Transition metal ions dispersed on high-surface area inorganic solids are very important catalysts and a full characterization of these materials requires a profound knowledge of the oxidation state, coordination environment and dispersion of the metal ions on the catalyst surface. Such information can only be obtained by using a combination of complementary spectroscopic techniques. 'Spectroscopy of Transition metal ions on Surfaces' serves as an introduction to some of the most important spectroscopic techniques nowadays used for studying the chemistry and catalytic properties of transition metal ions on surfaces. The basic principles and the strengths and weaknesses of continuous wave electron spin resonance, pulsed electron spin resonance, solid state nuclear magnetic resonance, infrared spectroscopy, Raman spectroscopy, diffuse reflectance spectroscopy and X-ray photoelectron spectroscopy are critically reviewed by internationally recognized experts. This gives the reader a solid background for judging literature results and for planning and conducting his/her own experiments. Each chapter closes with several relevant examples mainly from the recent literature. In addition, the use of in situ techniques and chemometrical techniques has been included because of its growing importance in catalyst characterization. As a consequence, the book has been written as a text not only for graduate students, but also for anyone else who is new in the field and wants a recent update. The following scientists have contributed to this textbook: Br.
This text describes the technique of optical spectroscopy applied to problems in condensed matter physics. It relates theoretical understanding to experimental measurement, including discussion of the optical spectroscopy of inorganic insulators, with many illustrative examples. Symmetry arguments are developed from a formal group theoretical basis and are frequently used, and a special effort is made to treat the subject of lattice vibrations and to show how these can affect the spectroscopic properties of solids. The elements of laser theory are developed, and the authors also explore the use of optically detected magnetic resonance techniques for the investigation of semiconducting materials.
``Spectroscopy of Crystals Containing Rare Earth Ions'' contains chapters on some key problems selected from a broad range of spectroscopic studies of RE-activated solids including both crystalline and glassy materials. Progress in crystal field theory is surveyed, an area which is basic to our understanding of the energy levels. The treatment of dynamical properties includes studies of coherence phenomena in isolated ions, energy transfer between ions and co-operative phenomena associated with ion-ion and ion-lattice interactions. In addition, the role of electron spins and nuclear spins is studied by light scattering and double resonance techniques. The presence of inhomogeneous broadening of spectral lines is observed and studied in many contexts, leading to new insights into general problems of the disordered state. Considerable attention is devoted to describing new experimental techniques whose development is of prime importance for progress in the spectroscopy of RE-activated solids. Many of these rely on the development and application of tunable lasers. At the moment this is a very active field of spectroscopy with more exciting developments likely to occur in the future.
A researcher trying to predict or interpret spectra of transition metal ionsin possible laser host materials is confronted with a variety of different methods of describing the same physical situation. This book provides a systematic approach to the applied theory of crystal-field interactions of transition metal ions in 49 crystalline hosts that are or show promise of being good laser materials. The tables that make up the main part of the book present the experimentally determined parameters of the 3dN, 4dN, and 5dN transition-metal ions in the second, third, and fourth ionization states. These parameters have been converted to Slater and crystal-field parameters. The book is a source for research workers in laser development and in crystal-field theory, and for graduate students of solid state chemistry and physics.
This book focuses mainly on the spectroscopy of laser materials, physics of laser materials, laser crystals and laser glasses. The spectroscopic and laser properties of rare earth and transition metal ion-doped solid state materials are systematically described based on modern quantum optics. The aim of this book is to relate the laser and spectroscopic properties to the structure and chemical composition of materials. It emphasises the nonlinear optical effects in laser materials, which are widely used in high power laser systems. The development of advanced solid state laser devices depends greatly on new laser materials. Much progress has been made recently in the development of new laser materials, and this is summarized in the book.
"Optical Properties of 3d-Ions in Crystals: Spectroscopy and Crystal Field Analysis" discusses spectral, vibronic and magnetic properties of 3d-ions in a wide range of crystals, used as active media for solid state lasers and potential candidates for this role. Crystal field calculations (including first-principles calculations of energy levels and absorption spectra) and their comparison with experimental spectra, the Jahn-Teller effect, analysis of vibronic spectra, materials science applications are systematically presented. The book is intended for researchers and graduate students in crystal spectroscopy, materials science and optical applications. Dr. N.M. Avram is an Emeritus Professor at the Physics Department, West University of Timisoara, Romania; Dr. M.G. Brik is a Professor at the Institute of Physics, University of Tartu, Estonia.
This book provides a conceptual and experimental basis for the interpretation of electronic absorption spectroscopy and related techniques. The basic theories, instrumentation and interpretation of the spectra of organic and coordination compounds for structural studies are presented step-by-step, in an easily understandable style. related topics of emission spectroscopes are covered as well.