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With the increasing demand for optimization of energy storage, maintenance of the environment, and effective production, control on nanostructures of catalysts and optimization of their organization have become key to achieving high efficiency and specificity in energy and material conversion systems. This book emphasizes and summarizes the novel design of soft matters (molecules, polymers, assembled motifs, etc.) for nanocatalysts and nanocatalyst supports. The diversity or specialty of soft matters offers a new perspective and great promise for the development of new nanocatalytic systems for future requirements. Soft matters can provide a simple and well-defined space for the discovery of new catalysts. This book covers nonmetallic organocatalysts, organometallic compounds, dendrimers, ionic liquids, enzymes, polymers, various organized nanoarchitectures for supporting catalysts, and molecular dynamics in catalytic surface reactions. It gives readers a complete picture of the catalysis systems based on soft matters and is a useful reference for advanced undergraduate- and graduate-level students and researchers in chemistry, biology, materials science, nanoscience, polymer science, and catalysis.
Bicontinuous interfacially jammed emulsion gels, now commonly termed 'bijels', are a class of soft materials, in which interpenetrating, continuous domains of two immiscible fluids are maintained in a rigid arrangement by a jammed layer of colloidal particles at their interface. Such gels have unusual material properties that promise exciting applications across diverse fields from energy materials and catalysis, to food science. This is the first book on the subject and provides the reader with a fundamental introduction. Edited by a recognised authority on bijels, the reader will learn about the bijel and its formation. Bringing together current understanding, this book aims to bring the potential application of bijels to diverse materials challenges closer to fruition. This is a must-have resource for anyone working in soft matter and applied fields.
"Soft matter science is an interdisciplinary field at the interface of physics, biology, chemistry, engineering, and materials science. It encompasses colloids, polymers, and liquid crystals as well as rapidly emerging topics such as metamaterials, memory formation and learning in matter, bioactive systems, and artificial life. This textbook introduces key phenomena and concepts in soft matter from a modern perspective, marrying established knowledge with the latest developments and applications. The presentation integrates statistical mechanics, dynamical systems, and hydrodynamic approaches, emphasizing conservation laws and broken symmetries as guiding principles while paying attention to computational and machine learning advances. The book features introductory chapters on fluid mechanics, elasticity, and stochastic phenomena and also covers advanced topics such as pattern formation and active matter. it discusses technological applications as well as relevant phenomena in the life sciences and offers perspectives on emerging research directions"--
This book is indexed in Chemical Abstracts ServiceSoft and bio-nanomaterials offer a tremendously rich behavior due to the diversity and tailorability of their structures. Built from polymers, nanoparticles, small and large molecules, peptoids and other nanoscale building blocks, such materials exhibit exciting functions, either intrinsically or through the engineering of their organization and combination of blocks. Thus, it is not surprising that a variety of challenges, for example, in energy storage, environment protection, advanced manufacturing, purification and healthcare, can be addressed using these materials. The recent advances in understanding the behavior of soft matter and biomaterials are being actively translated into functional materials systems and devices, which take advantages of newly discovered and specifically created morphologies with desired properties. This major reference work presents a detailed overview of recent research developments on fundamental and application-inspired aspects of soft and bio-nanomaterials and their emerging functions, and will be divided into four volumes: Vol 1: Soft Matter under Geometrical Confinement: From Fundamentals at Planar Surfaces and Interfaces to Functionalities of Nanoporous Materials; Vol 2: Polymers on the Nanoscale: Nano-structured Polymers and Their Applications; Vol 3: Bio-Inspired Nanomaterials: Nanomaterials Built from Biomolecules and Using Bio-derived Principles; Vol 4: Nanomedicine: Nanoscale Materials in Nano/Bio Medicine.
This book addresses the manufacturing methods, characteristic tubular morphologies, diverse functions, and potent applications of organic tubular architectures prepared or self-assembled from rationally designed molecular building blocks. The hollow cylindrical structures with high-aspect ratios are capable of creating unique functions that can be differentiated from well-known self-assembled nanostructures such as organic nanofibers, nanoribbons, and nanorods. Encapsulation, stabilization, transportation, release, and their cooperative functions pave the way for innovative chemical, physical, biological, and medical applications. The book presents attractive advantages of soft-matter nanotubes, which are also different from well-known hard-matter nanostructures such as carbon nanotubes. The topics and figures in this volume intrigue not only academic researchers but also engineers and university students.
A comprehensive look at the latest advances in soft material gradients Tremendous progress has been made in the field of surface-bound soft material gradients in recent years, with intriguing new areas of investigation opening up and advances in bioanalytics changing the way high-throughput screening methods are used in the design and discovery of catalysts and new materials. This volume provides the first complete, up-to-date summary of the progress in this field, showing readers how to harness the powerful properties of soft matter gradients in the design and development of modern functional materials. Contributed chapters from experts in diverse fields help bridge areas of materials science, chemistry, and biomaterials, covering fabrication techniques, gradients in self-assembled monolayers, polymer gradients, dynamic gradient structures, structure and assembly, mechanical properties, sensors, biomaterial applications, protein adsorption, and organization of cells on gradient surfaces. Readers will learn how to implement the techniques described in the book in their own work, while improving efficacy and lowering research and production costs. Soft Matter Gradient Surfaces is an invaluable resource for chemists, physicists, biologists, and engineers, and anyone who would like to take advantage of these unique soft matter building blocks.
Vanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast. Bringing together the research on the catalytic uses of this element into one essential resource, including theoretical perspectives on proposed mechanisms for vanadium catalysis and an overview of its relevance in biological processes, this book is a useful reference for industrial and academic chemists alike.
The pivotal text that bridges the gap between fundamentals and applications of soft matter in organic electronics Covering an expanding and highly coveted subject area, Supramolecular Soft Matter enlists the services of leading researchers to help readers understand and manipulate the electronic properties of supramolecular soft materials for use in organic opto-electronic devices, such as photovoltaics and field effect transistors, some of the most desired materials for energy conservation. Rather than offering a compilation of current trends in supramolecular soft matter, this book bridges the gap between fundamentals and applications of soft matter in organic electronics in an effort to open new directions in research for applying supramolecular assembly into organic materials while also focusing on the morphological functions originating from the materials' self-assembled architectures. This unique approach distinguishes Supramolecular Soft Matter as a valuable resource for learning to identify concepts that hold promise for the successful development of organic/polymeric electronics for use in real-world applications. Supramolecular Soft Matter: Combines important topics to help supramolecular chemists and organic electronics researchers work together Covers an interdisciplinary field of prime importance to government-supported R&D research Discusses the concepts and perspectives in a dynamic field to aid in the successful development of organic electronics Includes applications for energy conservation like photovoltaics and field effect transistors Teeming with applicable information on both molecular design and synthesis, as well as the development of smart molecular assemblies for organic electronic systems, Supramolecular Soft Matter provides more practical in-depth coverage of this rapidly evolving technology than any other book in its field.
Recently there have been profound developments in the understanding and interpretation of liquids and soft matter centered on constituents with sho- range interactions. Ionic soft matter is a class of conventional condensed soft matter with prevailing contribution from electrostatics and, therefore, can be subject to possible long-range correlations among the components of the - terial and in many cases crucially affecting its physical properties. Among the most popular representatives of such a class of materials are natural and synthetic saline environments, like aqueous and non-aqueous electrolyte - lutions and molten salts as well as variety of polyelectrolytes and colloidal suspensions. Equally well known are biological systems of proteins. All these systems are examples of soft matter strongly in?uenced, if not dominated, by long-range forces. For more than half of century the classical theories by Debye and Hückel as well as by Derjaguin, Landau, Verwey and Owerbeek (DLVO) have been at the basis of theoretical physical chemistry and chemical engineering. The substantial progress in material science during last few decades as well as the advent of new instrumentation and computational techniques made it apparent that in many cases the classical theories break down. New types of interactions (e.g. hydrodynamic, entropic) have been discovered and a number of questions have arisen from theoretical and experimental studies. Many of these questions still do not have de?nite answers.