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A comprehensive treatment of producing ceramic, glass, and composite materials using chemistry-based processing methods. Synthesizes the most up-to-date research. Includes new areas of computer aided processing, molecular calculations of ceramic processing reactions, and chemical control of surface films. Contributions from over 115 experts in the field. Index.
Many believe that the silicon/information age is heading to the Age of Biology and that the next frontier in ceramics will most likely require molecular level or nanoscale control. What, then, is the role of ceramics in the age of biology? As we change from an energy-rich society to an energy-declining society, how can ceramic materials appease the
Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing presents the physical and chemical principles of the sol-gel process. The book emphasizes the science behind sol-gel processing with a chapter devoted to applications. The first chapter introduces basic terminology, provides a brief historical sketch, and identifies some excellent texts for background reading. Chapters 2 and 3 discuss the mechanisms of hydrolysis and condensation for nonsilicate and silicate systems. Chapter 4 deals with stabilization and gelation of sols. Chapter 5 reviews theories of gelation and examines the predicted and observed changes in the properties of a sol in the vicinity of the gel point. Chapter 6 describes the changes in structure and properties that occur during aging of a gel in its pore liquor (or some other liquid). The discussion of drying is divided into two parts, with the theory concentrated in Chapter 7 and the phenomenology in Chapter 8. The structure of dried gels is explored in Chapter 9. Chapter 10 shows the possibility of using the gel as a substrate for chemical reactions or of modifying the bulk composition of the resulting ceramic by performing a surface reaction (such as nitridation) on the gel. Chapter 11 reviews the theory and practice of sintering, describing the mechanisms that govern densification of amorphous and crystalline materials, and showing the advantages of avoiding crystallization before sintering is complete. The properties of gel-derived and conventional ceramics are discussed in Chapter 12. The preparation of films is such an important aspect of sol-gel technology that the fundamentals of film formation are treated at length in Chapter 13. Films and other applications are briefly reviewed in Chapter 14. Materials scientists and researchers in the field of sol-gel processing will find the book invaluable.
Ceramic powder synthesis and processing are two of the most important technologies in chemical engineering and the ceramics-related area of materials science. This book covers both the processing and the synthesis ofceramic powders in great depth and is indeed the only up-to-date, comprehensive source on the subject available.The application of modern scientific and engineering methods to the field of ceramic powder synthesis has resulted in much greater control of properties. Fundamentals of Ceramic Powder Processing and Synthesis presents examples of these modern methods as they apply to ceramic powders. The book is organized to describe the natural and synthetic raw materials that comprise contemporary ceramics. It covers the three reactant processes used in synthetic ceramic powder synthesis: solid, liquid, andgas.Ceramic powder processing, as a field of materials processing, is undergoing rapid expansion. The present volume is intended as a complete and useful source on this subject of great current interest. It provides comprehensive coverage from a strong chemistry and chemical engineering perspective and is especially applicable to materials scientists, chemical engineers, and applied chemists.Key Features* The most complete and updated reference source on the subject* Comprehensive coverage from a stron chemical engineering and chemistry perspective* Emphasis on both natural and synthetic raw materials in ceramic powder synthesis* Information on reaction kinetics* Superior, more comprehensive coverage than that in existing texts* Sample problems and exercises* Problems at the end of each chapter which supplement the material
Organic Additives and Ceramic Processing: With Applications in Powder Metallurgy, Ink, and Paint describes the major manufacturing processes, such as slip casting, tape casting, injection molding, etc. The book covers each subject, including the ceramic processes, organic chemical structures, polymers, colloid science and others, starting from fundamental principles, with many literature references for further reading. After the fundamentals, detailed case studies from industrial applications are described for the optimization of solvents, dispersants, binders, plasticizers, lubricants and some minor additives. A wide range of information is covered, beginning with fundamental equations for students, and extending to advanced applications for development workers and factory problem solvers. Shanefield undertook this ambitious task only because of the previous lack of resources that address the growing need for detailed information on organic additives for ceramics. Suitable for use as a textbook and as a reference source for working ceramists and chemists who wish to supply the ceramics industry with additives.
This book presents a broad, general introduction to the processing of Sol-Gel technologies. This updated volume serves as a general handbook for researchers and students entering the field. This new edition provides updates in fields that have undergone rapid developments, such as Ceramics, Catalysis, Chromatropgraphy, biomaterials, glass science, and optics. It provides a simple, compact resource that can also be used in graduate-level materials science courses.
Materials scientists continue to develop stronger, more versatile ceramics for advanced technological applications, such as electronic components, fuel cells, engines, sensors, catalysts, superconductors, and space shuttles. From the start of the fabrication process to the final fabricated microstructure, Ceramic Processing covers all aspects of modern processing for polycrystalline ceramics. Stemming from chapters in the author's bestselling text, Ceramic Processing and Sintering, this book gathers additional information selected from many sources and review articles in a single, well-researched resource. The author outlines the most commonly employed ceramic fabrication processes by the consolidation and sintering of powders. A systematic approach highlights the importance of each step as well as the interconnection between the various steps in the overall fabrication route. The in-depth treatment of production methods includes powder, colloidal, and sol-gel processing as well as chemical synthesis of powders, forming, sintering, and microstructure control. The book covers powder preparation and characterization, organic additives in ceramic processing, mixing and packing of particles, drying, and debinding. It also describes recent technologies such as the synthesis of nanoscale powders and solid freeform fabrication. Ceramic Processing provides a thorough foundation and reference in the production of ceramic materials for advanced undergraduates and graduate students as well as professionals in corporate training or professional courses.
This book provides fundamental knowledge of ceramics science and technology in a compact volume. Based on inorganic chemistry, it is intended as a reader for graduate students and young researchers beginning work in ceramics. The importance of the book is that it provides a scientific understanding of structure, properties, and processing from the chemical aspect, leading to creation of future ceramics. Ceramics have high hardness, strength, thermal and chemical stability, as well as various electromagnetic functions. To take full advantage of ceramics, their use has been advanced to engineering and electronic ceramics. Most ceramics have been fabricated by powder processing, and new technologies have also evolved such as CVD and sol-gel methods: new ceramics aimed at new functions of highly pure oxides and artificial nitrides, carbides, and borides; fine ceramics focused on precise control of composition and microstructure; and design of unique morphology, such as nanoparticles, nanofibers, nanosheets, mesoporous materials, and hybrids. Materials are composed of atoms and molecules. They are assembled into crystals and are amorphous, leading to 3-D micro/nano structures. In addition to the topics described above, this book shows the importance of chemistry for materials design at the nanometer scale, and that chemistry develops new fields of environment, energy, informatics, biomaterials, and other areas.
Ceramic Materials: Science and Engineering is an up-to-date treatment of ceramic science, engineering, and applications in a single, comprehensive text. Building on a foundation of crystal structures, phase equilibria, defects, and the mechanical properties of ceramic materials, students are shown how these materials are processed for a wide diversity of applications in today's society. Concepts such as how and why ions move, how ceramics interact with light and magnetic fields, and how they respond to temperature changes are discussed in the context of their applications. References to the art and history of ceramics are included throughout the text, and a chapter is devoted to ceramics as gemstones. This course-tested text now includes expanded chapters on the role of ceramics in industry and their impact on the environment as well as a chapter devoted to applications of ceramic materials in clean energy technologies. Also new are expanded sets of text-specific homework problems and other resources for instructors. The revised and updated Second Edition is further enhanced with color illustrations throughout the text.
Progress in Ceramic Science