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Solidification and Crystallization Processing in Metals and Alloys Hasse Fredriksson KTH, Royal Institute of Technology, Stockholm, Sweden Ulla Åkerlind University of Stockholm, Sweden Solidification or crystallization occurs when atoms are transformed from the disordered liquid state to the more ordered solid state, and is fundamental to metals processing. Conceived as a companion volume to the earlier works, Materials Processing during Casting (2006) and Physics of Functional Materials (2008), this book analyzes solidification and crystallization processes in depth. Starting from the thermodynamic point of view, it gives a complete description, taking into account kinetics and mass transfer, down to the final structure. Importantly, the book shows the relationship between the theory and the experimental results. Topics covered include: Fundamentals of thermodynamics Properties of interfaces Nucleation Crystal growth - in vapours, liquids and melts Heat transport during solidification processes Solidification structures - faceted, dendritic, eutectic and peritectic Metallic glasses and amorphous alloy melts Solidification and Crystallization Processing in Metals and Alloys features many solved examples in the text, and exercises (with answers) for students. Intended for Masters and PhD students as well as researchers in Materials Science, Engineering, Chemistry and Metallurgy, it is also a valuable resource for engineers in industry.
Current interest in research of solidification of melts is focussed to understand crystal nucleation and crystal growth. They determine the solidified product with its physical properties. A detailed description of these processes lead to the development and validation of physical models, which may form the basis of quantitative modelling of solidification routes in e.g. casting and foundry processes in order to develop a predictive capability in the design of materials during solidification. This book, based on a symposium held at EUROMAT 2003 aims to gives an overview on current developments in the research of solidification and crystallisation of liquids. The materials of interest range from metals and their alloys over semiconductors and isolators to organic substances.
Rapidly Quenched Metals, Volume I covers the proceedings of the Fifth International Conference on Rapidly Quenched Metals, held in Wurzburg, Germany on September 3-7, 1984. The book focuses on amorphous and crystalline metals formed by rapid quenching from the melt. The selection first covers the scope and trends of developments in rapid solidification technology, rapid solidification, and undercooling of liquid metals by rapid quenching. Discussions focus on experimental method, powders, strip, particulate production, consolidation, and alloys and alloy systems. The text then examines the solidification of undercooled liquid alloys entrapped in solid; crystallization kinetics in undercooled droplets; and grain refinement in bulk undercooled alloys. The manuscript tackles the undercooling of niobium-germanium alloys in a 100 meter drop tube; influence of process parameters on the cooling rate of the meltspinning process; and the mechanism of ribbon formation in melt-spun copper and copper-zirconium. The formation and structure of thick sections of rapidly-solidified material by incremental deposition and production of ultrafine dispersions of rare earth oxides in Ti alloys using rapid solidification are also mentioned. The selection is a valuable reference for physicists, chemists, physical metallurgists, and engineers.
The 3rd edition of this popular textbook covers current topics in all areas of casting solidification. Partial differential equations and numerical analysis are used extensively throughout the text, with numerous calculation examples, to help the reader in achieving a working knowledge of computational solidification modeling. The features of this new edition include: • new chapters on semi-solid and metal matrix composites solidification • a significantly extended treatment of multiscale modeling of solidification and its applications to commercial alloys • a survey of new topics such as solidification of multicomponent alloys and molecular dynamic modeling • new theories, including a theory on oxide bi-films in the treatment of shrinkage problems • an in-depth treatment of the theoretical aspects of the solidification of the most important commercial alloys including steel, cast iron, aluminum-silicon eutectics, and superalloys • updated tables of material constants.
The progress of civilization can be, in part, attributed to their ability to employ metallurgy. This book is an introduction to multiple facets of physical metallurgy, materials science, and engineering. As all metals are crystalline in structure, it focuses attention on these structures and how the formation of these crystals are responsible for certain aspects of the material's chemical and physical behaviour. Concepts in Physical Metallurgy also discusses the mechanical properties of metals, the theory of alloys, and physical metallurgy of ferrous and non-ferrous alloys.
When considering the operational performance of stainless steel weldments the most important points to consider are corrosion resistance, weld metal mechanical properties and the integrity ofthe weldedjoint. Mechanical and corrosion resistance properties are greatly influenced by the metallurgical processes that occur during welding or during heat treatment of welded components. This book is aimed, there fore, at providing information on the metallurgical problems that may be encountered during stainless steel welding. In this way we aim to help overcome a certain degree of insecurity that is often encountered in welding shops engaged in the welding of stainless steels and is often the cause of welding problems which may in some instances lead to the premature failure of the welded component. The metallurgical processes that occur during the welding of stainless steel are of a highly intricate nature. The present book focuses in particular on the signif icance of constitution diagrams, on the processes occurring during the solidification of weld metal and on the recrystallization and precipitation phenomena which take place in the area of the welds. There are specific chapters covering the hot cracking resistance during welding and the practical welding of a number of different stainless steel grades. In addition, recommendations are given as to the most suitable procedures to be followed in order to obtain maximum corrosion resistance and mechanical properties from the weldments.
Reflecting the fast pace of research in the field, the Second Edition of Bulk Metallic Glasses has been thoroughly updated and remains essential reading on the subject. It incorporates major advances in glass forming ability, corrosion behavior, and mechanical properties. Several of the newly proposed criteria to predict the glass-forming ability of alloys have been discussed. All other areas covered in this book have been updated, with special emphasis on topics where significant advances have occurred. These include processing of hierarchical surface structures and synthesis of nanophase composites using the chemical behavior of bulk metallic glasses and the development of novel bulk metallic glasses with high-strength and high-ductility and superelastic behavior. New topics such as high-entropy bulk metallic glasses, nanoporous alloys, novel nanocrystalline alloys, and soft magnetic glassy alloys with high saturation magnetization have also been discussed. Novel applications, such as metallic glassy screw bolts, surface coatings, hyperthermia glasses, ultra-thin mirrors and pressure sensors, mobile phone casing, and degradable biomedical materials, are described. Authored by the world’s foremost experts on bulk metallic glasses, this new edition endures as an indispensable reference and continues to be a one-stop resource on all aspects of bulk metallic glasses.
Written by academics with more than 30 years experience teaching physics and material science, this book will act as a one-stop reference on functional materials. Offering a complete coverage of functional materials, this unique book deals with all three states of the material, providing an insightful overview of this subject not before seen in other texts. Includes solved examples, a number of exercises and answers to the exercises. Aims to promote understanding of the subject as a basis for higher studies. The use of mathematically complicated quantum mechanical equations will be minimized to aid understanding. For Instructors & Students: Visit Wiley’s Higher Education Site for: Supplements Online Resources Technology Solutions Instructors may request an evaluation copy for this title.
This textbook explains the physics of phase transformation and associated constraints from a metallurgical or materials science point of view, based on many topics including crystallography, mass transport by diffusion, thermodynamics, heat transfer and related temperature gradients, thermal deformation, and even fracture mechanics. The work presented emphasizes solidification and related analytical models based on heat transfer. This corresponds with the most fundamental physical event of continuous evolution of latent heat of fusion for directional or non-directional liquid-to-solid phase transformation at a specific interface with a certain geometrical shape, such as planar or curved front. Dr. Perez introduces mathematical and engineering approximation schemes for describing the phase transformation, mainly during solidification of pure metals and alloys. Giving clear definitions and explanations of theoretical concepts and full detail of derivation of formulae, this interdisciplinary volume is ideal for graduate and upper-level undergraduate students in applied science, and professionals in the metal making and surface reconstruction industries.