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Doctoral Thesis / Dissertation from the year 2010 in the subject Physics - Nuclear Physics, Molecular Physics, Solid State Physics, Dr. Babasaheb Ambedkar Marathwada University (-), course: PH.D., language: English, abstract: Wide scope is available to study these aspects of ferrite which at present to our knowledge was not probe by researchers. In relevance to the ever expanding possibilities, and potential that is available with the ferrite materials, the scope of presently undertaken work is designed carefully by selecting suitable ferrite and dopants. A sincere attempt was made to extract fruitful, exhaustive and, systematic information regarding structural, cation distribution, electrical, dielectric and magnetic aspects of the ferrite systems under investigations. In the present study, the properties of nickel ferrites substituted by diamagnetic Zn2+, non-magnetic trivalent In3+ ions and tetravalent Ce4+ ions are studied for various compositions. The properties are investigated with a view to understand the effect of divalent, trivalent and tetravalent substitution in nickel ferrite. The thesis consists of five chapters. Chapter 1 related to Scope, problem statement, theory of magnetism, ferrites, background, motivation and aim of the present work, properties of the samples under investigations, objective and outline of thesis. Chapter 2, 3 and 4 related to results and discussion of structural, electrical and magnetic properties of Ni1-xZnxFe2O4, NiInxFe2-xO4 and Ni1-2xCexFe2O4 ferrite system respectively. Chapter 5 gives the summary, discussion and conclusion on Zn, In and Ce substituted nickel ferrite. On summarizing the results obtained on Ni-Zn, Ni-In and Ni-Ce spinel ferrites it can be concluded that; - The structural properties are found to be varying in all the three systems. The lattice parameter of Ni ferrite systems increases with increasing valancy of dopants (Zn2+, In3+ and Ce4+). - The other prominent parameter of our structural study i.e. p
Ferrites are ceramic, homogeneous materials composed of various oxides with iron oxide as their main constituent. Ferrites are a class of ceramic ferromagnetic materials that by definition can be magnetized to produce large magnetic flux densities in response to small applied magnetization forces. Further, ferrites are chemical compounds, ceramic with iron (III) oxide Fe2O3 as their principal components [1]. Ferrites are usually non-conductive ferrimagnetic ceramic compounds derived from iron oxides such as hematite (Fe2O3) or magnetite (Fe3O4) as well as oxides of other metals. Ferrites are, like most other ceramics, hard and brittle. Many of them are magnetic materials and they are used to make permanent magnets, ferrite cores for transformers and in various other applications.
This book has given an overview of the sol-gel auto-combustion preparation method and characterization of Ni0.5Co0.5FeAlO4. This work focused on the structural properties XRD,TGA, SEM, TEM, FTIR, Magnetic Properties, Dielectric Properties were measured.By using the TG curve the exact temperature of formation of ferrite phase was obtained.The properties such as dielectric constant, dielectric loss tangent as a function of frequency and temperature. The addition of aluminium results in increasing the resistivity which decreases the dielectric losses and saturation magnetization. Sintering temperature and synthesis rout plays important role in the fabrication of nano-structured ferrite materials. Attempts are made to synthesis the ferrites by changing their sintering temperature and synthesis route in order to study the structural, electrical and magnetic properties. In the present investigation we have prepared the nanocrystalline powder of Ni-Co-Fe-Al-O ferrite and sintered at four different temperature 5000C, 6000C, 7000C and 8000C. Effect of sintering temperature on the structural, electric and magnetic properties of Ni-Co-Fe-Al-O ferrite nanoparticles were studied.
By browsing about 10 000 000 scientific articles of over 200 major journals mainly in a 'cover to cover approach' some 200 000 publications were selected. The extracted data is part of the following fundamental material research fields: crystal structures (S), phase diagrams (also called constitution) (C) and the comprehensive field of intrinsic physical properties (P). This work has been done systematically starting with the literature going back to 1900. The above mentioned research field codes (S, C, P) as well as the chemical systems investigated in each publication were included in the present work. The aim of the Inorganic Substances Bibliography is to provide researchers with a comprehensive compilation of all up to now published scientific publications on inorganic systems in only three handy volumes.
This book has given an overview of the sol-gel auto-combustion preparation method and characterization of Ni0.5Co0.5FeCrO4. This work focused on the structural properties XRD,TGA, SEM, TEM, FTIR, Magnetic Properties, Dielectric Properties were measured.By using the TG curve the exact temperature of formation of ferrite phase was obtained.The properties such as dielectric constant, dielectric loss tangent as a function of frequency and temperature. The addition of chromium in nickel – cobalt ferrite significantly changes the electrical and magnetic properties. Nickel and cobalt ferrites are inverse ferrites and hence for x £ 1, nickel ferrite shows structure of inverse spinel and for x >1, the inverse structure converted into normal structure. The crystal structure of ferrite, cation distribution, synthesis route, sintering conditions, amount and type of impurity addition decides the electric and magnetic properties of ferrites. Same ferrite with different crystalline size shows different properties. The electrical and magnetic properties even structural properties of ferrites at nano-crystalline phase shows significantly difference than the bulk one. In the present investigation we have presented the results on structural and magnetic properties of Ni0.5Co0.5FeCrO4 sintered at 5000C, 6000C, 7000C and 8000C for 6h.
This book brings together the most important advances in the field of recent decades. It provides instructors teaching graduate, postgraduate and researchers level for material science courses with a comprehensive and in-depth textbook, that will prepare post graduate students for research or further study as well as reading more advanced and specialized books and research literature in the field. This textbook covers Introduction to Spinel Ferrites, Materials and Methods, Synthesis of Ferrites, while discussing cutting-edge such as Structural Properties, Magnetic Properties, Electrical Properties, Results and Discussion, Experimental Procedure, Results and Discussion, Conclusions
Spinel nanoferrites have emerged as an advanced class of nanostructured materials in the domains of nanoscience and technology over the past decade. This book covers the fundamentals of spinel ferrites and their applications in the health sector and the environment. It focuses on the key applications of spinel ferrites in the health sector, such as hyperthermia, cancer diagnosis/treatment, and antimicrobial activity, as well as in environmental issues like water purification, wastewater treatment, and air pollution remediation. Features Covers the classification, synthesis, properties, structures, and applications of spinel ferrites. Provides exclusive coverage of biomedical and environmental applications. Includes discussions on environmental pollution, types of pollutants, and the removal of those pollutants using spinel nanoferrites. Reviews applications in cancer diagnosis and treatment, MRI, hyperthermia, and related fields. Recommends building environmentally-friendly ferrite materials for a clean environment. This book is aimed at graduate students and researchers in materials science, nanotechnology, environmental science, and bioengineering.