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Modification of Polymer Properties provides, for the first time, in one title, the latest information on gradient IPNs and gradient copolymers. The book covers the broad range of polymer modification routes in a fresh, current view representing a timely addition to the technical literature of this important area. Historically, blends, copolymers, or filled polymers have been developed to meet specific properties, or to optimize the cost/properties relationship. Using the gradient structure approach with conventional radical polymerization, it has been shown that it is possible to optimize properties if appropriate gradients in the composition of copolymer chains are obtained. An overview of the gradient structure approach for designing polymers has not appeared in the recent literature and this title covers the different methods used to modify properties, offering the whole range of ways to modify polymers in just one volume and making this an attractive option for a wide audience of practitioners. The approach for each chapter is to explain the fundamental principles of preparation, cover properties modification, describe future research and applications as examples of materials that may be prepared for specific applications, or that are already in use, in present day applications. The book is for readers that have a basic background in polymer science, as well as those interested in the different ways to combine or modify polymer properties. - Provides an integrated view on how to modify polymer properties - Presents the entire panorama of polymer properties modification in one reference, covering the essential information in each topic - Includes the optimization of properties using gradients in polymers composition or structure
Fundamental concepts coupled with practical, step-by-step guidance With its emphasis on core principles, this text equips readers with the skills and knowledge to design the many processes needed to safely and successfully manufacture thermoplastic parts. The first half of the text sets forth the general theory and concepts underlying polymer processing, such as the viscoelastic response of polymeric fluids and diffusion and mass transfer. Next, the text explores specific practical aspects of polymer processing, including mixing, extrusion dies, and post-die processing. By addressing a broad range of design issues and methods, the authors demonstrate how to solve most common processing problems. This Second Edition of the highly acclaimed Polymer Processing has been thoroughly updated to reflect current polymer processing issues and practices. New areas of coverage include: Micro-injection molding to produce objects weighing a fraction of a gram, such as miniature gears and biomedical devices New chapter dedicated to the recycling of thermoplastics and the processing of renewable polymers Life-cycle assessment, a systematic method for determining whether recycling is appropriate and which form of recycling is optimal Rheology of polymers containing fibers Chapters feature problem sets, enabling readers to assess and reinforce their knowledge as they progress through the text. There are also special design problems throughout the text that reflect real-world polymer processing issues. A companion website features numerical subroutines as well as guidance for using MATLAB®, IMSL®, and Excel to solve the sample problems from the text. By providing both underlying theory and practical step-by-step guidance, Polymer Processing is recommended for students in chemical, mechanical, materials, and polymer engineering.
Properties of Polymers: Their Correlation with Chemical Structure; Their Numerical Estimation and Prediction from Additive Group Contributions summarizes the latest developments regarding polymers, their properties in relation to chemical structure, and methods for estimating and predicting numerical properties from chemical structure. In particular, it examines polymer electrical properties, magnetic properties, and mechanical properties, as well as their crystallization and environmental behavior and failure. The rheological properties of polymer melts and polymer solutions are also considered. Organized into seven parts encompassing 27 chapters, this book begins with an overview of polymer science and engineering, including the typology of polymers and their properties. It then turns to a discussion of thermophysical properties, from transition temperatures to volumetric and calorimetric properties, along with the cohesive aspects and conformation statistics. It also introduces the reader to the behavior of polymers in electromagnetic and mechanical fields of force. The book covers the quantities that influence the transport of heat, momentum, and matter, particularly heat conductivity, viscosity, and diffusivity; properties that control the chemical stability and breakdown of polymers; and polymer properties as an integral concept, with emphasis on processing and product properties. Readers will find tables that give valuable (numerical) data on polymers and include a survey of the group contributions (increments) of almost every additive function considered. This book is a valuable resource for anyone working on practical problems in the field of polymers, including organic chemists, chemical engineers, polymer processers, polymer technologists, and both graduate and PhD students.
Advanced Processing, Properties, and Applications of Starch and Other Bio-based Polymers presents the latest cutting-edge research into the processing and applications of bio-based polymers, for novel industrial applications across areas including biomedical and electronics. The book is divided into three sections, covering processing and manufacture, properties, and applications. Throughout the book, key aspects of sustainability are considered, including improved utilization of available natural resources, sustainable design possibilities, cleaner production processes, and waste management. Focuses on starch-based polymers, examining the latest advances in processing and applications with this valuable category of biopolymer Highlights industrial sustainability considerations at all steps of the process, including when sourcing materials, designing and producing products, and dealing with waste Supports the processing and development of starch and other bio-based polymers with enhanced functionality for advanced applications
This book provides a unified mechanics and materials perspective on polymers: both the mathematics of viscoelasticity theory as well as the physical mechanisms behind polymer deformation processes. Introductory material on fundamental mechanics is included to provide a continuous baseline for readers from all disciplines. Introductory material on the chemical and molecular basis of polymers is also included, which is essential to the understanding of the thermomechanical response. This self-contained text covers the viscoelastic characterization of polymers including constitutive modeling, experimental methods, thermal response, and stress and failure analysis. Example problems are provided within the text as well as at the end of each chapter. New to this edition: · One new chapter on the use of nano-material inclusions for structural polymer applications and applications such as fiber-reinforced polymers and adhesively bonded structures · Brings up-to-date polymer production and sales data and equipment and procedures for evaluating polymer characterization and classification · The work serves as a comprehensive reference for advanced seniors seeking graduate level courses, first and second year graduate students, and practicing engineers
Polymers are used in everything from nylon stockings to commercial aircraft to artificial heart valves, and they have a key role in addressing international competitiveness and other national issues. Polymer Science and Engineering explores the universe of polymers, describing their properties and wide-ranging potential, and presents the state of the science, with a hard look at downward trends in research support. Leading experts offer findings, recommendations, and research directions. Lively vignettes provide snapshots of polymers in everyday applications. The volume includes an overview of the use of polymers in such fields as medicine and biotechnology, information and communication, housing and construction, energy and transportation, national defense, and environmental protection. The committee looks at the various classes of polymersâ€"plastics, fibers, composites, and other materials, as well as polymers used as membranes and coatingsâ€"and how their composition and specific methods of processing result in unparalleled usefulness. The reader can also learn the science behind the technology, including efforts to model polymer synthesis after nature's methods, and breakthroughs in characterizing polymer properties needed for twenty-first-century applications. This informative volume will be important to chemists, engineers, materials scientists, researchers, industrialists, and policymakers interested in the role of polymers, as well as to science and engineering educators and students.
This book deals with the polymers, different methods of synthesis, and synthesis of composites, as well as the different techniques used for polymer characterization. Most of the world’s industries extract the anomalous properties of polymers to make excellent cost-effective materials. Because of this, the types of polymers, their processing, and the analysis of their various properties are very significant. Readers will gain a thorough knowledge about the processing of different types of polymers and composites made from them, as well as their various applications. Suitable for classroom use but especially important for researchers, this book addresses: Adhesion of amorphous polymers with vitrified bulk and surface glass transition Functionalized biopolymers and their applications A new synthesis of p-Cresol-Adipamide-Formaldehyde copolymer resin and its applications as an ion-changer Correlating performance of commercial viscosity modifiers for formulating shear stable industrial lubricants Synthesis of phthalonitrile polymers in ionic liquid and microwave media Studies on nanocomposite polymer electrolytes doped with Ca3(PO4)2 for lithium batteries
Applied Mechanics of Polymers: Properties, Processing, and Behavior provides readers with an overview of the properties, mechanical behaviors and modeling techniques for accurately predicting the behaviors of polymeric materials. The book starts with an introduction to polymers, covering their history, chemistry, physics, and various types and applications. In addition, it covers the general properties of polymers and the common processing and manufacturing processes involved with them. Subsequent chapters delve into specific mechanical behaviors of polymers such as linear elasticity, hyperelasticity, creep, viscoelasticity, failure, and fracture. The book concludes with chapters discussing electroactive polymers, hydrogels, and the mechanical characterization of polymers. This is a useful reference text that will benefit graduate students, postdocs, researchers, and engineers in the mechanics of materials, polymer science, mechanical engineering and material science. Additional resources related to the book can be found at polymersmechanics.com. - Provides examples of real-world applications that demonstrate the use of models in designing polymer-based components - Includes access to a companion site from where readers can download FEA and MATLAB code, FEA simulation files, videos and other supplemental material - Features end-of-chapter summaries with design and analysis guidelines, practice problem sets based on real-life situations, and both analytical and computational examples to bridge academic and industrial applications
Polymer science is fundamentally interdisciplinary, yet specialists in one aspect, such as chemistry or processing, frequently encounter difficulties in understanding the effects of other disciplines on their own. This book describes clearly how polymer chemistry and polymer processing interact to affect polymer properties. As such, specialists in both disciplines can gain a deeper understanding of how these subjects underpin each other. Coverage includes step-by-step introductions to polymer processing technologies; details of fluid flow and heat transfer behaviour; shaping methods and physical processes during cooking and curing, and analyses of moulding and extrusion processes.
The sheer volume of topics which could have been included under our general title prompted us to make some rather arbitrary decisions about content. Modification by irradiation is not included because the activity in this area is being treated elsewhere. We have chosen to emphasize chemical routes to modification and have striven to pre sent as balanced a representation of current activity as time and page count permit. Industrial applications, both real and potential, are included. Where appropriate, we have encouraged the contributors to include review material to help provide the reader with adequate context. The initial chapter is a review from a historical perspective of polymer modification and contains an extensive bibliography. The remainder of the book is divided into four general areas: Reactions and Preparation of Copolymers Reactions and Preparation of Block and Graft Copolymers Modification Through Condensation Reactions Applications The chemical modification of homopolymers such as polyvinylchlo ride, polyethylene, poly(chloroalkylene sulfides), polysulfones, poly chloromethylstyrene, polyisobutylene, polysodium acrylate, polyvinyl alcohol, polyvinyl chloroformate, sulfonated polystyrene; block and graft copolymers such as poly(styrene-block-ethylene-co-butylene block-styrene), poly(I,4-polybutadiene-block ethylene oxide), star chlorine-telechelic polyisobutylene, poly(isobutylene-co-2,3-dimethyl- 1,3-butadiene), poly(styrene-co-N-butylmethacrylate); cellulose, dex tran and inulin, is described.