Download Free Removal Of Inorganic Contaminants And Natural Organic Matter By Enhanced Alum Coagulation Book in PDF and EPUB Free Download. You can read online Removal Of Inorganic Contaminants And Natural Organic Matter By Enhanced Alum Coagulation and write the review.

The removal of inorganic contaminants is a primary concern in drinking water treatment. Fluoride and arsenic both naturally occur in ground and surface waters throughout the world. Recent health concerns regarding extended exposure to high levels of fluoride in drinking water have prompted the United States Environmental Protection Agency (USEPA) to review the fluoride maximum contaminant level (MCL). Arsenic is one of the most well-known and toxic inorganic contaminants regulated by the USEPA. While typically associated with groundwater, arsenic could be an increasing concern for surface water sources in the future. Small water systems may not have the resources to adjust their treatment scheme to accommodate a lower fluoride MCL or target arsenic removal. In this study, enhanced alum coagulation was investigated as a treatment strategy for both fluoride and arsenic. Facilities with surface water sources face a particular challenge, as the presence of natural organic matter (NOM) may interfere with the removal of fluoride and/or arsenic during coagulation. This work builds upon previous investigation of the interactions between fluoride, NOM, and aluminum during coagulation by comparing two pilot studies in Texas and Colorado. Each pilot study confirmed that enhanced alum coagulation was able to remove fluoride during continuous flow experiments using natural source water; the comparison of the studies revealed that source water composition impacts the maximum efficacy of alum coagulation for fluoride removal. A higher influent organic concentration appears to reduce the maximum efficacy of fluoride removal. However, the use of pH control may also be a contributing factor to the discrepancy in fluoride removal between pilot studies. The pilot study with a lower maximum fluoride removal had a higher influent DOC concentration, but was run without pH control. Synthetic water jar testing confirmed the ability of alum coagulation to remove arsenic (V). A maximum arsenic removal of 99% was observed for As(V) at alum doses of 100 mg/L and above, and an alum dose of 20 mg/L achieved an As(V) removal of 97%. Aluminum residuals suggest that the presence of As(V) lowers the point of zero charge for aluminum hydroxide solid.
Coagulation and Flocculation in Water and Wastewater Treatment provides a comprehensive account of coagulation and flocculation techniques and technologies in a single volume covering theoretical principles to practical applications. Thoroughly revised and updated since the 1st Edition it has been progressively modified and increased in scope to cater for the requirements of practitioners involved with water and wastewater treatment. A thorough gamut of treatment scenarios is attempted, including turbidity, color and organics removal, including the technical aspects of enhanced coagulation. The effects of temperature and ionic content are described as well as the removal of specific substances such as arsenic and phosphorus. Chemical phosphorus removal is dealt with in detail, Rapid mixing for efficient coagulant utilization, and flocculation are dealt with in specific chapters. Water treatment plant waste sludge disposal is dealt with in considerable detail, in an Appendix devoted to this subject. Invaluble for water scientists, engineers and students of this field, Coagulation and Flocculation in Water and Wastewater Treatment is a convenient reference handbook in the form of numerous examples and appended information.
This monograph provides comprehensive coverage of technologies which integrate adsorption and biological processes in water and wastewater treatment. The authors provide both an introduction to the topic as well as a detailed discussion of theoretical and practical considerations. After a review of the basics involved in the chemistry, biology and technology of integrated adsorption and biological removal, they discuss the setup of pilot- and full-scale treatment facilities, covering powdered as well as granular activated carbon. They elucidate the factors that influence the successful operation of integrated systems. Their discussion on integrated systems expands from the effects of environmental to the removal of various pollutants, to regeneration of activated carbon, and to the analysis of such systems in mathematical terms. The authors conclude with a look at future needs for research and develoment. A truly valuable resource for environmental engineers, environmental and water chemists, as well as professionals working in water and wastewater treatment.
Some community water systems using sources containing elevated levels of fluoride, in the United States and worldwide, struggle to treat their drinking water to healthy fluoride concentrations. Many treatment plants in the U.S. currently use aluminum based salts, such as aluminum sulfate and polyaluminium chloride, as coagulants during conventional treatment for removal of particles from drinking water sources. Moreover, enhanced aluminum sulfate, or alum, coagulation requires higher concentrations of aluminum added to the process and has been shown to be effective for removal of disinfectant byproduct precursors, i.e., natural organic matter (NOM). The presence of fluoride may interfere with the formation of aluminum hydroxide precipitates, and interrelationships among NOM, aluminum precipitation and fluoride removal are not well understood. A fundamental understanding of how fluoride alters the properties of aluminum precipitates and how fluoride and NOM molecules compete as ligands interacting with soluble aluminum species is lacking. As a result, the development of guidelines for implementation and optimization of a treatment scheme that uses aluminum in the presence of fluoride requires a multi-faceted approach in which the development of a mechanistic understanding of these interactions is conducted in concert with macroscopic experiments to identify optimum conditions for simultaneous removal of fluoride and NOM. To date, little research has looked at the efficiency of removing both fluoride and organics from the perspective of the precipitation process. To provide a foundation for revising treatment techniques, this research evaluated the effect of co-precipitating aluminum in the presence of fluoride, organics, and in multi-ligand systems to characterize the solid precipitate and removal competition. This research verified the formation of a co-precipitate in the presence of fluoride and certain low molecular weight organics. Co-precipitation from organics and fluoride competes for removal, especially at low alum coagulant doses, complicating treatment for resource limited areas.
Natural Organic Matter in Water: Characterization, Treatment Methods, and Climate Change Impact, Second Edition focuses on advanced filtration and treatment options, as well as processes for reducing disinfection by-products, making it an essential resource on the latest breakthroughs in the characterization, treatment and removal of natural organic matter (NOM) from drinking water. Based on the editor’s years of research and field experience, the book covers general parameters, isolation and concentration, fractionation, composition and structural analysis, and biological testing, along with removal methods such as inorganic coagulants, polyelectrolytes and composite coagulants. In addition, sections cover electrochemical and membranes removal methods such as electrocoagulation, electrochemical oxidation, microfiltration and ultrafiltration, nanofiltration, and membrane fouling. This book is a valuable guide for engineers and researchers looking to integrate methods, processes and technologies to achieve desired affects. Provides a summary of up-to-date information surrounding NOM Presents enhanced knowledge on treatment strategies for the removal of NOM Covers conventional as well as advanced NOM removal methods
Approximately 77 percent of the freshwater used in the United States comes from surface-water sources and is subject to natural organic matter contamination according to the United States Geological Survey. This presents a distinct challenge to water treatment engineers. An essential resource to the latest breakthroughs in the characterization, treatment and removal of natural organic matter (NOM) from drinking water, Natural Organic Matter in Waters: Characterization and Treatment Methods focuses on advance filtration and treatment options, and processes for reducing disinfection byproducts. Based on the author’s years of research and field experience, this book begins with the characterization of NOM including: general parameters, isolation and concentration, fractionation, composition and structural analysis and biological testing. This is followed by removal methods such as inorganic coagulants, polyelectrolytes and composite coagulants. Electrochemical and membranes removal methods such as: electrocoagulation, electrochemical oxidation, microfiltration and ultrafiltration, nanofiltration and membrane fouling. Covers conventional as well as advanced NOM removal methods Includes characterization methods of NOM Explains removal methods such as: removal by coagulation, electrochemical, advanced oxidation, and integrated methods