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Introduction to photochemistry and photophysics. Polymer structure and reactivity. Diffusion and permeability in polymers. Determination of scission and crosslinking in polymers. Photoprocesses in solid polymer matrices. Fluorescence. Excimers and exciplexes. Phosphorescence. Energy transfer and migration in polymers. Photochemistry of carbonyl-containing polymers. Photopolymerization. Photocyclization. Miscellaneous photoprocesses. Photo- and radiation chemistry of polymers.
Ein Lehrbuch eines exzellenten Autorenteams mit wissenschaftlicher Erfahrung und der Kompetenz im Schreiben didaktischer Texte zu allen Facetten der Photochemie und Photophysik: Grundlagen sowie ausgewählte Beispielen moderner Anwendungen und aus der heutigen Forschung.
S. Georgiou: Laser Cleaning Methodologies of Polymer Substrates; T. Lippert: Laser Application of Polymers; J. Krueger, W. Kautek: Ultrashort Pulse Laser Interactions with Polymers and Dielectrics; Y. Zhang: Synchrotron Radiation Direct Photo-Etching of Polymers.
Focusing on complex naturally-occurring and synthetic supramolecular arrays, this work describes the mechanism by which transition metal complexes bind to DNA and how the DNA scaffold modifies the photochemical and photophysical properties to bound complexes. It includes details of photoinduced electron transfer between intercalated molecules, and examines thermally and photochemically induced electron transfer in supramolecular assemblies consisting of inorganic molecular building blocks.
Provides scientists engaged in basic and applied polymer research with a clear understanding of the current status of polymer photophysics. Offers topics ranging from luminescence decay analysis of biologically important polymers to investigation of electronic energy relaxation in the synthesis of aromatic vinyl polymers using picosecond fluorescence spectroscopy. Provides discussions on energy migration in polymer films and solutions, as well as fluorescent conformational probes of polymers in solution, dye labeling techniques, kinetic spectroscopy, excitation migration, triplet antenna effect, and more.
Photochemistry in Microheterogeneous Systems provides an introduction to the subject of photochemistry in microheterogeneous systems. Emphasis is on the unimolecular and bimolecular reactions of electronically excited molecules in non-homogeneous media, as well as the application of photophysical and photochemical processes and techniques to the study of various microheterogeneous systems of chemical and biological interest, from normal and inverted micelles to vesicles and liposomes, monolayers, black lipid membranes, and liquid crystalline solvents. This monograph is comprised of 10 chapters and begins with an overview of microheterogeneous systems; excited-state processes and reactions; photochemistry in microheterogeneous systems; and structural and dynamical aspects of micellar aggregates. The discussion then turns to micellar photophysics and photochemistry, with emphasis on singlet-state and triplet-state reactions. Subsequent chapters focus on photoprocesses in a variety of microheterogeneous systems such as reversed micelles, microemulsions, lipids, surfactant vesicles, and liposomes; polymers, polyelectrolytes, and ion-exchange membranes; and molecular inclusion complexes. The final chapter is devoted to the photochemistry of molecules in the adsorbed state. This text is intended for graduate students and practicing chemists.
The degradation and stabilisation of polymeric materials is of crucial interest to any chemist working in this field. This book offers up-to-date information on light-related characteristics of polymers, and represents a compilation of specialised topics from prestigious international authorities in polymer photochemistry.
This is the most updated, comprehensive collection of monographs on all aspects of photochemistry and photophysics related to natural and synthetic, inorganic, organic, and biological supramolecular systems. Supramolecular Photochemistry: Controlling Photochemical Processes addresses reactions in crystals, organized assemblies, monolayers, zeolites, clays, silica, micelles, polymers, dendrimers, organic hosts, supramolecular structures, organic glass, proteins and DNA, and applications of photosystems in confined media. This landmark publication describes the past, present, and future of this growing interdisciplinary area.
In 1980 the New York Academy of Sciences sponsored a three-day conference on luminescence in biological and synthetic macromolecules. After that meeting, Professor Frans DeSchryver and I began to discuss the possibility of organizing a different kind of meeting, with time for both informal and in-depth discussions, to examine certain aspects of the application of fluorescence and phosphorescence spectroscopy to polymers. Our ideas developed through discussions with many others, particularly Professor Lucien Monnerie. By 1983, when we submitted our proposal to NATO for an Advanced Study Institute, the area had grown enormous ly. It is interesting in retrospect to look back on the points which emerged from these discussions as the basis around which the scientific program would be organized and the speakers chosen. We decided early on to focus on applications of these methods to provide information about polymer molecules and polymer systems: The topics would all relate to the conformation and dynamics of macromolecules, or to the morphology of polymer-containing systems. Another important decision was to expand the scope of the ASI to include certain photochemical techniques, parti cular ly laser flash pho to lys is. These appl icat ions were at the time quite new, but full of promise as important sources of information about polymers.