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As concerns with the efficient use of energy resources, and the minimization of environmental damage have come to the fore, there has been a renewed interest in the role that thermoelectric devices could play in generating electricity from waste heat, enabling cooling via refrigerators with no moving parts, and many other more specialized applications. The main problem in realizing this ambition is the rather low efficiency of such devices for general applications. This book deals with the proceedings of a workshop addressed that problems by reviewing the latest experimental and theoretical work on suitable materials for device applications and by exploring various strategies that might increase their efficiency. The proceedings cover a broad range of approaches, from the experimental work of fabricating new compounds through to theoretical work in characterizing and understanding their properties. The effects of strong electron correlation, disorder, the proximity to metal-insulator transitions, the properties of layered composite materials, and the introduction of voids or cages into the structure to reduce the lattice thermal conductivity are all explored as ways of enhancing the efficiency of their use in thermoelectric devices.
The disproportionate use of fossil fuels has turned into a serious environmental issue. Thus, we are encountering one of the biggest challenges of the twenty-first century, satisfying the energy demand with respect to the environment. Thermoelectricity is an emerging technology, which contributes to reducing the impact of the use of traditional technologies, harvesting the waste heat, and eliminating the use of refrigerants. The book Bringing Thermoelectricity into Reality covers the current thermoelectric investigations: the study of novel thermoelectric materials, the development of computational models, the design of proper assemblies, and the optimization of thermal designs, as well as novel thermoelectric generators, coolers, and heating applications. This book looks for the definitive thermoelectric applications applied to everyday life.
This book provides a concise but comprehensive introduction to the fundamentals and current state of the art in thermoelectrics. Addressing an audience of materials scientists and engineers, the book covers theory, materials selection, and applications, with a wide variety of case studies reflecting the most up-to-date research approaches from the past decade, from single crystal to polycrystalline form and from bulk to thin films to nano dimensions. The world is facing major challenges for finding alternate energy sources that can satisfy the increasing demand for energy consumption while preserving the environment. The field of thermoelectrics has long been recognized as a potential and ideal source of clean energy. However, the relatively low conversion efficiency of thermoelectric devices has prevented their utility on a large scale. While addressing the need for thermal management in materials, device components, and systems, thermoelectrics provides a fundamental solution to waste heat recovery and temperature control. This book summarizes the global efforts that have been made to enhance the figure of merit of various thermoelectric materials by choosing appropriate processes and their influence on properties and performance. Because of these advances, today, thermoelectric devices are found in mainstream applications such as automobiles and power generators, as opposed to just a few years ago when they could only be used in niche applications such as in aeronautics, infrared imaging, and space. However, the continued gap between fundamental theoretical results and actual experimental data of figure of merit and performance continues to challenge the commercial applications of thermoelectrics. This book presents both recent achievements and continuing challenges, and represents essential reading for researchers working in this area in universities, industry, and national labs.
Thermoelectric Materials and Devices summarizes the latest research achievements over the past 20 years of thermoelectric material and devices, most notably including new theory and strategies of thermoelectric materials design and the new technology of device integration. The book's author has provided a bridge between the knowledge of basic physical/chemical principles and the fabrication technology of thermoelectric materials and devices, providing readers with research and development strategies for high performance thermoelectric materials and devices. It will be a vital resource for graduate students, researchers and technologists working in the field of energy conversion and the development of thermoelectric devices. - Discusses the new theory and methods of thermoelectric materials design - Combines scientific principles, along with synthesis and fabrication technologies in thermoelectric materials - Presents the design optimization and interface technology for thermoelectric devices - Introduces thermoelectric polymers and organic-inorganic thermoelectric composites
Environmental and economic concerns have significantly spurred the search for novel, high-performance thermoelectric materials for energy conversion in small-scale power generation and refrigeration devices. This quest has been mainly fueled by the introduction of new designs and the synthesis of new materials. In fact, good thermoelectric material
Advanced Thermoelectric Materials for Energy Harvesting Applications is a research-intensive textbook covering the fundamentals of thermoelectricity and the process of converting heat energy into electrical energy. It covers the design, implementation, and performance of existing and advanced thermoelectric materials. Chapters examine such topics as organic/inorganic thermoelectric materials, performance and behaviors of thermoelectric devices, and energy harvesting applications of thermoelectric devices.
It has been almost thirty years since the publication of a book that is entirely dedicated to the theory, description, characterization and measurement of the thermal conductivity of solids. The recent discovery of new materials which possess more complex crystal structures and thus more complicated phonon scattering mechanisms have brought innovative challenges to the theory and experimental understanding of these new materials. With the development of new and novel solid materials and new measurement techniques, this book will serve as a current and extensive resource to the next generation researchers in the field of thermal conductivity. This book is a valuable resource for research groups and special topics courses (8-10 students), for 1st or 2nd year graduate level courses in Thermal Properties of Solids, special topics courses in Thermal Conductivity, Superconductors and Magnetic Materials, and to researchers in Thermoelectrics, Thermal Barrier Materials and Solid State Physics.
Thermoelectrics is the science and technology associated with thermoelectric converters, that is, the generation of electrical power by the Seebeck effect and refrigeration by the Peltier effect. Thermoelectric generators are being used in increasing numbers to provide electrical power in medical, military, and deep space applications where combinations of their desirable properties outweigh their relatively high cost and low generating efficiency. In recent years there also has been an increase in the requirement for thermoelectric coolers (Peltier devices) for use in infrared detectors and in optical communications. Information on thermoelectrics is not readily available as it is widely scattered throughout the literature. The Handbook centralizes this information in a convenient format under a single cover. Sixty of the world's foremost authorities on thermoelectrics have contributed to this Handbook. It is comprised of fifty-five chapters, a number of which contain previously unpublished material. The contents are arranged in eight sections: general principles and theoretical considerations, material preparation, measurement of thermoelectric properties, thermoelectric materials, thermoelectric generation, generator applications, thermoelectric refrigeration, and applications of thermoelectric cooling. The CRC Handbook of Thermoelectrics has a broad-based scope. It will interest researchers, technologists, and manufacturers, as well as students and the well-informed, non-specialist reader.
Introduction to Thermoelectricity is the latest work by Professor Julian Goldsmid drawing on his 55 years experience in the field. The theory of the thermoelectric and related phenomena is presented in sufficient detail to enable researchers to understand their observations and develop improved thermoelectric materials. The methods for the selection of materials and their improvement are discussed. Thermoelectric materials for use in refrigeration and electrical generation are reviewed. Experimental techniques for the measurement of properties and for the production of thermoelements are described. Special emphasis is placed on nanotechnology which promises to yield great improvements in the efficiency of thermoelectric devices. Chapters are also devoted to transverse thermoelectric effects and thermionic energy conversion, both techniques offering the promise of important applications in the future.
Complex metal alloys (CMAs) comprise a huge group of largely unknown alloys and compounds, where many phases are formed with crystal structures based on giant unit cells containing atom clusters, ranging from tens of to more than thousand atoms per unit cell. In these phases, for many phenomena, the physical length scales are substantially smaller than the unit-cell dimension. Hence, these materials offer unique combinations of properties which are mutually exclusive in conventional materials, such as metallic electric conductivity combined with low thermal conductivity, good light absorption with high-temperature stability, high metallic hardness with reduced wetting by liquids, etc.This book is the second of a series of books issued yearly as a deliverable to the European Community of the School established within the European Network of Excellence CMA. Written by reputed experts in the fields of metal physics, surface physics, surface chemistry, metallurgy, and process engineering, this book brings together expertise found inside as well as outside the network to provide a comprehensive overview of the current state of knowledge in CMAs.