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This book provides an overview of polymer nanocomposites and hybrid materials with polyhedral oligomeric silsesquioxanes (POSS). Among inorganic nanoparticles, functionalized POSS are unique nano-building blocks that can be used to create a wide variety of hybrid and composite materials, where precise control of nanostructures and properties is required. This book describes the influence of incorporation of POSS moieties into (organic) polymer matrices on the mechanical, thermal and flammability behavior of composites and hybrid organic-inorganic materials. Importantly, POSS-containing materials can be bio-functionalized by linking e.g. peptides and growth factors through appropriate surface modification in order to enhance the haemo-compatibility of cardiovascular devices made of these materials. This volume includes descriptions of synthesis routes of POSS and POSS-containing polymeric materials (e.g. based on polyolefines, epoxy resins and polyurethanes), presentation of POSS’ role as flame retardants and as biocompatible linker, as well as the depiction of decomposition and ageing processes.
Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites: From Synthesis to Applications offers extensive coverage of polyhedral oligomeric silsesquioxanes and their nanocomposites, including their synthesis, characterization, interfacial interactions and advanced applications. Sections introduce essentials, information on their preparation and discussions on polymeric materials, including elastomers, thermoplastics, thermosetting polymers, polymer blends and IPNs. Further sections cover the latest analysis techniques, examine the properties of POSS-polymer nanocomposites, and discuss key application areas, such as biological, energy, defense, and space. Finally, issues surrounding industry implementation and lifecycle are explored. This is a valuable reference for researchers, scientists and advanced students in the areas of polymer composites and nanocomposites, polymer chemistry, polymer physics, polymer science, and materials science and engineering. In an industrial setting, this book will be of great interest to scientists, R&D professionals, and engineers across industries and disciplines. - Covers all aspects of polyhedral oligomeric silsesquioxanes (POSS) and their nanocomposites, including synthesis and characterization techniques, properties, analysis, applications and trends - Targets POSS nanocomposites, describing synthesis, characterization and the selection of POSS filler types according to polymeric material - Explains the preparation and utilization of POSS polymer nanocomposites for cutting-edge applications, including biological, energy, and defense field applications
The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions.
Combines chemistry and material science in order to provide a complete overview of the design, synthesis, and applications of organo-silica This book offers comprehensive and systematic coverage of the latest developments in functional hybrid silicon copolymers, their applications, and how they were developed in relation to previous works in the preparation of various functional groups terminated silicone materials. Silicon Containing Hybrid Copolymers begins with a chapter that introduces readers to organo-silicon materials. It then presents a chapter on reactive functionally terminated polyorganosiloxanes, and contains a section on the methods and advances of functionalized polyhedral oligomeric silsesquioxanes (POSS) and copolymers. Nanostructured self-assemblies from silicon containing hybrid copolymers are discussed?as are superhydrophobic materials derived from hybrid silicon. Other chapters examine silicone copolymers for healthcare and personal care applications; construction of organic optoelectronic materials by using polyhedral oligomeric silsesquioxanes (POSS); and 3D printing silicone materials and devices. The book also includes an overview of material toughening and fire retardancy in regards to hybrid POSS nanocomposites. This title: -Focuses on design and synthesis strategies, providing a valuable resource for researchers in academia and industry -Presents recent applications, with emphasis on the underlying strategies and the influence from previous designs, in fields such as healthcare and consumer care -Combines synthetic pathways with design specific considerations to provide the reader with greater control over the design process Silicon Containing Hybrid Copolymers is an ideal book for materials scientists, polymer chemists, and bioinorganic chemists.
Polymer Composites with Functional Nanoparticles: Synthesis, Properties, and Applications reviews the latest research in the area of polymer nanocomposites and functionalized nanoparticles, providing an introduction for those new to the field, and supporting further research and development. The book helps researchers and practitioners better understand the key role of nanoparticle functionalization for improving the compatibility of inorganic metallic nanomaterials with organic polymers, and for the fabrication of nanostructured materials with special properties. A range of nanoparticles, such as carbon nanotubes are covered, along with descriptions of the methods of functionalization to support better compatibility with polymer matrices. The book also discusses the various applications of this technology, including uses in electronics and the medical and energy industries. - Summarizes the latest research in functionalized nanoparticles for modification of polymer matrices, providing a valuable platform for further research - Includes functionalization of a range of nanoparticles for incorporation into nanocomposites, including carbon nanotubes, graphene, gold and silver, silica and clay - Provides detailed coverage of application areas, including energy, electronics, biomedical applications, and end-of-life considerations
This book is focused primarily on polymer nanocomposites, based on the author's research experience as well as open literature. The environmental health and safety aspects of nanomaterials and polymer nanocomposites, risk assessment and safety standards, and fire toxicity of polymer nanocomposites, are studied. In the final chapter, a brief overview of opportunities, trends, and challenges of polymer nanocomposites are included. Throughout the book, the theme is developed that polymer nanocomposites are a whole family of polymeric materials whose properties are capable of being tailored to meet specific applications. This volume serves as a general introduction to students and researchers just entering the field and to scholars from other subfields seeking information.
Silicon based materials and polymers are made of silicon containing polymers, mainly macromolecular siloxanes (silicones). This book covers the different kinds of siliconbased polymers: silicones, silsesquioxanes (POSS), and silicon-based copolymers. Other silicon containig polymers: polycarbosilanes, polysilazanes, siloxane-organic copolymers, silicon derived high-tech ceramics: silicon carbide and oxycarbide, silicon nitride, etc. have also a very important practical meaning and a hudge number of practical applications. These materials make up products in a variety of industries and products, including technical and medical applicatons. Polycrystalline silicon is the basic material for large scale photovoltaic (PV) applications as solar cells. Technical applications of crystalline (c-Si) and amorphous (a-Si) silicon (fully inorganic materials), silicon nanowires are still quickly growing, especially in the fi eld of microelectronics, optoelectronics, photonics. and photovoltaics, catalysts, and different electronic devices (e.g. sensors, thermoelectric devices). This book is ideal for researchers and as such covers the industrial perspective of using each class of silicon based materials. Discusses silanes, silane coupling agents (SCA), silica, silicates, silane modified fillers, silsesquioxanes, silicones, and other silicon polymers and copolymers for practical applications as polymeric materials and very useful ingredients in materials science.
Functional Nanocomposite Hydrogels: Synthesis, Characterization, and Biomedical Applications reviews how the unique properties of nanoscale composite materials make them ideal candidates for use in biomedical hydrogels. The book covers a range of key nanocomposite materials for use in biomedical hydrogels, including graphene quantum dot, cellulose and collagen nanocomposites. A wide selection of biomedical applications for functional nanocomposite hydrogels is explored, from drug delivery and cancer therapy, to wound healing and bioimaging. This is a key reference for those working in the fields of biomaterials, nanotechnology, pharmacology, biomedical engineering, and anyone with a particular interest in composites and hydrogels. To improve the properties of conventional hydrogels, nanoparticles or nanostructures are incorporated into the hydrogel networks, forming a composite hydrogel with specialized functional properties which are tailored to a specific biomedical application. - Reviews the benefits and challenges of nanocomposites as novel materials in biomedical hydrogels, providing the reader with a wider range of choice and improved options for hydrogel development - Describes the synthesis and characterization of nanocomposite hydrogels, offering end-to-end analysis of the process - Details the range of applications in biomedicine for nanocomposite hydrogels, including biosensing, antimicrobics and drug delivery
Polymer Nanocomposite Materials Discover an authoritative overview of zero-, one-, and two-dimensional polymer nanomaterials Polymer Nanocomposite Materials: Applications in Integrated Electronic Devices delivers an original and insightful treatment of polymer nanocomposite applications in energy, information, and biotechnology. The book systematically reviews the preparation and characterization of polymer nanocomposites from zero-, one-, and two-dimensional nanomaterials. The two distinguished editors have selected resources that thoroughly explore the applications of polymer nanocomposites in energy, information, and biotechnology devices like sensors, solar cells, data storage devices, and artificial synapses. Academic researchers and professional developers alike will enjoy one of the first books on the subject of this environmentally friendly and versatile new technology. Polymer Nanocomposite Materials discusses challenges associated with the devices and materials, possible strategies for future directions of the technology, and the possible commercial applications of electronic devices built on these materials. Readers will also benefit from the inclusion of: A thorough introduction to the fabrication of conductive polymer composites and their applications in sensors An exploration of biodegradable polymer nanocomposites for electronics and polymer nanocomposites for photodetectors Practical discussions of polymer nanocomposites for pressure sensors and the application of polymer nanocomposites in energy storage devices An examination of functional polymer nanocomposites for triboelectric nanogenerators and resistive switching memory Perfect for materials scientists and polymer chemists, Polymer Nanocomposite Materials: Applications in Integrated Electronic Devices will also earn a place in the libraries of sensor developers, electrical engineers, and other professionals working in the sensor industry seeking an authoritative one-stop reference for nanocomposite applications.
Polymer-Based Nanocomposites for Energy and Environmental Applications provides a comprehensive and updated review of major innovations in the field of polymer-based nanocomposites for energy and environmental applications. It covers properties and applications, including the synthesis of polymer based nanocomposites from different sources and tactics on the efficacy and major challenges associated with successful scale-up fabrication. The chapters provide cutting-edge, up-to-date research findings on the use of polymer based nanocomposites in energy and environmental applications, while also detailing how to achieve material's characteristics and significant enhancements in physical, chemical, mechanical and thermal properties. It is an essential reference for future research in polymer based nanocomposites as topics such as sustainable, recyclable and eco-friendly methods for highly innovative and applied materials are current topics of importance. - Covers a wide range of research on polymer based nanocomposites - Provides updates on the most relevant polymer based nanocomposites and their prodigious potential in the fields of energy and the environment - Demonstrates systematic approaches and investigations from the design, synthesis, characterization and applications of polymer based nanocomposites - Presents a useful reference and technical guide for university academics and postgraduate students (Masters and Ph.D.)