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Siloxanes belong to a group of substances used in a number of industrial applications and in consumer products such as additives in fuel, car polish, cleaners, anti foamiers and car waxes. Besides this, they are widely used in e.g. personal care and biomedical products. As a result of their wide use, siloxanes are presumably spread into the environment both via point sources and via diffuse sources and may be found in the environment. Recent studies have suggested that siloxanes may have direct or indirect toxic effects on various biological processes. The aim of this screening study was to obtain a snapshot of the occurrence of siloxanes in the Nordic environment. The here presented screening study involved six countries: Denmark, Faroe Islands, Finland, Iceland, Norway and Sweden. Sampled media types were air, biota, sediment, sludge, soil and water. Siloxanes were found in all the analysed samples types except soils. The results indicate that there is a general pollution of siloxanes in the Nordic environment, close to dense population and major sources. There was, however, a great variation in concentrations. The cyclic siloxanes occurred in all media in significantly higher concentrations than the linear siloxanes. At present, the observed concentrations are not alarmingly high, and many background sites seem to be non-contaminated. However, the use of siloxanes is extensive and it is possible that continued use will lead to increased environmental levels, eventually reaching effect concentrations.
Comprising 12 chapters, this book focuses on volatile methylsiloxanes (VMSs), the shorter-chained organosiloxanes, and reviews the main areas and environmental compartments where they have been found and studied. It opens with a detailed description of the structural and functional properties, toxic risks and possible transformations of VMSs in the environment and their main uses in various activities and products, as well as the identification of the main sources of emission. Further chapters examine the analytical strategies and protocols that have been used to address the quantification of VMSs, including the issue of possible cross-contaminations. The book also discusses the presence of VMSs in wastewater treatment plants (WWTPs) and in water bodies, their atmospheric fate and levels in biota, as well as occurrences of VMSs in remote areas of the world. It closes with a comprehensive conclusion and discussion on future directions for upcoming studies. This book is not intended as a finishing line, but rather as an important step towards improving our understanding of VMSs, to fuel new collaborations between research groups and/or with industry and lastly to convince more researchers to explore the mysteries of these ubiquitous, yet understudied, chemicals.
This volume offers an overview of the occurrence and distribution of personal care products in continental and marine waters, presents analytical methods and degradation technologies and discusses their impact on human health. Experts from different disciplines highlight major issues for each family of compounds related to their occurrence in the water column as well as in solid and biota samples, methodological strategies for their analysis, non-conventional degradation technologies, (eco)toxicity data and their human and environmental risk assessment. The book also includes a general introduction to personal care products, covering their properties, use, behaviour and regulatory framework, and a final chapter identifying knowledge gaps and future research trends. It will appeal to experts from various fields of research, including analytical and environmental chemistry, toxicology and environmental engineering.
Waterproof and Water Repellent Textiles and Clothing provides systematic coverage of the key types of finishes and high performance materials, from conventional wax and silicone, through controversial, but widely used fluoropolymers and advanced techniques, such as atmospheric plasma deposition and sol-gel technology. The book is an essential resource for all those engaged in garment development, production and finishing, and for academics engaged in research into apparel technology and textile science. Rapid innovation in this field is driving new performance demands in many areas, including the sporting and military sectors. However, another innovation driver is the regulatory framework in the USA, Europe and globally, addressing both health concerns (e.g. with PFOS / PFOA) and environmental impacts (e.g. C8 fluorocarbon finishes). Both of these aspects are fully covered, along with the replacement materials / technologies currently available and under development. In addition, oleophobic and multifunctional coatings are discussed, as are aspects of performance, testing and applications in sportswear, protective clothing, and footwear. - Introduces innovative materials and technologies, exploring their current and potential use across different sectors - Provides expert guidance on the health and environmental aspects of key waterproof materials and coatings and their associated regulations - Demystifies testing processes and design principles
This report describes a screening study of in all ninety-nine conventional and emerging per- and polyfluoroalkyl substances (PFASs) in the Nordic environment. In addition, extractable organic fluorine (EOF) was analysed. The latter can provide the amount, but not identity, of organofluorine in the samples, which in turn can be used to assess the mass balance between known and unknown PFASs. The study was initiated by the Nordic Screening Group and funded by these and the Nordic Council of Ministers through the Chemicals Group.A total of 102 samples were analyzed in this study, including bird eggs, fish, marine mammals, terrestrial mammals, surface water, WWTP effluents and sludge, and air. Samples were collected by institutes from the participating countries and self-governing areas; Denmark, Faroe Islands, Finland, Greenland, Iceland, Norway, and Sweden.
Marine Ecotoxicology: Current Knowledge and Future Issues is the first unified resource to cover issues related to contamination, responses, and testing techniques of saltwater from a toxicological perspective. With its unprecedented focus on marine environments and logical chapter progression, this book is useful to graduate students, ecotoxicologists, risk assessors, and regulators involved or interested in marine waters. As human interaction with these environments increases, understanding of the pollutants and toxins introduced into the oceans becomes ever more critical, and this book builds a foundation of knowledge to assist scientists in studying, monitoring, and making decisions that affect both marine environments and human health. A team of world renowned experts provide detailed analyses of the most common contaminants in marine environments and explain the design and purpose of toxicity testing methods, while exploring the future of ecotoxicology studies in relation to the world's oceans. As the threat of increasing pollution in marine environments becomes an ever more tangible reality, Marine Ecotoxicology offers insights and guidance to mitigate that threat. - Provides practical tools and methods for assessing and monitoring the accumulation and effects of contaminants in marine environments - Unites world renowned experts in marine ecotoxicology to deliver thorough and diverse perspectives - Builds the foundation required for risk assessors and regulators to adequately assess and monitor the impact of pollution in marine environments - Offers helpful insights and guidance to graduate students, ecotoxicologists, risk assessors, and regulators interested in mitigating threats to marine waters
Available online: https://pub.norden.org/temanord2022-519/ On behalf of the Nordic Council of Ministers’ Screening Group, NILU and NIVA performed a monitoring study on selected environmental contaminants, namely UV-filters, dechloranes, and chlorinated paraffins. UV-compounds were frequently detected in samples related to the marine food web. In the group of dechloranes, dechlorane 602 was detected most frequently in samples related to the marine, freshwater, and terrestrial food web. Short and medium chain chlorinated paraffins (SCCPs and MCCPs) were found in most of the samples, but long chain chlorinated paraffins (LCCPs) with a slightly lower detection frequency. For nearly all biota samples, the concentrations of MCCPs were higher than the SCCP concentrations. LCCP-concentrations were as high or higher than the SCCP-concentrations.