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Polymers are an example of “products-by-process”, where the final product properties are mostly determined during manufacture, in the reactor. An understanding of processes occurring in the polymerization reactor is therefore crucial to achieving efficient, consistent, safe and environmentally friendly production of polymeric materials. Polymer Reaction Engineering provides the link between the fundamentals of polymerization kinetics and polymer microstructure achieved in the reactor. Organized according to the type of polymerization, each chapter starts with a description of the main polymers produced by the particular method, their key microstructural features and their applications Polymerization kinetics and its effect on reactor configuration, mass and energy balances and scale-up are covered in detail. The text is illustrated with examples emphasizing general concepts, principles and methodology. Written as an authoritative guide for chemists and chemical engineers in industry and academe, Polymer Reaction Engineering will also be a key reference source for advanced courses in polymer chemistry and technology.
Approximately half of the world production of the petrochemical industry (more than 100 million tonnes) is in the form of polymers, yet it would probably surprise most people to learn how much their lifestyle depends on polymers ranging, as they do, from detergents, kitchenware and electrical appliances to furnishings and a myriad other domestic goods. Still less are they likely to be aware of the extensive part they play in engineering applications for mechanical machine components and advanced high performance aircraft. This versatility derives from the fact that polymeric materials are made up of a range of molecules of varying length, whose properties are related to molecular structure and the proportions of the chains in the mixture. For example, polypropylene is a commodity polymer which is produced in hun dreds of different grades to meet specific market requirements. This depends on the catalyst as well as the operating conditions and reactor design. A major area for growth is in substituting polymers for conventional materials such as ceramics and metals. Not only can they match these materials in terms of mechanical strength and robustness but they have very good resistance to chemical attack. Polyamides, for example, are widely used for car bumpers and new polymers are being developed for engine manifolds and covers. In 1993 there is, typically, 100 kg of various polymers used in cars and this is continually increasing, giving a net weight reduction and hence better fuel economy.
The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science.The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics.Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned.Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students.
Monomers composed of carbon and hydrogen atoms are the simple building blocks that make up polyolefins - molecules which are extremely useful and which have an extraordinary range of properties and applications. How these monomer molecules are connected in the polymer chain defines the molecular architecture of polyolefins. Written by two world-renowned authors pooling their experience from industry and academia, this book adopts a unique engineering approach using elegant mathematical modeling techniques to relate polymerization conditions, reactor and catalyst type to polyolefin properties. Readers thus learn how to design and optimize polymerization conditions to produce polyolefins with a given microstructure, and how different types of reactors and processes are used to create the different products. Aimed at polymer chemists, plastics technologists, process engineers,the plastics industry, chemical engineers, materials scientists, and company libraries.
The literature in polymerization reaction engineering has bloomed sufficiently in the last several years to justify our attempt in putting together this book. Rather than offer a comprehensive treatment of the entire field, thereby duplicating earlier texts as well as some ongoing bookwriting efforts, we decided to narrow down our aim to step growth polymerization systems. This not only provides us the lUxury of a more elaborate presentation within the constraints of production costs, but also enables us to remain on somewhat familiar terrain. The style and format we have selected are those of a textbook. The first six chapters present the principles of step growth polymerization. These are quite general, and can easily be applied in such diverse and emerging fields as polymerization applications in photolithography and microelec tronics. A detailed discussion of several important step growth polymeriz ations follows in the next five chapters. One could cover the first six chapters of this book in about six to eight weeks of a three-credit graduate course on polymerization reactors, with the other chapters assigned for reading. This could be followed by a discussion of chain-growth and other polymeriz ations, with which our material blends well. Alternately, the entire contents of this book could be covered in a course on step growth systems alone.
Recently, supercritical fluids have emerged as more sustainable alternatives for the organic solvents often used in polymer processes. This is the first book emphasizing the potential of supercritical carbon dioxide for polymer processes from an engineering point of view. It develops a state-of-the-art overview on polymer fundamentals, polymerization reactions and polymer processing in supercritical carbon dioxide. The book covers topics in a multidisciplinary approach starting from polymer chemistry and thermodynamics, going through monitoring, polymerization processes and ending with polymer shaping and post-processing. The authors are internationally recognized experts from different fields in polymer reaction engineering in supercritical fluids. The book was initiated by the Working Party on Polymer Reaction Engineering of the European Federation of Chemical Engineering and further renowned international experts.
Exploring the chemistry of synthesis, mechanisms of polymerization, reaction engineering of step-growth and chain-growth polymerization, polymer characterization, thermodynamics and structural, mechanical, thermal and transport behavior of polymers as melts, solutions and solids, Fundamentals of Polymer Engineering, Third Edition covers essential concepts and breakthroughs in reactor design and polymer production and processing. It contains modern theories and real-world examples for a clear understanding of polymer function and development. This fully updated edition addresses new materials, applications, processing techniques, and interpretations of data in the field of polymer science. It discusses the conversion of biomass and coal to plastics and fuels, the use of porous polymers and membranes for water purification, and the use of polymeric membranes in fuel cells. Recent developments are brought to light in detail, and there are new sections on the improvement of barrier properties of polymers, constitutive equations for polymer melts, additive manufacturing and polymer recycling. This textbook is aimed at senior undergraduate students and first year graduate students in polymer engineering and science courses, as well as professional engineers, scientists, and chemists. Examples and problems are included at the end of each chapter for concept reinforcement.
Tremendous developments in the field of polymer science, its growing importance, and an increase in the number of polymer science courses in both physics and chemistry departments have led to the revision of the First Edition. This new edition addresses subjects as spectroscopy (NMR), dynamic light scattering, and other modern techniques unknown before the publication of the First Edition. The Second Edition focuses on both theory (physics and chemistry) and engineering applications which make it useful for chemistry, physics, and chemical engineering departments.
Introducing a unique, modular approach to modeling polymerization reactions, this useful book will enable practitioners - chemists and engineers alike - to set up and structure their own models for simulation software like Predici®, C++, MatLab® or others. The generic modules are exemplified for concrete situations for various reactor types and reaction mechanisms and allow readers to quickly find their own point of interest - a highly useful information source for polymer engineers and researchers in industry and academia.
Advances in Polymer Reaction Engineering, Volume 56 in the Advances in Chemical Engineering series is aimed at reporting the latest advances in the field of polymer synthesis. Chapters in this new release include Polymer reaction engineering and composition control in free radical copolymers, Reactor control and on-line process monitoring in free radical emulsion polymerization, Exploiting pulsed laser polymerization to retrieve intrinsic kinetic parameters in radical polymerization, 3D printing in chemical engineering, Renewable source monomers in waterborne polymer dispersions, Importance of models and digitalization in Polymer Reaction Engineering, Recent Advances in Modelling of Radical Polymerization, and more. - Covers recent advances in the control and monitoring of polymerization processes and in reactor configurations - Provides modelling of polymerization reactions and up-to-date approaches to estimate reaction rate constants - Includes authoritative opinions from experts in academia and industry