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The proceedings summarise the oral and poster presentations of the Winterschool on the above topic. The event was the sixth in a series aimed at describing and discussing recent advances in the understanding of the electronic properties of novel materials. The topic of the meeting, fullerenes and related materials, was chosen as a sequel to that of the previous year in an effort to keep abreast of this new and rapidly evolving field of research. For the duration of the week, world experts from the fields of physics, chemistry and materials science were gathered together to present their current research as well as to participate in the many lively discussions which evolved from the presentations. As such, the proceedings constitute a definitive description of the state of the art of fullerene research.
Until 1985, the chemical element Carbon was only known to exist in two forms -- diamond and graphite. This changed when Kroto and co-workers discovered an entirely new form of carbon, which became known as C60 or the fullerene molecule. (This discovery later led to their award of the 1996 Nobel Prize in Chemistry.) The original discovery of C60 was in the soot produced from the laser ablation of graphite. Since then, other methods of production have been developed. It is also thought that isolated C60 molecules may be found in stars and interstellar media. It was soon discovered that C60 is not the only ball-like carbon molecule possible (although it is the most stable and the most dominant). The rugby-ball shaped C70 molecule is another possibility. In nanotechnology, the potential applications of carbon nanotubes (formed by combining hexagonal rings of carbon atoms only, rather than hexagons and pentagons as in C60) for very small electronic devices are currently the subject of much activity. This book presents the latest research in this dynamic field.
This book provides detailed knowledge about fullerene nanowhiskers and the related low-dimensional fullerene nanomaterials. It introduces tubular nanofibers made of fullerenes, fullerene nanotubes, and single crystalline thin film made of C60, called fullerene nanosheet.Since the discovery of C60 in 1985, various fullerene molecules, including high
Nanocarbon chemistry and physics is a fast-developing, broad research area – the Nobel prizes in 1996 and 2010 awarded to two key discoveries in the field, and several other nanocarbon achievements of comparable importance. Owing to this rapid growth, the nanocarbon landscape fundamentally changes every few years, creating a need to survey the field on a regular basis to update the books that have become incomplete or even obsolete. As such, this book focuses on fullerenes and metallofullerenes and also on the related areas of nanotubes and graphenes. All the covered research topics provide important fundamental knowledge for the natural sciences, but also for applications in molecular electronics, superconductivity, catalysis, photovoltaics and medical diagnostics. The current nanocarbon research activities have particularly high application potential in the conversion of solar energy, future molecular memories, non-conventional materials for optoelectronics, and new treatments for civilization diseases. Offering a truly up-to-date critical survey of nanocarbon science, its concepts and highlights, it follows the concept of a handbook: it addresses key topics systematically, from historical background, methodological aspects, current important issues, and application potential, all supplied with extensive referencing. With individual chapters written by leading experts with extensive research experience, it is a comprehensive reference resource for graduate students and active researchers alike.
Until recently, the element carbon was believed to exhibit only two main allotropic forms, diamond and graphite. Research in the US and Europe has now confirmed the existence of a third previously unknown form - buckminsterfullerene (C60) and its relatives, the fullerenes (C24, C28, C32, C70 etc). The story of fullerene chemistry, physics and materials science began in 1985, almost twenty years after the existence of a spherical carbon cluster was first considered. In September 1985 a joint Sussex/Rice Universities team including Kroto, Heath, O'Brien, Curl and Smalley used a powerful mass spectrometric technique to identify the C+60 species, and proposed a spherical structure and the name buckminsterfullerene. It was not, however, until Krätschmer and Huffman reported the isolation of crystals of C60 in 1990 that the closed cage structure of C60 could be confirmed. The Fullerenes documents the work leading up to 1990 and more recent developments in the field of fullerene research and will serve as an indispensible reference tool for all workers in this area.
This edited book highlights the central players in the Bionanotechnology field - which are the nanostructures and biomolecules. It provides broad examples of current developments in Bionanotechnology research and is an excellent introduction to the field. The book describes how nanostructures are synthesized and details the wide variety of nanostructures available for biological research and applications. Examples of the unique properties of nanostructures are provided along with the current applications of these nanostructures in biology and medicine. The final chapters of the book describe the toxicity of nanostructures.
The discovery of caged carbon structures, in 1985, established a whole new field of carbon chemistry. Unlike graphite and diamond, these structures known as fullerenes are finite in structure and are relevant to a wide variety of fields including supramolecular assemblies, nanostructures, optoelectronic devices and a whole range of biological activities. Fullerenes: Principles and Applications discusses all aspects of this exciting field. Sections include: the basic principles for the chemical reactivity of fullerenes, electrochemistry, light induced processes, fullerenes for material sciences, fullerenes and solar cells, biological applications and multifunctional carbon nanotube materials. Written by leading experts in the field the book summarises the basic principles of fullerene chemistry but also highlights some of the most remarkable advances that have occurred in recent years. Fullerenes: Principles and Applications will appeal to researchers in both academia and industry.
This book is the first of its kind to reflect upon the intense and rapidly growing interest in open geodesic polyaromatic molecules, specifically focusing on their synthesis and reactivity in metal binding reactions. The book broadly covers all aspects related to the fullerene fragment chemistry: current synthetic techniques, description of the available members of this new family (which has grown to more than two dozens members, with none being available commercially), molecular geometry and trends in the solid state packing, as well as extensions into physical properties and new buckybowl-based molecules and materials. It covers fundamental research related to a new class of hydrocarbons, namely open geodesic polyarenes that map onto the surfaces of fullerenes (and referred to as fullerene fragments or buckybowls.
The closed-cage carbon molecules known as fullerenes provide an entirely new branch of chemistry, materials science, and physics. Fullerene research is now engaging the frenetic attention of thousands of scientists. Initially, the chemistry was relatively slow to develop due to the low availability of material, and the need for state-of-the-art instrumentation for product analysis. This research area is now very definitely up-and-running, and will soon become the main focus of attention in the fullerene field. The number of published papers already runs into hundreds, and the main features of fullerene reactivity have been established. This book describes all of the known types of reactions as well as the means of production, the purification, and the properties of fullerenes.
During the last decade, fullerenes and carbon nanotubes have attracted special interest as new nanocarbons with novel properties. Because of their hollow caged structure, they can be used as containers for atoms and molecules, and nanotubes can be used as miniature test-tubes. Chemistry of Nanocarbons presents the most up-to-date research on chemical aspects of nanometer-sized forms of carbon, with emphasis on fullerenes, nanotubes and nanohorns. All modern chemical aspects are mentioned, including noncovalent interactions, supramolecular assembly, dendrimers, nanocomposites, chirality, nanodevices, host-guest interactions, endohedral fullerenes, magnetic resonance imaging, nanodiamond particles and graphene. The book covers experimental and theoretical aspects of nanocarbons, as well as their uses and potential applications, ranging from molecular electronics to biology and medicine.