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ABSTRACT: The new thioethers MeSi and Si have been synthesized with the goal of investigating the effect of the tert-butyl substituents on their structure and coordination chemistry. These tridentate or tetradentate ligands are new members of existing families of acyclic thioethers. Reactivity studies of these newly synthesized ligands were performed by coordinating them to group 6 metal carbonyl derivatives. These complexes have been compared with the group 6 metal complexes of other thioether ligands to determine the electronic and steric differences that the tert-butyl group may cause. Spectroscopic and X-ray diffraction studies were performed to determine those effects.
This dissertation, "Synthesis and Properties of Some Amine and Thioether Complexes of Ruthenium and Osmium" by Chi-ming, Che, 支志明, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3122986 Subjects: Ruthenium Osmium Complex compounds