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Highlighting a broad range multiscale modeling and methods for anticipating the morphologies and the properties of interfaces and multiphase materials, this reference covers the methodology of predicting polymer properties and its potential application to a wider variety of polymer types than previously thought possible. A comprehensive source, the
Among the thousands of synthesized polymers, new polymeric substances and materials with new, often unusual, properties often arise. Consequently, this presents a problem in determining the physical properties of polymers, and thus makes it difficult to ascertain how to synthesize polymers with desired properties. This book discusses what molecular modelling can do to predict the properties of realistic polymer systems. Organized by property, each chapter will address the methods one may use to study the particular system. * Focuses on polymer properties rather than methods, making it more accessible to the average scientist/engineer * All important polymers will be covered, such as amorphous polymers, semicrystalline polymers, elastomers, emulsions, polymer interfaces and surfaces * Chapters contributed by experts in the field * Discusses current commercial software used in molecular simulation
Service Life Prediction of Polymers and Coatings: Enhanced Methods focuses on the cutting-edge science behind how plastic and polymer materials are modified by the effects of weathering, offering the latest advances in service life prediction methods. The chapters have been developed by experts based on their contributions as part of the 7th Service Life Prediction Meeting. The volume begins with the premise that it is possible to produce and design life predictions, also looking at how these predictions can be used. Subsequent chapters present new developments in service life prediction, examining the most important considerations in SLP design, timescales, and other major issues. The book also considers the current state of the field in terms of both accomplishments and areas that require significant research going forward. This is a highly valuable reference for engineers, designers, technicians, scientists and R&D professionals who are looking to develop materials, components or products for outdoor applications across a range of industries. The book also supports academic researchers, scientists and advanced students with an interest in service life, the effects of weathering, material degradation, failure analysis, or sustainability across the fields of plastics engineering, polymer science and materials science. - Presents novel prediction techniques for plastics and polymers exposed to outdoor weathering - Provides a consensus roadmap on the scientific barriers related to a validated, predictive model for the response of polymer and plastics to outdoor exposure - Enables the reader to assess and compare different methods and approaches to service life prediction
Modification of Polymer Properties provides, for the first time, in one title, the latest information on gradient IPNs and gradient copolymers. The book covers the broad range of polymer modification routes in a fresh, current view representing a timely addition to the technical literature of this important area. Historically, blends, copolymers, or filled polymers have been developed to meet specific properties, or to optimize the cost/properties relationship. Using the gradient structure approach with conventional radical polymerization, it has been shown that it is possible to optimize properties if appropriate gradients in the composition of copolymer chains are obtained. An overview of the gradient structure approach for designing polymers has not appeared in the recent literature and this title covers the different methods used to modify properties, offering the whole range of ways to modify polymers in just one volume and making this an attractive option for a wide audience of practitioners. The approach for each chapter is to explain the fundamental principles of preparation, cover properties modification, describe future research and applications as examples of materials that may be prepared for specific applications, or that are already in use, in present day applications. The book is for readers that have a basic background in polymer science, as well as those interested in the different ways to combine or modify polymer properties. - Provides an integrated view on how to modify polymer properties - Presents the entire panorama of polymer properties modification in one reference, covering the essential information in each topic - Includes the optimization of properties using gradients in polymers composition or structure
Describes a consistent set of relations between the structure of polymers and their commercially important thermal and mechanical properties for engineering applications--facilitating the development of a framework of polymer physics to explore new application areas without prior correlations. Includes methods for the easy calculation of input parameters and tabulates the most important parameters for 250 polymers.
Service Life Prediction of Polymers and Plastics Exposed to Outdoor Weathering discusses plastics and polymers and their unique applications, from sealants used in construction, to polymer composites used in planes. While these materials are important enablers for advanced technologies, exposure to weather changes the very properties of plastics that make them so useful. This book reviews current research needs and provides a consensus roadmap of the scientific barriers to validated predictive models for the response of polymers and plastics to outdoor exposure. Despite extensive efforts over the past 20-30 years, testing of polymeric materials in accelerated or natural weathering conditions and the interpretation of the weathering results still require substantial improvements. This book represents the state-of-the-art in the prediction techniques available and in development. Engineers and materials scientists working in this field will be able to use the content of this book to assess the strengths and challenges of a range of different methods and approaches. - Enables engineers and scientists in a range of industries to more successfully predict the durability of polymers, paints and coatings when exposed to weather - Provides the latest information to help determine the sustainability of polymeric materials - Reviews the current state-of-the-art in this area and identifies research needs that are followed by more detailed discussions of specific polymers and applications
Properties of Polymers: Their Correlation with Chemical Structure; Their Numerical Estimation and Prediction from Additive Group Contributions summarizes the latest developments regarding polymers, their properties in relation to chemical structure, and methods for estimating and predicting numerical properties from chemical structure. In particular, it examines polymer electrical properties, magnetic properties, and mechanical properties, as well as their crystallization and environmental behavior and failure. The rheological properties of polymer melts and polymer solutions are also considered. Organized into seven parts encompassing 27 chapters, this book begins with an overview of polymer science and engineering, including the typology of polymers and their properties. It then turns to a discussion of thermophysical properties, from transition temperatures to volumetric and calorimetric properties, along with the cohesive aspects and conformation statistics. It also introduces the reader to the behavior of polymers in electromagnetic and mechanical fields of force. The book covers the quantities that influence the transport of heat, momentum, and matter, particularly heat conductivity, viscosity, and diffusivity; properties that control the chemical stability and breakdown of polymers; and polymer properties as an integral concept, with emphasis on processing and product properties. Readers will find tables that give valuable (numerical) data on polymers and include a survey of the group contributions (increments) of almost every additive function considered. This book is a valuable resource for anyone working on practical problems in the field of polymers, including organic chemists, chemical engineers, polymer processers, polymer technologists, and both graduate and PhD students.
This volume represents a continuation of the Polymer Science and Technology series edited by Dr. D. M. Brewis and Professor D. Briggs. The theme of the series is the production of a number of stand alone volumes on various areas of polymer science and technology. Each volume contains short articles by a variety of expert contributors outlining a particular topic and these articles are extensively cross referenced. References to related topics included in the volume are indicated by bold text in the articles, the bold text being the title of the relevant article. At the end of each article there is a list of bibliographic references where interested readers can obtain further detailed information on the subject of the article. This volume was produced at the invitation of Derek Brewis who asked me to edit a text which concentrated on the mechanical properties of polymers. There are already many excellent books on the mechanical properties of polymers, and a somewhat lesser number of volumes dealing with methods of carrying out mechanical tests on polymers. Some of these books are listed in Appendix 1. In this volume I have attempted to cover basic mechanical properties and test methods as well as the theory of polymer mechanical deformation and hope that the reader will find the approach useful.
Based on Wiley's renowned Encyclopedia of Polymer Science and Technology, this book provides coverage of key methods of characterization of the physical and chemical properties of polymers, including atomic force microscopy, chromatographic methods, laser light scattering, nuclear magnetic resonance, and thermal analysis, among others. Written by prominent scholars from around the world, this reference presents over twenty-five self -contained articles on the most used analytical techniques currently practiced in polymer science.