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Paraffins: Chemistry and Technology deals primarily with fundamentals of those methods and processes for the manufacture and chemical treatment of the paraffinic hydrocarbons. The present book, the first edition of which was published by the Akademie-Verlag GmbH, Berlin, in 1956, and an unchanged reprint of which of the first edition was necessary in 1959, has been revised, in 1962, for translation into English. The book begins with a discussion of the production and manufacture of the paraffinic hydrocarbons. Separate chapters then cover the catalytic hydrogenation of carbon monoxide by means of the Fischer-Tropsch synthesis; the chlorination, sulfochlorination, and oxidation the paraffins along with the corresponding products; and the direct nitration of the paraffinic hydrocarbons. Subsequent chapters deal with the sulfoxidation and other substitution reactions of the paraffinic hydrocarbons and isomerization of the paraffinic hydrocarbons. The book is directed primarily to the chemist involved in research and development. It will also give the advanced student a picture of the many-sided possibilities of the use of the paraffinic hydrocarbons, which were long regarded as extraordinarily unreactive.
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Fluorine Chemistry, Volume V focuses on the compositions, reactions, properties, and functions of fluorine compounds. The book first discusses the general chemistry of fluorine compounds and the physical chemistry of fluorocarbons. Vapor pressures; details of interaction of polyatomic molecules; coefficients and equations of state for gases; liquid compressibility; and compressibilities of liquid mixtures are discussed. The text looks at the radiochemistry and radiation chemistry of fluorine. Isotopes of fluorine; useful methods for producing F18 and F20; radiochemical properties and counting of F20; fluorine activities in nuclear reactors; and analytical determinations are described. The selection also provides numerical analysis and tabulated representations. The book also focuses on the industrial and utilitarian features of fluorine chemistry. Historical and economic factors; properties of fluorocarbons; refrigerants and propellants; gaseous dielectrics; fire extinguishing agents; and fluorocarbon surfactants are discussed. The text is a vital source of data for readers wanting to study fluorine compounds.
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