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Simple Processes at the Gas-Solid Interface
In Volume 30, an attempt is made to consider comprehensively both theoretical and experimental data that have been obtained to date on electron tunneling reactions involving chemical compounds of various classes, and to discuss the role played by these reactions in different areas of chemistry. The discussion of the above problem is preceded by a review of data on tunneling phenomena in nuclear physics, atomic physics, solid-state physics, as well as on the tunneling effects in chemistry that go beyond the framework of the main subject of this monograph. This review is included to acquaint the reader with the role of tunneling phenomena in physics and chemistry as a whole, to show how diversified the kingdom of tunneling phenomena is, and to see more distinctly the similarities and the differences between electron tunneling in chemical reactions and other tunnel phenomena.
Modeling of Chemical Reactions covers detailed chemical kinetics models for chemical reactions. Including a comprehensive treatment of pressure dependent reactions, which are frequently not incorporated into detailed chemical kinetic models, and the use of modern computational quantum chemistry, which has recently become an extraordinarily useful component of the reaction kinetics toolkit. It is intended both for those who need to model complex chemical reaction processes but have little background in the area, and those who are already have experience and would benefit from having a wide range of useful material gathered in one volume. The range of subject matter is wider than that found in many previous treatments of this subject. The technical level of the material is also quite wide, so that non-experts can gain a grasp of fundamentals, and experts also can find the book useful. - A solid introduction to kinetics - Material on computational quantum chemistry, an important new area for kinetics - Contains a chapter on construction of mechanisms, an approach only found in this book
Volumes 26 and 27 are both concerned with reactions occurring at electrodes arising through the passage of current. They provide an introduction to the study of electrode kinetics. The basic ideas and experimental methodology are presented in Volume 26, whilst Volume 27 deals with reactions at particular types of electrodes.Chapter 1 of the present volume deals with redox reactions at metal electrodes, Chapter 2 with semiconducting electrodes and Chapter 3 with reactions at metal oxide electrodes. Both theoretical aspects and experimental results are covered.
This book has been written by a group of mathematicians and chemists whose common interest is in the complex dynamics of catalytic reactions. Based on developments in mathematical chemistry, a general theory is described that allows the investigation of the relationships between the kinetic characteristics of complex reactions and their detailed reaction mechanism. Furthermore, a comprehensive analysis is made of some typical mechanism of catalytic reactions, in particular for the oxidation of carbon monoxide on platinum metals. In fact, the book presents three kinetics: (a) detailed, oriented to the elucidation of a detailed reaction mechanism according to its kinetic laws; (b) applied, with the aim of obtaining kinetic relationships for the further design of chemical reactors; and (c) mathematical kinetics whose purpose is the analysis of mathematical models for heterogeneous catalytic reactions taking place under steady- or unsteady-state conditions.
Liquid Phase Oxidation
Gas-Solid Reactions describes gas-solid reaction systems, focusing on the four phenomena—external mass transfer, pore diffusion, adsorption/desorption, and chemical reaction. This book consists of eight chapters. After the introduction provided in Chapter 1, the basic components of gas-solid reactions are reviewed in Chapter 2. Chapter 3 describes the reactions of individual nonporous solid particles, while Chapter 4 elaborates the reaction of single porous particles. Solid-solid reactions proceeding through gaseous intermediates are considered in Chapter 5. Chapter 6 deals with the experimental approaches to the study of gas-solid reaction systems. How information on single-particle behavior may be used for the design of multiparticle, large-scale assemblies, and packed- and fluidized-bed reaction systems is deliberated in Chapter 7. The last chapter covers the specific gas-solid reaction systems, including some statistical indices indicating the economic importance of the systems and processes it's based on. This publication is recommended for practicing engineers engaged in process research, development, and design in the many fields where gas-solid reactions are important.
There is an increasing challenge for chemical industry and research institutions to find cost-efficient and environmentally sound methods of converting natural resources into fuels chemicals and energy. Catalysts are essential to these processes and the Catalysis Specialist Periodical Report series serves to highlight major developments in this area. This series provides systematic and detailed reviews of topics of interest to scientists and engineers in the catalysis field. The coverage includes all major areas of heterogeneous and homogeneous catalysis and also specific applications of catalysis such as NOx control kinetics and experimental techniques such as microcalorimetry. Each chapter is compiled by recognised experts within their specialist fields and provides a summary of the current literature. This series will be of interest to all those in academia and industry who need an up-to-date critical analysis and summary of catalysis research and applications. Catalysis will be of interest to anyone working in academia and industry that needs an up-to-date critical analysis and summary of catalysis research and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr
This book aims to provide a straightforward introduction to chemical applications of the catastrophe theory. It is primarily intended for chemists interested in placing chemical reactions in the broader context of non-linear science, but it has a practical relevance for scientists in general. Catastrophe theory deals with those non-linear phenomena in which a continuous change in the control parameters results in a discontinuous alteration of a characteristic quantity of the system. The author discusses the origins of catastrophe theory, giving examples of occurrences in the areas of physics, chemistry and biology. Elementary theory and non-chemical applications are also described. The chemical kinetics and methods of analysis of chemical kinetic equations arising from elementary and generalized catastrophe theories are reviewed. Finally, the theory is applied to analyse and classify phenomena associated with the stability loss that may occur in chemical reactions. The book contains over 100 figures and an extensive subject index.