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Teil B/1-2.
Ring-forming Polymerizations, Part A: Carbocyclic and Metallorganic Rings covers polymerization reactions that form carbocyclic rings and those that lead to metallorganic ring-containing structures. This book is organized into 11 chapters. The first four chapters describe ring-forming polymerizations that lead to the formation of homocyclic carbon-containing rings. These chapters specifically examine Diels-Alder polymerizations and certain diisopropenyl monomers polymerization yielding high molecular weight polyindanes. Chapter V is an introduction to polymers from metals and unsaturated carbon compounds, which has been called a ""natural coordination polymer"". Chapters VI to X deal with metallorganic ring polymers formed by chelation and are arranged according to the elements in the ligands that are affecting chelation. The final chapter explores ring forming polymerizations that yield polysiloxanes, polysilazanes, and certain polymetalloxanes. This book will be of value to organic chemists and researchers, as well as to organic chemistry teachers and students.
For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.
Ring-Forming Polymerizations, Part B, 1: Heterocyclic Rings presents a comprehensive review and compilation of ring-forming polymerization reactions that proceed with the formation of heterocyclic rings. Emphasis is placed on polymerizations leading to linear, high molecular weight products. This book is comprised of three chapters and begins with a discussion on polymerizations that result in the formation of a multiple bond containing at least one heteroatom. The condensation of amines with carbonyl compounds to yield poly(Schiff bases) and related polymers is examined, along with other carbon-nitrogen double bond-forming polymerizations. The next chapter is devoted to the polymerization of rings containing two carbon atoms, including the polymerization of polyphenols with diboronic acids and that of diisocyanides with triorganoborons. The last chapter describes the polymerization of rings containing three carbon atoms, with particular reference to polyisoxazoles and related polymers, polythiazoles, polyimidazoles and related polymers, polypyrazoles, and polytriazines. This monograph will be of interest to polymer and organic chemists and others who are concerned with the polymer chemistry of living systems.
Ring-forming Polymerizations is a part of a volume that features a complete review and compilation of ring-forming polymerization reactions that result to heterocyclic ring formation. This book shows relevant growth in terms of research and commercial development in the area of polymer chemistry. This volume is comprised of four major chapters and is organized according to the specific heterocyclic ring structure resulting from ring-forming polymerizations. Each of the chapters is arranged further according to the polymer type and the different methods used in the preparation of that type, where emphasis is given to synthetic methods. This book specifically discusses the linear polymers that were intentionally made. Also, the structures presented are limited in scope considering that they are the result of the research cited in this book. However, claims that dispute a certain structure found in the research are also included to provide balance, fairness, and objectivity. Specifically, this book is a valuable resource for polymer and organic chemists. However, it can also be of great use to those scientists and researchers interested in the study of polymer chemistry of living systems.
Like so many of its kind, this textbook originated from the requirements of teaching. While lecturing on macromolecular science as a required subject for chemists and materials scientists on the undergraduate, graduate, and postgraduate levels at Swiss Federal Institute of Technology at Zurich (1960-1971), I needed a one-volume textbook which treated the whole field of macromolecular science, from its chemistry and physics to its applications, in a not too elementary manner. This textbook thus intends to bridge the gap between the often oversimplified introductory books and the highly specialized texts and monographs that cover only parts of macromolecular science. This first English edition is based on the third German edition (1975), which is about 40% different from the first German edition (1971), a result of rapid progress in macromolecular science and the less rapid education of the writer. This text intends to survey the whole field of macromolecular science. Its organization results from the following considerations. The chemical structure of macromolecular compounds should be independent of the method of synthesis, at least in the ideal case. Part I is thus concerned with the chemical and physical structure of macro molecules. Properties depend on structure. Solution properties are thus discussed in Part II, solid state properties in Part III. There are other reasons for discussing properties before syntheses: For example, it is difficult to under stand equilibrium polymerization without knowledge of solution thermody of the glass temperature, etc.
Teil B/1-2.
Includes subject section, name section, and 1968-1970, technical reports.