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Introduction and Scope-During the last few decades, an enormous effort has been made to understand corrosion phenomena and their mechanisms, and to elucidate the causes that dramatically influence the service lifetime of metal materials. The performance of metal materials in aggressive environments is critical for a sustainable society. The failure of the material in service impacts the economy, the environment, health, and society. In this regard, corrosion-based economic losses due to maintenance, repair, and the replacement of existing structures and infrastructure account for up to 4% of gross domestic product (GDP) in well developed countries. One of the biggest issues in corrosion engineering is estimating service lifetime. Corrosion prediction has become very difficult, as there is no direct correlation with service lifetime and experimental lab results, usually as a result of discrepancies between accelerated testing and real corrosion processes. It is of major interest to forecast the impact of corrosion-based losses on society and the global economy, since existing structures and infrastructure are becoming old, and crucial decisions now need to be made to replace them. On the other hand, environmental protocols seek to reduce greenhouse effects. Therefore, low emission policies, in force, establish regulations for the next generation of materials and technologies. Advanced technologies and emergent materials will enable us to get through the next century. Great advances are currently in progress for the development of corrosion-resistant metal materials for different sectors, such as energy, transport, construction, and health. This Special Issue on the corrosion and protection of metals is focused on current trends in corrosion science, engineering, and technology, ranging from fundamental to applied research, thus covering subjects related to corrosion mechanisms and modelling, protection and inhibition processes, and mitigation strategies.
Electrochemistry is the branch of chemistry that deals with the chemical action of electricity and the production of electricity by chemical reactions. In a world short of energy sources yet long on energy use, electrochemistry is a critical component of the mix necessary to keep the world economies growing. Electrochemistry is involved with such important applications as batteries, fuel cells, corrosion studies, hydrogen energy conversion, bioelectricity. Research on electrolytes, cells, and electrodes is within the scope of this old but extremely dynamic field. This volume deals with prevention of metal corrosion.
Human beings undoubtedly became aware of corrosion just after they made their first metals. These people probably began to control corrosion very so on after that by trying to keep metal away from corrosive environments. "Bring your tools in out of the rain" and "Clean the blood off your sword right after battle" would have been early maxims. Now that the mechanisms of corrosion are better understood, more techniques have been developed to control it. My corrosion experience extends over 10 years in industry and research and over 20 years teaching corrosion courses to university engineering students and industrial consulting. During that time I have developed an approach to corrosion that has successfully trained over 1500 engineers. This book treats corrosion and high-temperature oxidation separately. Corrosion is divided into three groups: (1) chemical dissolution including uniform attack, (2) electrochemical corrosion from either metallurgicalor environmental cells, and (3) corrosive-mechanical interactions. It seems more logical to group corrosion according to mechanisms than to arbitrarily separate them into 8 or 20 different types of corrosion as if they were unrelated. University students and industry personnel alike generally are afraid of chemistry and consequently approach corrosion theory very hesitantly. In this text the electrochemical reactions responsible for corrosion are summed up in only five simple half-cell reactions. When these are combined on a polarization diagram, which is explained in detail, the electrochemical pro cesses become obvious.
Corrosion Protection at the Nanoscale explores fundamental concepts on how metals can be protected at the nanoscale by using both nanomaterials-based solutions, including nanoalloys, noninhibitors and nanocoatings. It is an important reference resource for both materials scientists and engineers wanting to find ways to create an efficient corrosion prevention strategy. Nanostructure materials have been widely used in many products, such as print electronics, contact, interconnection, implant, nanosensors and display units to lessen the impact of corrosion. Traditional methods for protection of metals include various techniques, such as coatings, inhibitors, electrochemical methods (anodic and cathodic protections), metallurgical design are covered in this book. Nanomaterials-based protective methods can offer many advantages over their traditional counterparts, such as protection for early-stage, higher corrosion resistance, better corrosion control. This book also outlines these advantages and discusses the challenges of implementing nanomaterials as corrosion protection agents on a wide scale.
Corrosion may be defined as an unintentional attack on a material through reaction with a surrounding medium. The term can refer to a process or to the damage caused by such a process. According to this general definition, materials other than metals, such as ceramics, plastics or concrete, may also be subject to corrosion (or corrode). When no particular reference is made to the material, however, it is normally understood that a metal is being attacked. It is entirely in this limited sense that the term is used in this book. There are good reasons for treating the corrosion of metals separately, apart from deterioration or decay of other materials. Since metals have a high electric conductivity, their corrosion is usually of an electrochemical nature. The chemical deterioration of electrically non-conducting ma terials, such as plastics and ceramics, is governed by other physico-chemical principles. It is necessary to devote more attention to metallic corrosion nowadays than earlier, due to 1. An increased use of metals within all fields of technology. 2. The use for special applications, e.g. within the atomic energy field, of rare and expensive metals, whose preservation requires particular precautions. 3. A more corrosive environment due to the increasing pollution of air and water. 4. The use of metallic constructions of more slender dimensions which do not tolerate corrosive attacks to the same extent as did the heavy constructions used in the old days.
Corrosion is a huge issue for materials, mechanical, civil and petrochemical engineers. With comprehensive coverage of the principles of corrosion engineering, this book is a one-stop text and reference for students and practicing corrosion engineers. Highly illustrated, with worked examples and definitions, it covers basic corrosion principles, and more advanced information for postgraduate students and professionals. Basic principles of electrochemistry and chemical thermodynamics are incorporated to make the book accessible for students and engineers who do not have prior knowledge of this area. Each form of corrosion covered in the book has a definition, description, mechanism, examples and preventative methods. Case histories of failure are cited for each form. End of chapter questions are accompanied by an online solutions manual.* Comprehensively covers the principles of corrosion engineering, methods of corrosion protection and corrosion processes and control in selected engineering environments* Structured for corrosion science and engineering classes at senior undergraduate and graduate level, and is an ideal reference that readers will want to use in their professional work* Worked examples, extensive end of chapter exercises and accompanying online solutions and written by an expert from a key pretochemical university
For a senior/graduate-level course in corrosion. Comprehensive in approach, this text explores the scientific principles and methods that underlie the cause, detection, measurement, and prevention of many metal corrosion problems in engineering practice. Most chapters progress from qualitative, descriptive sections (including methods of prevention and testing), to more quantitative sections (involving metallurgy and electrochemistry), and finally to sections on current research developments in the chapter topic."
Hot-dip galvanization is a method for coating steel workpieces with a protective zinc film to enhance the corrosion resistance and to improve the mechanical material properties. Hot-dip galvanized steel is the material of choice underlying many modern buildings and constructions, such as train stations, bridges and metal domes. Based on the successful German version, this edition has been adapted to include international standards, regulations and best practices. The book systematically covers all steps in hot-dip galvanization: surface pre-treatment, process and systems technology, environmental issues, and quality management. As a result, the reader finds the fundamentals as well as the most important aspects of process technology and technical equipment, alongside contributions on workpiece requirements for optimal galvanization results and methods for applying additional protective coatings to the galvanized pieces. With over 200 illustrated examples, step-by-step instructions, presentations and reference tables, this is essential reading for apprentices and professionals alike.
Provides a methodology for integrating materials selection with the design process, including simultaneous technical and economic evaluation. Save hours of frustrating research time: Get fast answers about the best material for a particular application. In the past, researching the endless sources on corrosion and materials in their countless applications were next to impossible. That's why this book was written: to help simplify your materials selection problems. It's an exhaustive source on the different corrosion-resistant materials, types of corrosion, factors affecting corrosion, passivation, corrosion monitoring, corrosion control measures, methodology of materials selection, and more.
The use of conducting polymers for the anticorrosion protection of metals has attracted great interest during the last 30 years. The design and development of conducting polymers-based coating systems with commercial viability is expected to be advanced by applying nanotechnology and has received substantial attention recently. This book begins wit