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RUBBER TO RUBBER ADHESION Readers will get helpful ideas and in-depth knowledge about various aspects of rubber to rubber adhesion with particular reference to theory and practice. This book covers various aspects of rubber to rubber adhesion which is important theoretically, as well as having practical implications. Rubber is a polymer whose glass transition temperature is well below the room temperature and hence the chains are very mobile at room and higher temperatures, making the material very versatile. Rubber is used in a large number of applications ranging from underground mining to tire to space vehicles. In all these cases, compounded rubbers are used in laminates and joined. The higher the adhesion, the higher will be the joint strength. The principles taught in adhesion science and technology are extensively used to prepare better joints and more useful products. The book serves to satisfy a wide range of disciplines (polymers, materials, chemical, chemistry, mechanical, etc.) and starts with an introduction on rubber, then characterization of rubber, rubber surface and joints and, finally, other chapters on rubber to rubber adhesion. Scientific aspects to understand the technology are highlighted. It gives a comprehensive treatment on adhesion between unvulcanized elastomers, self-healing of elastomers, adhesion between compounded elastomers by co-crosslinking, adhesion between partially vulcanized compounded rubber and partially vulcanized compounded rubber, adhesion between vulcanized rubber and unvulcanized rubber- or partially vulcanized rubber, and adhesion between vulcanized rubber and vulcanized rubber. Audience The book will be used by academicians in polymer science, materials science, chemical and mechanical engineering, chemistry, R & D personnel, industry people, as well as rubber and adhesion practitioners.
Annotation. Many books and papers have been published on adhesion of materials in general but the topics covered by this book have been selected to cover a wide range of interests, both in terms of products and applications. Although there is some discussion of relevant theory in various sections of d104, the emphasis in this volume has been to concentrate on the practicalities of bonding of rubbers, to themselves and substrates. It is considered that this type of information is of immediate interest to the practising technologist dealing with shop floor problems on a daily basis.
Poly mer Interface and Adhesion provides the critical basis for further advancement in thisfield. Combining the principles of interfacial science, rheology, stress analysis, and fracturemechanics, the book teaches a new approach to the analysis of long standing problemssuch as: how is the interface formed; what are its physical and mechanical properties;and how does the interface modify the stress field and fracture strength of the material.The book offers many outstanding features, including extensive listings of pertinent references, exhaustive tabulations of the interfacial properties of polymers, critical reviews ofthe many conflicting theories, and complete discussions of coupling agents, adhesion promotion, and surface modifications. Emphasis is placed on physical concepts and mechanisms, using clear, understandable mathematics.Polymer Interface and Adhesion promotes a more thorough understanding of the physical, mechanical, and adhesive properties of multiphase, polymer systems. Polymer scientistsand engineers, surface chemists, materials scientists, rheologists, as well as chemical andmechanical engineers interested in the research, development or industrial applications ofpolymers, plastics, fibers, coatings, adhesives, and composites need this important newsource b
A solid collection of interdisciplinary review articles on the latest developments in adhesion science and adhesives technology With the ever-increasing amount of research being published, it is a Herculean task to be fully conversant with the latest research developments in any field, and the arena of adhesion and adhesives is no exception. Thus, topical review articles provide an alternate and very efficient way to stay abreast of the state-of-the-art in many subjects representing the field of adhesion science and adhesives. Based on the success of the preceding volumes in this series "Progress in Adhesion and Adhesives"), the present volume comprises 9 review articles published in Volume 6 (2018) of Reviews of Adhesion and Adhesives. The subject of these reviews fall into the following general areas: 1. Adhesion to wood and wood bonds 2. Adhesive joints 3. Adhesion in microelectronic packaging 4. Surface modification 5. Contact angle, wettability and surface free energy. The topics covered include: Adhesion phenomena in microelectronic packaging; adhesives for wood and lignocellulosic materials; adhesion to wood and lignocellulosic materials; adhesively bonded lap joints having bi-adhesive and modulus-graded bondlines; adhesion between compounded elastomers; applications of contact angle measurements in pharmaceuticals and foods; oxygen or ammonia plasma treatment of polyolefin surfaces; surface free energy determination of powders and particles; wood bonds; and dispersion adhesion forces between macroscopic objects.
The objectives of rubber compounding may be essentially defined as providing optimised performance and processability, generally at minimum cost, by the incorporation of non-rubber ingredients. Optimised performance in this context refers not only to mechanical properties but also, for example, resistance to bacteria or particular chemicals. In some applications a rubber may also need to be coloured, or bonded to another material, and further ingredients may be required. For many years, rubber compounding was largely empirical and frequently described as a black art. Today it is practised predominantly on the basis of scientific principles elucidated over years of study and is still the subject of intensive research. In this new report Claude Hepburn reviews the following range of compounding ingredients, considering the range of materials available, their particular actions and recent interesting advances: Process and extender oils; Process aids and surfactants; Coupling agents and adhesion promoters; Fire retardants, bactericides and blowing agents, colourants and odourants. An additional indexed section containing several hundred abstracts from the Polymer Library provides many more examples of novel materials and their applications.
In addition to technological advances pushing the development of adhesion and interfacial sciences, recent experimental and computational tools have helped to pull these areas forward. Novel spectroscopic techniques and improved equipment has led to a better understanding of bond formation and breaking upon contact and separation. In addition, the recent advances in computer technology have facilitated both the acquisition of data and the enhancement of theoretical understanding of adhesion and interfacial phenomena. Because of the rapid advances and importance of the fields of adhesion and interfacial sciences, a three-day symposium entitled ''Fundamentals of Adhesion and Interfaces'' was held in Chicago at the August 1993 meeting of the American Chemical Society. The papers in this volume are based on selected presentations given at this symposium. These papers were originally reviewed and published in two special issues of the Journal of Adhesion Science and Technology.
This section of industry is currently at a crossroads brought about by atmospheric anti-pollution legislation which restricts the choice of solvents, and this problem is addressed in his review with a discussion of new practices such as the use of water-based systems. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database provides useful references for further reading.
From weather-proof tires and artificial hearts to the o-rings and valve seals that enable successful space exploration, rubber is an indispensable component of modern civilization. Stiff competition and stringent application requirements foster continuous challenges requiring manufacturers to fund ever-expanding research projects. However, this vas
This review has been written as a practical approach to bonding various kinds of elastomers to substrates such as steel and plastics, as used in the manufacture of diverse products such as rubber covered rolls, urethane fork lift wheels, rubber lining for chemical storage or solid rocket motors, engine bushes and mounts, seals for transmissions, electrical power connectors and military tank track pads. Based on the authors' years of experience working closely with end-use customers and it offers a thorough overview of how to successfully bond rubber to a given substrate in the manufacture of quality rubber engineered components. This review is supported by an indexed section containing several hundred key references and abstracts selected from the Rapra Abstracts database.