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Materials with nanometer size particles exhibit unique chemical and physical properties. In particular, nanocomposite materials, composed of nanometric metal and metal oxide particles embedded in vitreous matrices, present a variety of interesting magnetic, electric and catalytic properties, that are strongly size-dependent. Among the different preparation methods which can be used to obtain this kind of materials, the sol-gel process is particularly interesting because it is affected by several parameters which allow a versatile control of the structural, textural and chemical properties of the final products. The present volume focusses on the preparation of metal-silica and metal oxide-silica (Me=Ni, Fe, Zn) nanocomposites by the sol-gel method and the characterization of their structural and magnetic properties.
Metal Oxide Nanocomposites: Synthesis and Applications summarizes many of the recent research accomplishments in the area of metal oxide-based nanocomposites. This book focussing on the following topics: Nanocomposites preparation and characterization of metal oxide nanocomposites; synthesis of core/shell metal oxide nanocomposites; multilayer thin films; sequential assembly of nanocomposite materials; semiconducting polymer metal oxide nanocomposites; graphene-based metal and metal oxide nanocomposites; carbon nanotube–metal–oxide nanocomposites; silicon mixed oxide nanocomposites; gas semiconducting sensors based on metal oxide nanocomposites; metal ]organic framework nanocomposite for hydrogen production and nanocomposites application towards photovoltaic and photocatalytic.
This book provides comprehensive coverage of nanocomposite materials obtained by the sol-gel method, from synthesis to applications and including design tools for combining different properties. Sol-gel nanocomposites are of great interest in meeting processing and application requirements for the development of multifunctional materials. These materials are already commercialized for a number of applications from scratch-resistant and anti-adhesive coatings to optical materials with active and passive properties. Biomedical applications, holographic recordings, fuel cells and hydrogen storage, resists and catalysts are among the potential uses. The novel mechanical, optical and electronic properties of nanocomposite materials depend not only on the individual component materials, but also on their morphology and nanoscale interfacial characteristics. Sol-gel is a highly versatile method for obtaining both the matrix and the filler of the nanocomposite and for chemically adjusting the interface to optimize structure and properties. Although nanocomposites are widely discussed in the literature, the focus has been mainly on polymer nanocomposites. This book addresses nanocomposites based on inorganic or hybrid organic-inorganic matrices, with an emphasis on the scientific principles which are the basis for nanocomposite sol-gel synthesis and applications. A didactic approach is followed, with different topics developed from a fundamental point of view together with key examples and case studies. First comprehensive treatment of nanocomposites obtained by sol-gel methods Focuses on nanocomposites with inorganic and hybrid organic-inorganic matrices Describes design tools to optimize structure and properties for various applications Covers synthesis, processing, characterization, and modeling Uses first principles to describe the influence of interfacial characteristics on materials properties Presents case studies for both films and bulk applications Provides examples of products on the market, with descriptions of the scientific principles at the base of their success Includes contributions from recognized leaders in this multidisciplinary area.
Versatility, extended compositional ranges, better homogeneity, lesser energy consumption, and requirement of nonexpensive equipments have boosted the use of sol-gel process on top of the popularity in the synthesis of nanosystems. The sol-gel technique has not only revolutionized oxide ceramics industry and/or material science but has also extended widely into multidimensional applications. The book Recent Applications in Sol-Gel Synthesis comprises 14 chapters that deal mainly with the application-oriented aspects of the technique. Sol-gel prepared metal oxide (MO) nanostructures like nanospheres, nanorods, nanoflakes, nanotubes, and nanoribbons have been employed in biomedical applications involving drug deliveries, mimicking of natural bone, and antimicrobial activities. The possibility of controlling grain size in aerogel and preparation of ultrahigh-temperature ceramic (UHTC)-based materials, fluorescent glasses, ultraviolet photosensors, and photocatalysts have been discussed in detail by the experts in the field. The usefulness of sol-gel materials as active GRIN, as textile finisher, and as leather modifier with water-repellent and oil-resistive properties would be an incentive for researchers keen to pursue the field.
Aerogels are the lightest solids known. Up to 1000 times lighter than glass and with a density as low as only four times that of air, they show very high thermal, electrical and acoustic insulation values and hold many entries in Guinness World Records. Originally based on silica, R&D efforts have extended this class of materials to non-silicate inorganic oxides, natural and synthetic organic polymers, carbon, metal and ceramic materials, etc. Composite systems involving polymer-crosslinked aerogels and interpenetrating hybrid networks have been developed and exhibit remarkable mechanical strength and flexibility. Even more exotic aerogels based on clays, chalcogenides, phosphides, quantum dots, and biopolymers such as chitosan are opening new applications for the construction, transportation, energy, defense and healthcare industries. Applications in electronics, chemistry, mechanics, engineering, energy production and storage, sensors, medicine, nanotechnology, military and aerospace, oil and gas recovery, thermal insulation and household uses are being developed with an estimated annual market growth rate of around 70% until 2015. The Aerogels Handbook summarizes state-of-the-art developments and processing of inorganic, organic, and composite aerogels, including the most important methods of synthesis, characterization as well as their typical applications and their possible market impact. Readers will find an exhaustive overview of all aerogel materials known today, their fabrication, upscaling aspects, physical and chemical properties, and most recent advances towards applications and commercial products, some of which are commercially available today. Key Features: •Edited and written by recognized worldwide leaders in the field •Appeals to a broad audience of materials scientists, chemists, and engineers in academic research and industrial R&D •Covers inorganic, organic, and composite aerogels •Describes military, aerospace, building industry, household, environmental, energy, and biomedical applications among others
Sol-Gel processing methods, first used historically for decorative and constructional materials, were extensively developed in the last century for applications such as glasses, ceramics, catalysts, coatings, composites and fibres. Today they are reaching their full potential, enabling the preparation of new generations of advanced materials not easily accessible by other methods yet using mild, low-energy conditions. The topic is therefore increasingly included in advanced undergraduate, MSc and PhD programmes in the areas of chemistry, physics and materials science. This concise introductory text, written at the advanced undergraduate/first-year postgraduate level, is also suitable as an introduction to the development, mechanisms, chemistry, characterisation methods and applications of the technique. It provides readers with an extensive yet concise grounding in the theory of each area of the subject and details the real and potential applications and the future prospects of sol-gel chemistry.
Metal Oxide Nanoparticles in Organic Solvents discusses recent advances in the chemistry involved for the controlled synthesis and assembly of metal oxide nanoparticles, the characterizations required by such nanoobjects, and their size and shape depending properties. In the last few years, a valuable alternative to the well-known aqueous sol-gel processes was developed in the form of nonaqueous solution routes. Metal Oxide Nanoparticles in Organic Solvents reviews and compares surfactant- and solvent-controlled routes, as well as providing an overview of techniques for the characterization of metal oxide nanoparticles, crystallization pathways, the physical properties of metal oxide nanoparticles, their applications in diverse fields of technology, and their assembly into larger nano- and mesostructures. Researchers and postgraduates in the fields of nanomaterials and sol-gel chemistry will appreciate this book’s informative approach to chemical formation mechanisms in relation to metal oxides.
This comprehensive three-volume handbook brings together a review of the current state together with the latest developments in sol-gel technology to put forward new ideas. The first volume, dedicated to synthesis and shaping, gives an in-depth overview of the wet-chemical processes that constitute the core of the sol-gel method and presents the various pathways for the successful synthesis of inorganic and hybrid organic-inorganic materials, bio- and bio-inspired materials, powders, particles and fibers as well as sol-gel derived thin films, coatings and surfaces. The second volume deals with the mechanical, optical, electrical and magnetic properties of sol-gel derived materials and the methods for their characterization such as diffraction methods and nuclear magnetic resonance, infrared and Raman spectroscopies. The third volume concentrates on the various applications in the fields of membrane science, catalysis, energy research, biomaterials science, biomedicine, photonics and electronics.
This book presents reliable, well-tested, up-to-date methods of synthesizing the major iron oxides. Such a collection is invaluable since iron oxides play an important role in numerous disciplines, including chemistry, soil science, medicine, corrosion science and aquatic and environmental chemistry. The emphasis is on techniques and apparatus that are readily accessible to the scientist. For students, the sections dealing with potential sources of error should prove extremely useful. Techniques for iron oxide characterization are also described in detail. Special Feature: color plates illustrating how the color of iron oxides varies with crystal structure, particle size, and metal substitution.
Oxide surface materials are widely used in many applications, in particular where chemically modified oxide surfaces are involved. Indeed, in disciplines such as separation, catalysis, bioengineering, electronics, ceramics, etc., modified oxide surfaces are very important. In all cases, the knowledge of their chemical and surface characteristics is of great importance for the understanding and eventual improvement of their performances. This book reviews the latest techniques and procedures in the characterization and chemical modification of the silica surface, presenting a unified and state-of-the-art approach to the relevant analysis techniques and modification procedures, covering 1000 references integrated into one clear concept.