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Zeolites and related microporous materials are used in oil processing and in the fine and petrochemical industries on a large scale. New applications of zeolites contribute to environmentally friendly processes and refined zeolites such as catalytic zeolite membranes and zeolites containing exhaust-pipe reactors are being introduced. Recent diversity in zeolite research has been fueled by the increase in number of microporous materials and the combination with interfacing science areas. The possibility to accommodate ions, large molecules or nanostructures in the crystalline matrix has been explored and the performance of electronic, acoustic and photonic modified response of the materials has been tested.This volume provides up-to-date information on new zeolite and related materials and composites, their applications, testing of new processes and techniques, and promising laboratory results as well. A vast amount of work from a fundamental aspect is incorporated. In particular, the combination of science and application offers useful information for readers interested in molecular sieves.
Zeolites and Zeolite-like Materials offers a comprehensive and up-to-date review of the important areas of zeolite synthesis, characterization, and applications. Its chapters are written in an educational, easy-to-understand format for a generation of young zeolite chemists, especially those who are just starting research on the topic and need a reference that not only reflects the current state of zeolite research, but also identifies gaps and opportunities. The book demonstrates various applications of zeolites in heterogeneous catalysis and biomass conversion and identifies the endless possibilities that exist for this class of materials, their structures, functions, and future applications. In addition, it demonstrates that zeolite-like materials should be regarded as a living body developing towards new modern applications, thereby responding to the needs of modern technology challenges, including biomass conversion, medicine, laser techniques, and nanomaterial design, etc. The book will be of interest not only to zeolite-focused researchers, but also to a broad scientific and non-scientific audience. - Provides a comprehensive review of the literature pertaining to zeolites and zeolite-like materials since 2000 - Covers the chemistry of novel zeolite-like materials such as Metal-Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), hierarchical zeolite materials, new mesoporous and composite zeolite-like micro/mesoporous materials - Presents essential information of the new zeolite-like structures, with a balanced coverage of the most important areas of the zeolite research (synthesis, characterization, adsorption, catalysis, new applications of zeolites and zeolite-like materials) - Contains chapters prepared by known specialists who are members of the International Zeolite Association
Interest in zeolites continues to grow, making it vital to keep up to date with recent findings. These proceedings include some of the latest discoveries in the zeolite field. Four plenary lectures provide in-depth coverage of key topics, namely the influence of diffusion on catalysis, recent advances in synthesis, modification of zeolites by alumination, and quantum chemical studies of acidity. These are followed by nineteen papers written by contributors from all over the world covering a wide range of material of current interest. Several synthetic studies are presented, including the introduction of heteroatoms to induce higher catalytic acidity. Acidity and catalysis are probed by solid-state NMR and discussed through theoretical calculations. Two papers are concerned with the growing interest in using zeolites to catalyze shape-selective organic reactions. There are specific studies of zeolite characterization by NMR and electron energy loss spectroscopy. There are also a number of quantum chemical papers on zeolite stability and on the location of adsorbed species.The material presented is particularly up-to-date and will be of considerable interest to all research groups involved in zeolite sciences.
Recent Advances in Science and Technology of Zeolites and Related Materials is a collection of oral and poster communications, presented during the 14th International Zeolite Conference (IZC). The conference was hosted by the Catalysis Society of South Africa. In the tradition of the IZC series, this Conference provides a forum for the presentation of new knowledge in the science and technology of zeolites and related materials. Papers presented cover a wide range of topics that include synthesis, structure determination, characterisation, modelling, and catalysis. This highly visual book is a must for readers looking to stay up-to-date on zeolite science. * This three-part volume provides valuable information on zeolites and related materials* Includes papers that cover topics such as structure determination, modelling and separation processes* Contains new and exciting developments in the field
This volume was conceived as a handbook for the Pre-Conference Summer School on Zeolites, held in Taejon, Korea. The 11th IZC Summer School was organized to acquaint those already actively working in zeolite science and technology with the latest developments and to develop new prospects of zeolite science and technology for the 21st century.The aim of this volume is to give an extensive review and analysis of the important new findings of the last 10 years on the synthesis, characterization and applications of zeolite materials as well as the prediction of new R&D directions for the next decade.
The Handbook of Zeolite Science and Technology offers effective analyses ofsalient cases selected expressly for their relevance to current and prospective research. Presenting the principal theoretical and experimental underpinnings of zeolites, this international effort is at once complete and forward-looking, combining fundamental
Zeolites have been the focus of intensive activity and growth in applications over the past 25 years in ion exchange, in adsorp tion and in catalytic process technology. Beginning with the syn thetic zeolites A,X and Y, continuing into the emerging ZSM series, and including selected natural zeolites, applications span the range from large-scale purification and separation to such major petroleum and petrochemical processes as catalytic cracking and aromatics alkylation. The future promises several new areas of signiciant use as our energy resource base is expanded. As a result, a NATO Advanced Study Institute on Zeolites was held in Alcabideche, Portugal, May 1-12, 1983. Its purpose was to summarize the state-of-the-art in zeolite science and technology, with particular emphasis on recent developments. This summary is intended to complement presentations of the latest research results at the 1983 International Zeolites Association meeting in .Reno, Nevada - USA. Both the fundamentals concepts and industrial applications are addressed in the lectures of the Institute. Individual chapters cover historical development, structure, crystallography and synthesis techniques. Basic principles of adsorption, diffusion, ion exchange and acidity are reviewed. A section on catalysis addresses shape selectivity, transition metals, bifunctional catalysis and "methanol to-gasoline". Included in the section on industrial applications are chapters on reactor and adsorber design, catalytic cracking, xylene and n -paraffins isomerization, as well as ion exchange and adsorption.
Zeolite is a mineral that consists mainly of aluminosilicate, and its major commercial use is as a surfactant. Over the last decade, significant efforts have been devoted to the development of micro-mesoporous zeolite materials, which are also referred to as mesostructured zeolites. Zeolites show potential as heterogeneous catalysts for terpenes valorisation into fragrances and flavours, replacing the homogenous catalysts. The results of research on of zeolite catalysts for selective reduction of nitrogen oxides by C1-C4-hydrocarbons and ethanol are demonstrated, in particular, the selective reduction activity of Ag/BEA catalysts. The authors also explore the synthesis of hierarchical zeolites uzing green templates such as natural polymers, surfactants and biological agents, as traditional templates are expensive and toxic. The recent developments in dehydration of organics, organic/organic separation, desalination and gas separation using zeolite membranes are reviewed in detail. Studies on the synthesis of zeolites in alkali-activated materials and the physicochemical changes of alkali-activated materials induced by these zeolites are presented. Due to their stability, form selectivity, non-corrosiveness, and environmental compatibility, zeolites are suggested as a suitable option for the thermal catalytic cracking process. The authors provide fundamental research data on the Cuban zeolite in Detoxsan®, including its different medical applications in comparison to the available literature regarding the medical use of zeolites.
These proceedings reflect recent developments in the field of zeolite chemistry and catalysis with an emphasis on the role of a modifying component on the properties of the molecular sieve material. The plenary lectures and contributed papers concentrate on the problem of isomorphous substitution in a zeolitic framework; on the occlusion and the structure of metal, metal oxide, and metal sulphide clusters and complexes in the intracrystalline void volume of molecular sieves and zeolites as well as in the interlaminar space of layered compounds.Catalytic applications are discussed, not only in regard to traditional hydrocarbon transformation, but also in such areas as: reduction of SO2, decomposition of NO, reactions of sulphur containing compounds and conversion of CO, CO2 to hydrocarbons or of alcohols to oxygenated products.Because the book provides valuable data and information on new achievements in the zeolite material science and application, it will be of considerable interest to all research groups involved in zeolite science.
Accessible references for researchers and industrialists in this exciting field, covering both developments and applications of catalysis.