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This volume contains eight chapters covering a wide range of topics: ultrasonic vibration potentials, impedance measurements, photo electrochemical kinetics, chlorine production, electrochemical behavior of titanium, structural properties of membranes, bioelec troche mistry, and small-particle effects for electrocatalysis. Chapter 1, contributed by Zana and Yeager, discusses the little used but potentially important area of ultrasonic vibration potentials. The authors review the historical literature and the associated theoretical equations. They continue by discussing various aspects of the experimental technique and close with a review of the existing studies. They conclude by noting that vibra tion potentials may be useful for determining the effects of various agents on colloidal suspensions found in such important industries as paper production. Chapter 2 is a review of impedance techniques, written by Macdonald and McKubre. The authors include not only derivations of various impedance functions for electrochemical systems but also particularly useful discussions of instrumental methods. The authors close with an interesting claim: "the distribution of current and potential within a porous battery or fuel-cell electrode and within 'flow-through' electrodes is best analyzed in terms of the frequency dispersion of the impedance." Chapter 3, by Khan and Bockris, is a timely review of photo electrochemical kinetics and related devices. Their work begins by reviewing critically important papers on photoelectrochemical kinetics. They continue by presenting detailed discussions concern ing the conceptual ideas of the semiconductor-solution interface.
It is now time for a comprehensive treatise to look at the whole field of electrochemistry. The present treatise was conceived in 1974, and the earliest invitations to authors for contributions were made in 1975. The completion of the early volumes has been delayed by various factors. There has been no attempt to make each article emphasize the most recent situation at the expense of an overall statement of the modern view. This treatise is not a collection of articles from Recent Advances in Electrochemistry or Modern Aspects of Electrochemistry. It is an attempt at making a mature statement about the present position in the vast area of what is best looked at as a new interdisciplinary field. Texas A & M University J. O'M. Bockris University of Ottawa B. E. Conway Case Western Reserve University Ernest Yeager & M University Texas A Ralph E. White Preface to Volume 2 This volume brings together some dozen processes well known to the electro chemist and treats them according to their various degrees of importance. The production of hydrogen is one of the more important processes, particularly with respect to the prospects of a hydrogen economy. No one would doubt, however, that the most commercially important electrochemical processes at the present time are the production of aluminum and of chlorine. Each of these processes has a separate chapter devoted to it.
Explores both electrochemistry fundamentals and the applications of oxygen in electrochemical systems. Much of the information is summarized in tables which are accompanied by a list of references to consult for details. Emphasizes fuel cells and metal/air batteries.