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Relaxation phenomena of excited molecular states are abundant in all nature. They mediate such key processes as photochemical reactions or even the pathways of ordinary chemical reactions. However, for a long time the main research in electronic relaxation processes was concerned with anorganic solids, in part because of their great technological importance (photography, semiconductors ... ) in part also because these compounds were the "workhorses" of the solid state physicists. In the last 30 years, there was a steadily increasing interest in organic molecular systems, first in molecular crystals and later in all forms of molecular solids (glasses, polymers, membranes, ... ). The present volume combines papers on quite different types of relaxation phenomena: the type of solid studied, the electronic states involved, the physical processes responsible for the relaxations are all different. Nevertheless, after reading this book, a more clear and complete picture of the phenomenon "relaxa tion" emerges that proves that this volume is more than just a collection of individual articles. The volume starts with the paper "Spin-lattice and spin-spin relaxation in photo-excited triplet states in molecular crystals" by Jan Schmidt. Even in these seemingly simple systems of isolated guest molecules in a single crystal host, the relaxation phenomena are quite involved and a very thorough investigation is necessary to find the key relaxation processes. The end of the article provides a bridge to the following paper: it treats interactions of two molecules (dimers), where resonant interactions become important and lead to new, characteristic relaxation processes.
The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students
The handbook comprehensively covers the field of inorganic photochemistry from the fundamentals to the main applications. The first section of the book describes the historical development of inorganic photochemistry, along with the fundamentals related to this multidisciplinary scientific field. The main experimental techniques employed in state-of-art studies are described in detail in the second section followed by a third section including theoretical investigations in the field. In the next three sections, the photophysical and photochemical properties of coordination compounds, supramolecular systems and inorganic semiconductors are summarized by experts on these materials. Finally, the application of photoactive inorganic compounds in key sectors of our society is highlighted. The sections cover applications in bioimaging and sensing, drug delivery and cancer therapy, solar energy conversion to electricity and fuels, organic synthesis, environmental remediation and optoelectronics among others. The chapters provide a concise overview of the main achievements in the recent years and highlight the challenges for future research. This handbook offers a unique compilation for practitioners of inorganic photochemistry in both industry and academia.
New organic compounds with interesting and improved electronic and photonic properties are being reported on a daily basis, with new light-triggered materials being designed for molecular and bioelectronic devices. The relatively new concept of molecular photonics embraces photochemistry and photophysics, dealing with light-induced changes in materials and their electronic states as well as the field of optics. This volume begins with a background and survey of current light-related research fields, moving on to the fundamentals of molecular photonics. Subsequent chapters deal with the characteristics of photochemical reaction and typical processes of photophysical chemistry, while the last two chapters focus on the study of materials-induced changes in light. The most important concepts are summarized in overview tables to promote active understanding of new topics. .
The presence of nanomaterials, whether designed for photochemistry or not, can have dramatic impacts on environmental, plant, and animal systems. In order to fully utilize nanomaterials for photochemical and other applications, it is necessary to design and manage them in a way that avoids undesirable or unexpected consequences. To provide a solid foundation, this book covers basic principles of photochemistry and fundamentals of nanomaterials and then provides insight into photochemical based nanomaterial applications and environmental behavior of nanomaterials.
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