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Describes the surface phenomena in soils, both experiment and theory, from the point of view of modern coordinational chemistry. The topics covered include surface area and change, the structure of absorbed water, the points of zero change, electrokinetic phenomena, adsorption of inorganic and organic solutes, computer models of adsorption, a nd colloidal aspects of surface chemistry in soils
Given the presence of a wide variety of contaminants in the environment, it is important to understand what drives a contaminant from one medium to another, as well as the manner and extent to which a contaminant associates with the different media or phases within a local environmental system. Partition and Adsorption of Organic Contaminants in Environmental Systems forms a comprehensive resource on the behavioral characteristics of contaminants so that appropriate strategies can be adopted to either prevent or minimize their adverse impacts on human welfare and natural resources. Cary Chiou’s far-reaching text depicts the processes by which nonionic organic contaminants are sorbed to natural biotic and abiotic substances. This book focuses on physical principles and system parameters that affect the contaminant uptake by soil from water, air, and other media; by fish from water; and by plants from soil and water. As contaminant uptake by natural organic substances is often predominantly a partition interaction, the partition characteristics in several solvent-water model mixtures are treated in detail to elucidate the relevant physicochemical parameters. The account of contaminant sorption to soils, fish, and plants is strengthened by companion chapters on: Fundamentals of solution theory Interphase partition equations Fundamentals of adsorption theory Vapor adsorption on mineral and carbonaceous solids No other single source in the field delivers as compelling a combination of background understanding and "state-of-the-science" comprehension of current issues. Ideally suited for a graduate-level environmental course, Partition and Adsorption of Organic Contaminants in Environmental Systems also serves as a technical guide to current and future research in the field.
Pesticides in the soil environment - an overview. Pesticide sources to the soil and principles of spray physics. The retention processes: mechanisms. Sorption estimates for modeling. Abiotic transformations in water, sediments, and soil. Biological transformation processes of pesticides. Volatilization and vapor transport processes. Organic chemical transport to Groundwater. Movement of pesticides into surface waters. Modeling pesticide fate in soils. Efficacy of soil-applied pesticides. Impact of pesticides on the environment. Risk/benefit and regulations. Chemical index.
In contrast to the classical books which largely focus on separate, individual physicochemical and biological aspects, this book aims to integrate the frontiers of knowledge on the fundamentals and the impact of physicochemical and biological interactions and processes of AOCs in soil, sediment, water and air. The specific objectives of this book are to address: (1) fundamental biophysico-chemical processes of AOCs in the environment, (2) occurrence and distribution of AOCs in air, water, and soil, and their global cycling, (3) the state-of-the-art analytical techniques of AOCs, and (4) restoration of natural environments contaminated by AOCs. The book also identifies the gaps in knowledge on the subject matter and as such provides future directions to stimulate scientific research to advance the chemical science on biophysico-chemical interfacial reactions in natural habitats. By virtue of complex nature of the interactions of AOCs with different environmental components and matrixes, no single available technique and instrument is satisfactory yet for determining their fate, transport, availability, and risk in the environment. In order to fully understand the biophysico-chemical interactions and processes of AOCs in the environment, it is critical to know chemical, physical and biological properties of AOCs and their analytical techniques. The book is unique because of its multidisciplinary approach as it provides a comprehensive and integrated coverage of biophysico-chemical reactions and processes of AOCs in various environments, associated analytical techniques, and restoration of natural environments contaminated by AOCs.
Bioavailability refers to the extent to which humans and ecological receptors are exposed to contaminants in soil or sediment. The concept of bioavailability has recently piqued the interest of the hazardous waste industry as an important consideration in deciding how much waste to clean up. The rationale is that if contaminants in soil and sediment are not bioavailable, then more contaminant mass can be left in place without creating additional risk. A new NRC report notes that the potential for the consideration of bioavailability to influence decision-making is greatest where certain chemical, environmental, and regulatory factors align. The current use of bioavailability in risk assessment and hazardous waste cleanup regulations is demystified, and acceptable tools and models for bioavailability assessment are discussed and ranked according to seven criteria. Finally, the intimate link between bioavailability and bioremediation is explored. The report concludes with suggestions for moving bioavailability forward in the regulatory arena for both soil and sediment cleanup.
In the past decades, environmental scientists, economists and physicists have been juggling critical issues within environmental strategies and environmental management styles in order to find a feasible medium between limited resources, long term demands and objectives, and interest groups. In the search for best management alternatives, practice has undergone a pendulum swing between stages that can be characterised as frontier economics, radical environmentalism, resource management/allocation, selective environmentalism and sustainable environmental management. The next stage of management must answer such questions as: `Can there be a global - uniform environmental strategy?', or `Based on their characteristics, can different issues, different regions and different applications have unique environmental strategies?' Based on this premise, the next stage of management may be identified as risk based sustainable environmental management. The goal of this style will be the risk based, long term, harmonious management of economic resources and environmental preservation for health, safety and prosperity of sustainable populations. When evaluation of risk or risk based ranking of management alternatives enter the picture as part of the overall puzzle, then social policy, ethics and health issues assume a very important role in the management strategy. Economic incentives and environmental constraints have to be considered harmoniously, the main emphasis being placed on protection and preservation of human health and the long term sustaining of populations.