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Twenty years after the discovery of a quasicrystalline compound, the field of quasicrystals still raises interest and is continuously evolving. Quasicrystals display properties different from conventional crystals with small unit cells and present interesting potential for industrial purposes. This book offers an updated look into the field of quasicrystalline research. For example, a report on electrodeposited Al-Cu-Fe quasicrystals shows great promise for industry. It is also demonstrated that when Al-Cu-Fe quasicrystals are used as catalysts, in particular at high temperatures, such quasicrystals outperform conventional industrial catalysts. A new class of quasicrystal, based on a novel type of local order differing from previously observed Mackay- and Bergman-type quasicrystals, is featured. A detailed description of layer-by-layer growth of a Cu film on a quasicrystalline surface is also provided. Additional topics include: synthesis and structure; transport properties; electronic properties; mechanical properties; quasicrystals from metallic glasses; surfaces and coatings; and applications and hydrogen storage.
The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.
The measure of a thermoelectric material is given by the material's figure of merit. For over three decades the best thermoelectric materials had a ZT = 1. Recently, however, there are reports of new methods of materials synthesis that result in improvements beyond this performance. In addition, rapid characterization, as well as faster theoretical modeling of thermoelectric materials, has resulted in a more rapid evaluation of new materials. This book offers a look at these results and provides a benchmark for the current state in the field of thermoelectric materials research and development. The focus is on new and innovative directions that will lead to the next generation thermoelectric materials for small-scale refrigeration and power generation applications. The book emphasizes the multidisciplinary nature of the research needed to advance the science and technology of the field. Both theoretical and experimental studies are featured. Topics include: low-dimensional systems and nanocomposites; devices; oxides; skutterudites; complex bulk materials and measurements; novel approaches; and thermoelectric materials and technology.
The aim of this book is to acquaint the reader with what the authors regard as the most basic characteristics of quasicrystals -- structure, formation and stability, and properties -- in relationship with the applications of quasicrystalline materials. Quasicrystals are fascinating substances that form a family of specific structures with strange physical, chemical and mechanical properties as compared to those of metallic alloys. This, on the one hand, requires a generalization of the crystallographic description of solids and is still stimulating intensive research to understand the most basic properties of quasicrystals. On the other hand, these properties open the way to technological applications, demonstrated or potential, mostly regarding energy savings. This valuable book discusses those various facets of quasicrystals in six chapters, ending with the authors' own interpretation of the properties with respect to their unique structure.
The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.
Covering fundamental research as well as real-world applications, this first book on CMAs at an introductory level treats everything from atomistic details to surface processing. Comprehensive, self-contained chapters provide readers with the latest knowledge on the most salient features of the topic, selected in terms of their relevance to potential technological applications. Edited by one of the most distinguished authorities on quasicrystals and this most important of their subclasses, the contributions elucidate aspects of CMAs from a particular viewpoint: physical and chemical characteristics in the sub-nanometer regime, mesoscale phenomena, preparation and processing of thin films, and large-scale engineering properties. The whole is rounded off by a look at the commercial potential of CMA-based applications. For PhD students and lecturers alike.
The availability of materials that can bind selectively to a target molecule is the key to unlocking a host of new technologies. Molecular imprinting is an established technology, which allows the synthesis of materials containing highly specific receptor sites having an affinity for a target compound. For example, molecularly imprinted materials can mimic some of the functions of enzymes through the creation of three-dimensional cavities of specific size and shape for biorecognition of bioactive compounds. This volume offers a forum for technical exchange among members of the worldwide community of scientists and engineers who work in the area of molecular imprinting. Researchers from academia, government and industry present results in applications of molecular imprinting related to catalysis, combinatorial and computational methods, new monomers and recognition strategies, sensors, drug discovery and therapy, and new molecular imprinting formats.
This book focuses on recent advances in nanostructured and nanophase materials and their applications. Nanostructured materials consist of domains of less than 100nm and include atom clusters and cluster assemblies, one- and two-dimensionally modulated layers and three-dimensional structures. The term 'nanophase' refers to structures comprised of domains or particles of a single material that are typically less than 100nm, whereas 'nanocomposite' refers to a composite of more than one nanophase. Nanoscale materials can be engineered as homogeneous or porous ceramics, metals, metal oxides, semiconductors, organic polymers, or as composite materials containing these components. This book brings together scientists from many disciplines to share and discuss advances in the field. Topics include: nanophase materials; nanocomposite materials; nanoporous materials; nanostructured materials; applications and properties of nanostructured materials; carbon nanotubes; nanostructured thin films and coatings; and theoretical and modeling studies of nanostructured materials.
The advent of nanomaterials has introduced a new dimension in applications of energetic and reactive materials. A fundamental understanding of their synthesis mechanisms, atomic- and molecular-scale structural characteristics, and an evaluation of properties combined with modeling of the limits to those properties are required to realize the full potential of energetic and reactive nanomaterials. Many techniques have been recently developed that make it possible to exploit the benefits of the "nano" structure and design materials with desired energy release rates and energy densities, while they also improve their safety, reliability and load-bearing capability. Advances in modeling and characterization have made it possible to determine mechanisms controlling the thermal, chemical and mechanical behavior of nanomaterials. This volume brings together researchers from around the world to assess fundamental studies on synthesis, characterization of structure, and evaluation of properties of energetic/reactive nanomaterials. Applications such as new propellant formulations, underwater detonation developments, biomedical research, and combustion of nanolayered metal films for cladding materials are featured. Topics include: applications and toxicology; synthesis; characterization; characterization and theory; theory and modeling; and general discussion.
This volume, a continuation of the MEMS, NEMS, and molecular machines symposium of the 2002 MRS Fall Meeting, is devoted to the investigation of materials and device behavior at the micro-, nano-, and molecular scale as well as interdisciplinary work futhering the design and development of micro-, nano-, and molecular devices. New materials and fabrication techniques are introduced, and ongoing issues such as reliability, surface effects, processing and packaging, biocompatibility, and stability are discussed. Projects coupling micro-and nanoscale approaches to solve ongoing issues in the development of small-scale systems are featured. Topics include: nanotechnology; alternative fabrication techniques; micro- and nanofluidics; applied micro- and nanotechnology; mechanical properties; biotechnology and nanotechnology; alternative materials and metrology; and surface engineering and tribology.