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Electrolytes for Lithium and Lithium-ion Batteries provides a comprehensive overview of the scientific understanding and technological development of electrolyte materials in the last several years. This book covers key electrolytes such as LiPF6 salt in mixed-carbonate solvents with additives for the state-of-the-art Li-ion batteries as well as new electrolyte materials developed recently that lay the foundation for future advances. This book also reviews the characterization of electrolyte materials for their transport properties, structures, phase relationships, stabilities, and impurities. The book discusses in-depth the electrode-electrolyte interactions and interphasial chemistries that are key for the successful use of the electrolyte in practical devices. The Quantum Mechanical and Molecular Dynamical calculations that has proved to be so powerful in understanding and predicating behavior and properties of materials is also reviewed in this book. Electrolytes for Lithium and Lithium-ion Batteries is ideal for electrochemists, engineers, researchers interested in energy science and technology, material scientists, and physicists working on energy.
In this book, the development of next-generation batteries is introduced. Included are reports of investigations to realize high energy density batteries: Li-air, Li-sulfur, and all solid-state and metal anode (Mg, Al, Zn) batteries. Sulfide and oxide solid electrolytes are also reviewed.A number of relevant aspects of all solid-state batteries with a carbon anode or Li-metal anode are discussed and described: The formation of the cathode; the interface between the cathode (anode) and electrolyte; the discharge and charge mechanisms of the Li-air battery; the electrolyte system for the Li-air battery; and cell construction. The Li-sulfur battery involves a critical problem, namely, the dissolution of intermediates of sulfur during the discharge process. Here, new electrolyte systems for the suppression of intermediate dissolution are discussed. Li-metal batteries with liquid electrolytes also present a significant problem: the dendrite formation of lithium. New separators and electrolytes are introduced to improve the safety and rechargeability of the Li-metal anode. Mg, Al, and Zn metal anodes have been also applied to rechargeable batteries, and in this book, new metal anode batteries are introduced as the generation-after-next batteries.This volume is a summary of ALCA-SPRING projects, which constitute the most extensive research for next-generation batteries in Japan. The work presented in this book is highly informative and useful not only for battery researchers but also for researchers in the fields of electric vehicles and energy storage.
Battery technology is constantly changing, and the concepts and applications of these changes are rapidly becoming increasingly more important as more and more industries and individuals continue to make “greener” choices in their energy sources. As global dependence on fossil fuels slowly wanes, there is a heavier and heavier importance placed on cleaner power sources and methods for storing and transporting that power. Battery technology is a huge part of this global energy revolution. Zinc batteries are an advantageous choice over lithium-based batteries, which have dominated the market for years in multiple areas, most specifically in electric vehicles and other battery-powered devices. Zinc is the fourth most abundant metal in the world, which is influential in its lower cost, making it a very attractive material for use in batteries. Zinc-based batteries have been around since the 1930s, but only now are they taking center stage in the energy, automotive, and other industries. Zinc Batteries: Basics, Developments, and Applicationsis intended as a discussion of the different zinc batteries for energy storage applications. It also provides an in-depth description of various energy storage materials for Zinc (Zn) batteries. This book is an invaluable reference guide for electrochemists, chemical engineers, students, faculty, and R&D professionals in energy storage science, material science, and renewable energy.
Here in a single source is an up-to-date description of the technology associated with the Li-Ion battery industry. It will be useful as a text for researchers interested in energy conversion for the direct conversion of chemical energy into electrical energy.
Emerging Nanotechnologies in Rechargeable Energy Storage Systems addresses the technical state-of-the-art of nanotechnology for rechargeable energy storage systems. Materials characterization and device-modeling aspects are covered in detail, with additional sections devoted to the application of nanotechnology in batteries for electrical vehicles. In the later part of the book, safety and regulatory issues are thoroughly discussed. Users will find a valuable source of information on the latest developments in nanotechnology in rechargeable energy storage systems. This book will be of great use to researchers and graduate students in the fields of nanotechnology, electrical energy storage, and those interested in materials and electrochemical cell development. - Gives readers working in the rechargeable energy storage sector a greater awareness on how novel nanotechnology oriented methods can help them develop higher-performance batteries and supercapacitor systems - Provides focused coverage of the development, process, characterization techniques, modeling, safety and applications of nanomaterials for rechargeable energy storage systems - Presents readers with an informed choice in materials selection for rechargeable energy storage devices
This book updates the latest advancements in new chemistries, novel materials and system integration of rechargeable batteries, including lithium-ion batteries and batteries beyond lithium-ion and addresses where the research is advancing in the near future in a brief and concise manner. The book is intended for a wide range of readers from undergraduates, postgraduates to senior scientists and engineers. In order to update the latest status of rechargeable batteries and predict near research trend, we plan to invite the world leading researchers who are presently working in the field to write each chapter of the book. The book covers not only lithium-ion batteries but also other batteries beyond lithium-ion, such as lithium-air, lithium-sulfur, sodium-ion, sodium-sulfur, magnesium-ion and liquid flow batteries.
This expert volume addresses the practical challenges which have so far inhibited the commercial realization of a rechargeable magnesium battery, placing the discussion within the context of the already established lithium-ion battery. Lithium-ion batteries are becoming commonplace in most power applications, starting with portable electronics and expanding to motor vehicles, stationary storage, and backup power. Since their introduction 25 years ago, they have slowly been replacing all other battery chemistries. As the technology has matured, it is nearing its theoretical limits in terms of energy density, so research and development worldwide is quickly shifting towards the study of new battery chemistries with cheaper components and higher energy densities. A very popular battery candidate which has generated a lot of recent interest is the magnesium rechargeable battery. Magnesium is five orders of magnitude more abundant than lithium, can move two electrons per cation, and is known to plate smoothly without any evidence of dendritic growth. However, many challenges remain to be overcome. This essential volume presents an unfiltered view on both the realistic promises and significant obstacles for this technology, providing key insights and proposed solutions.
This practical reference remains the most comprehensive guide to the fundamental theories, techniques, and strategies used for battery operation and design. It includes new and revised chapters focusing on the safety, performance, quality, and enhancement of various batteries and battery systems. From automotive, electrochemical, and high-energy applications to system implementation, selection, and standardization, the Second Edition presents expert discussions on electrochemical energy storage, the advantages of battery-powered traction, the disposal and recycling of used batteries, hazard prevention, and the chemistry and physics of lithium primary batteries.
Over-consumption of fossil fuels has caused deficiency of limited resources and environmental pollution. Hence, deployment and utilization of renewable energy become an urgent need. The development of next-generation rechargeable batteries that store more energy and last longer has been significantly driven by the utilization of renewable energy.This book starts with principles and fundamentals of lithium rechargeable batteries, followed by their designs and assembly. The book then focuses on the recent progress in the development of advanced functional materials, as both cathode and anode, for next-generation rechargeable batteries such as lithium-sulfur, sodium-ion, and zinc-ion batteries. One of the special features of this book is that both inorganic electrode materials and organic materials are included to meet the requirement of high energy density and high safety of future rechargeable batteries. In addition to traditional non-aqueous rechargeable batteries, detailed information and discussion on aqueous batteries and solid-state batteries are also provided.