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Open system behavior is predicated on a fundamental relationship between the timescale over which mass is transported and the timescale over which it is chemically transformed. This relationship describes the basis for the multidisciplinary field of reactive transport (RT). In the 20 years since publication of Review in Mineralogy and Geochemistry volume 34: Reactive Transport in Porous Media, RT principles have expanded beyond early applications largely based in contaminant hydrology to become broadly utilized throughout the Earth Sciences. RT is now employed to address a wide variety of natural and engineered systems across diverse spatial and temporal scales, in tandem with advances in computational capability, quantitative imaging and reactive interface characterization techniques. The present volume reviews the diversity of reactive transport applications developed over the past 20 years, ranging from the understanding of basic processes at the nano- to micrometer scale to the prediction of Earth global cycling processes at the watershed scale. Key areas of RT development are highlighted to continue advancing our capabilities to predict mass and energy transfer in natural and engineered systems.
Conceptual separation of humans and natural ecosystems is reflected in the thinking of most natural resource management professions, including for estry, wildlife management, fisheries, range management, and watershed management (Burch 1971). Such thinking can deny the reality of the human element in local, regional, and global ecosystems (Bonnicksen and Lee 1982, Klausner 1971, Vayda 1977). As complex organisms with highly developed cultural abilities to modify their environment, humans directly or indirectly affect almost all terrestrial and aquatic ecosystems (Bennett 1976). Conse quently, information for managing watershed ecosystems is incomplete without consideration of human institutions and activities. Sociologists have studied the relationships between human societies and the land base or ecosystems on which they depend for over 60 years (Field and Burch 1990). These studies are distinguished by (1) a holistic perspec tive that sees people and their environments as interacting systems, (2) flex ible approaches that permit either the environment or human society to be treated as the independent variable in analyzing of society-environment re lations, and (3) accumulation of a substantial body of knowledge about how the future welfare of a society is influenced by its uses (or misuses) of land and water (Firey 1990).
A comprehensive ecological study of a Lake Eric estuary and its watershed, including chapters on geology, soils, climatology, hydrolesy, biology, ecology, archaeology, history, and land use. This book serves as a site profile of the only Nation a Estuarine Research Reserve in the Great Lakes Resion. Over 200 color illustrations.
This book provides a comprehensive overview of reaction processes in the Earth's crust and on its surface, both in the laboratory and in the field. A clear exposition of the underlying equations and calculation techniques is balanced by a large number of fully worked examples. The book uses The Geochemist's Workbench® modeling software, developed by the author and already installed at over 1000 universities and research facilities worldwide. Since publication of the first edition, the field of reaction modeling has continued to grow and find increasingly broad application. In particular, the description of microbial activity, surface chemistry, and redox chemistry within reaction models has become broader and more rigorous. These areas are covered in detail in this new edition, which was originally published in 2007. This text is written for graduate students and academic researchers in the fields of geochemistry, environmental engineering, contaminant hydrology, geomicrobiology, and numerical modeling.
This second edition is extensively revised throughout with expanded discussion of modeling fundamentals and coverage of advances in model calibration and uncertainty analysis that are revolutionizing the science of groundwater modeling. The text is intended for undergraduate and graduate level courses in applied groundwater modeling and as a comprehensive reference for environmental consultants and scientists/engineers in industry and governmental agencies. - Explains how to formulate a conceptual model of a groundwater system and translate it into a numerical model - Demonstrates how modeling concepts, including boundary conditions, are implemented in two groundwater flow codes-- MODFLOW (for finite differences) and FEFLOW (for finite elements) - Discusses particle tracking methods and codes for flowpath analysis and advective transport of contaminants - Summarizes parameter estimation and uncertainty analysis approaches using the code PEST to illustrate how concepts are implemented - Discusses modeling ethics and preparation of the modeling report - Includes Boxes that amplify and supplement topics covered in the text - Each chapter presents lists of common modeling errors and problem sets that illustrate concepts
The globally important nature of wetland ecosystems has led to their increased protection and restoration as well as their use in engineered systems. Underpinning the beneficial functions of wetlands are a unique suite of physical, chemical, and biological processes that regulate elemental cycling in soils and the water column. This book provides an in-depth coverage of these wetland biogeochemical processes related to the cycling of macroelements including carbon, nitrogen, phosphorus, and sulfur, secondary and trace elements, and toxic organic compounds. In this synthesis, the authors combine more than 100 years of experience studying wetlands and biogeochemistry to look inside the black box of elemental transformations in wetland ecosystems. This new edition is updated throughout to include more topics and provide an integrated view of the coupled nature of biogeochemical cycles in wetland systems. The influence of the elemental cycles is discussed at a range of scales in the context of environmental change including climate, sea level rise, and water quality. Frequent examples of key methods and major case studies are also included to help the reader extend the basic theories for application in their own system. Some of the major topics discussed are: Flooded soil and sediment characteristics Aerobic-anaerobic interfaces Redox chemistry in flooded soil and sediment systems Anaerobic microbial metabolism Plant adaptations to reducing conditions Regulators of organic matter decomposition and accretion Major nutrient sources and sinks Greenhouse gas production and emission Elemental flux processes Remediation of contaminated soils and sediments Coupled C-N-P-S processes Consequences of environmental change in wetlands# The book provides the foundation for a basic understanding of key biogeochemical processes and its applications to solve real world problems. It is detailed, but also assists the reader with box inserts, artfully designed diagrams, and summary tables all supported by numerous current references. This book is an excellent resource for senior undergraduates and graduate students studying ecosystem biogeochemistry with a focus in wetlands and aquatic systems.
Methods in Stream Ecology, Second Edition, provides a complete series of field and laboratory protocols in stream ecology that are ideal for teaching or conducting research. This updated edition reflects recent advances in the technology associated with ecological assessment of streams, including remote sensing. In addition, the relationship between stream flow and alluviation has been added, and a new chapter on riparian zones is also included. The book features exercises in each chapter; detailed instructions, illustrations, formulae, and data sheets for in-field research for students; and taxanomic keys to common stream invertebrates and algae. With a student-friendly price, this book is key for all students and researchers in stream and freshwater ecology, freshwater biology, marine ecology, and river ecology. This text is also supportive as a supplementary text for courses in watershed ecology/science, hydrology, fluvial geomorphology, and landscape ecology. - Exercises in each chapter - Detailed instructions, illustrations, formulae, and data sheets for in-field research for students - Taxanomic keys to common stream invertebrates and algae - Link from Chapter 22: FISH COMMUNITY COMPOSITION to an interactive program for assessing and modeling fish numbers