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Sonochemistry is studied primarily by chemists and sonoluminescence mainly by physicists, but a single physical phenomenon - acoustic cavitation - unites the two areas. The physics of cavitation bubble collapse, is relatively well understood by acoustical physicists but remains practically unknown to the chemists. By contrast, the chemistry that gives rise to electromagnetic emissions and the acceleration of chemical reactions is familiar to chemists, but practically unknown to acoustical physicists. It is just this knowledge gap that the present volume addresses. The first section of the book addresses the fundamentals of cavitation, leading to a more extensive discussion of the fundamentals of cavitation bubble dynamics in section two. A section on single bubble sonoluminescence follows. The two following sections address the new scientific discipline of sonochemistry, and the volume concludes with a section giving detailed descriptions of the applications of sonochemistry. The mixture of tutorial lectures and detailed research articles means that the book can serve as an introduction as well as a comprehensive and detailed review of these two interesting and topical subjects.
Sonochemistry is studied primarily by chemists and sonoluminescence mainly by physicists, but a single physical phenomenon - acoustic cavitation - unites the two areas. The physics of cavitation bubble collapse, is relatively well understood by acoustical physicists but remains practically unknown to the chemists. By contrast, the chemistry that gives rise to electromagnetic emissions and the acceleration of chemical reactions is familiar to chemists, but practically unknown to acoustical physicists. It is just this knowledge gap that the present volume addresses. The first section of the book addresses the fundamentals of cavitation, leading to a more extensive discussion of the fundamentals of cavitation bubble dynamics in section two. A section on single bubble sonoluminescence follows. The two following sections address the new scientific discipline of sonochemistry, and the volume concludes with a section giving detailed descriptions of the applications of sonochemistry. The mixture of tutorial lectures and detailed research articles means that the book can serve as an introduction as well as a comprehensive and detailed review of these two interesting and topical subjects.
Sonochemistry and the Acoustic Bubble provides an introduction to the way ultrasound acts on bubbles in a liquid to cause bubbles to collapse violently, leading to localized 'hot spots' in the liquid with temperatures of 5000° celcius and under pressures of several hundred atmospheres. These extreme conditions produce events such as the emission of light, sonoluminescence, with a lifetime of less than a nanosecond, and free radicals that can initiate a host of varied chemical reactions (sonochemistry) in the liquid, all at room temperature. The physics and chemistry behind the phenomena are simply, but comprehensively presented. In addition, potential industrial and medical applications of acoustic cavitation and its chemical effects are described and reviewed. The book is suitable for graduate students working with ultrasound, and for potential chemists and chemical engineers wanting to understand the basics of how ultrasound acts in a liquid to cause chemical and physical effects.
This book was written by authors in the field of ultrasound-assited synthesis and their applications. Among others, some of the topics covered are: ultrasound-assited synthesis of metal/metal oxide nanoparticles, graphene nanosheets, and ultrasound applications. In this book, authors focused on recent studies, applications, and new technological developments on fundamental properties of the ultrasound process.
Despite the fact that chemical applications of ultrasound are now widely acknowledged, a detailed presentation of inorganic systems covering nano-particles, catalysis, aqueous chemistry of metallic solutions and their redox characteristics, both from a theoretical and experimental perspective has eluded researchers of this field. Theoretical and Experimental Sonochemistry Involving Inorganic Systems fills this gap and presents a concise and thorough review of this fascinating area of Sonochemistry in a single volume.
This brief explains in detail fundamental concepts in acoustic cavitation and bubble dynamics, and describes derivations of the fundamental equations of bubble dynamics in order to support those readers just beginning research in this field. Further, it provides an in-depth understanding of the physical basis of the phenomena. With regard to sonochemistry, the brief presents the results of numerical simulations of chemical reactions inside a bubble under ultrasound, especially for a single-bubble system and including unsolved problems. Written so as to be accessible both with and without prior knowledge of fundamental fluid dynamics, the brief offers a valuable resource for students and researchers alike, especially those who are unfamiliar with this field. A grasp of fundamental undergraduate mathematics such as partial derivative and fundamental integration is advantageous; however, even without any background in mathematics, readers can skip the equations and still understand the fundamental physics of the phenomena using the book’s wealth of illustrations and figures. As such, it is also suitable as an introduction to the field.
While it is still a mystery of how a low-energy-density sound wave can concentrate enough energy in a small enough volume to cause the emission of light, research in acoustic cavitation and sonoluminescence has lead to plausible theories in which the source of light can be experimentally sustained. It has also lead to promising applications, such a
The Acoustic Bubble describes the interaction of acoustic fields with bubbles in liquid. The book consists of five chapters. Chapter 1 provides a basic introduction to acoustics, including some of the more esoteric phenomena that can be seen when high-frequency high-intensity underwater sound is employed. Chapter 2 discusses the nucleation of cavitation and basic fluid dynamics, while Chapter 3 draws together the acoustics and bubble dynamics to discuss the free oscillation of a bubble and acoustic emissions from such activity. The acoustic probes that are often applied to study the behavior of a bubble when an externally-applied acoustic field drives it into oscillation is deliberated in Chapter 4. The last chapter outlines a variety of effects associated with acoustically-induced bubble activity. The bubble detection, sonoluminescence, sonochemistry, and pulse enhancement are also covered. This publication is a good reference for physics and engineering students and researchers intending to acquire knowledge of the acoustic interactions of acoustic fields with bubbles.
This book presents the latest research on fundamental aspects of acoustic bubbles, and in particular on various complementary ways to characterize them. It starts with the dynamics of a single bubble under ultrasound, and then addresses few-bubble systems and the formation and development of bubble structures, before briefly reviewing work on isolated bubbles in standing acoustic waves (bubble traps) and multibubble systems where translation and interaction of bubbles play a major role. Further, it explores the interaction of bubbles with objects, and highlights non-spherical bubble dynamics and the respective collapse geometries. It also discusses the important link between bubble dynamics and energy focusing in the bubble, leading to sonochemistry and sonoluminescence. The second chapter focuses on the emission of light by cavitation bubbles at collapse (sonoluminescence) and on the information that can be gained by sonoluminescence (SL) spectroscopy, e.g. the conditions reached inside the bubbles or the nature of the excited species formed. This chapter also includes a section on the use of SL intensity measurement under pulsed ultrasound as an indirect way to estimate bubble size and size distribution. Lastly, since one very important feature of cavitation systems is their sonochemical activity, the final chapter presents chemical characterizations, the care that should be taken in using them, and the possible visualization of chemical activity. It also explores the links between bubble dynamics, SL spectroscopy and sonochemical activity. This book provides a fundamental basis for other books in the Molecular Science: Ultrasound and Sonochemistry series that are more focused on applied aspects of sonochemistry. A basic knowledge of the characterization of cavitation bubbles is indispensable for the optimization of sonochemical processes, and as such the book is useful for specialists (researchers, engineers, PhD students etc.) working in the wide area of ultrasonic processing.