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This book highlights the state of the art in solid electrolytes, with particular emphasis on lithium garnets, electrolyte-electrode interfaces and all-solid-state batteries based on lithium garnets. Written by an international group of renowned experts, the book addresses how garnet-type solid electrolytes are contributing to the development of safe high energy density Li batteries. Unlike the flammable organic liquid electrolyte used in existing rechargeable Li batteries, garnet-type solid electrolytes are intrinsically chemically stable in contact with metallic lithium and potential positive electrodes, while offering reasonable Li conductivity. The book's respective chapters cover a broad spectrum of topics related to solid electrolytes, including interfacial engineering to resolve the electrolyte-electrode interfaces, the latest developments in the processing of thin and ultrathin lithium garnet membranes, and fabrication strategies for the high-performance solid-state batteries.This highly informative and intriguing book will appeal to postgraduate students and researchers at academic and industrial laboratories with an interest in the advancement of high energy-density lithium metal batteries
Solid-state batteries hold the promise of providing energy storage with high volumetric and gravimetric energy densities at high power densities, yet with far less safety issues relative to those associated with conventional liquid or gel-based lithium-ion batteries. Solid-state batteries are envisioned to be useful for a broad spectrum of energy storage applications, including powering automobiles and portable electronic devices, as well as stationary storage and load-leveling of renewably generated energy. This comprehensive handbook covers a wide range of topics related to solid-state batteries, including advanced enabling characterization techniques, fundamentals of solid-state systems, novel solid electrolyte systems, interfaces, cell-level studies, and three-dimensional architectures. It is directed at physicists, chemists, materials scientists, electrochemists, electrical engineers, battery technologists, and evaluators of present and future generations of power sources. This handbook serves as a reference text providing state-of-the-art reviews on solid-state battery technologies, as well as providing insights into likely future developments in the field. It is extensively annotated with comprehensive references useful to the student and practitioners in the field.
All-solid-state batteries have gained much attention as the next-generation batteries. This book is about various Li ion ceramic electrolytes and their applications to all-solid-state battery. It contains a wide range of topics from history of ceramic electrolytes and ion conduction mechanisms to recent research achievements. Here oxide-type and sulfide-type ceramic electrolytes are described in detail. Additionally, their applications to all-solid-state batteries, including Li-air battery and Li-S battery, are reviewed.Consisting of fundamentals and advanced technology, this book would be suitable for beginners in the research of ceramic electrolytes; it can also be used by scientists and research engineers for more advanced development.
Since the 90s, the Li-ion batteries are the most commonly used energy storage systems. The demand for performance and safety is constantly growing, current commercial batteries based liquid electrolytes or gels may not be able to meet the needs of emerging applications such as for electric and hybrid vehicles and renewable energy storage , and it is therefore necessary to develop advanced storage systems with characteristics such that the highest density of energy technology, long life, low cost of production, little or no maintenance and high safety of use. Batteries "all solid" are a technology of choice to meet these requirements. In this technology, the electrolyte separator between the two electrodes is no longer a liquid medium but a solid.
Recent years has seen a tremendous growth in interest for solid state batteries based on polymer electrolytes, with advantages of higher safety, energy density, and ease of processing. The book explains which polymer properties guide the performance of the solid-state device, and how these properties are best determined. It is an excellent guide for students, newcomers and experts in the area of solid polymer electrolytes.
Storage and conversion are critical components of important energy-related technologies. "Advanced Batteries: Materials Science Aspects" employs materials science concepts and tools to describe the critical features that control the behavior of advanced electrochemical storage systems. This volume focuses on the basic phenomena that determine the properties of the components, i.e. electrodes and electrolytes, of advanced systems, as well as experimental methods used to study their critical parameters. This unique materials science approach utilizes concepts and methodologies different from those typical in electrochemical texts, offering a fresh, fundamental and tutorial perspective of advanced battery systems. Graduate students, scientists and engineers interested in electrochemical energy storage and conversion will find "Advanced Batteries: Materials Science Aspects" a valuable reference.
The idea of a NATO Science Committee Institute on "Materials for Advanced Batteries" was suggested to JB and DWM by Dr. A. G. Chynoweth. His idea was to bring together experts in the field over the entire spectrum of pure research to applied research in order to familiarize everyone with potentially interesting new systems and the problems involved in their development. Dr. M. C. B. Hotz and Professor M. N. Ozdas were instrumental in helping organize this meeting as a NATO Advanced Science Institute. An organlzlng committee consisting of the three of us along with W. A. Adams, U. v Alpen, J. Casey and J. Rouxel organized the program. The program consisted of plenary talks and poster papers which are included in this volume. Nearly half the time of the conference was spent in study groups. The aim of these groups was to assess the status of several key aspects of batteries and prospects for research opportunities in each. The study groups and their chairmen were: Current status and new systems J. Broadhead High temperature systems W. A. Adams Interface problems B. C. H. Steele Electrolytes U. v Alpen Electrode materials J. Rouxel These discussions are summarized in this volume. We and all the conference participants are most grateful to Professor J. Rouxel for suggesting the Aussois conference site, and to both he and Dr. M. Armand for handling local arrangements.