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Aqueous polymer dispersions are environmentally friendly and therefore they have replaced in many applications polymers dissolved in organic solvents. This substitution process is still ongoing. This book discusses the world of aqueous polymer dispersions from the viewpoint of how they are applied. For a better understanding it starts with a general description of the synthesis of polymer dispersions and their characterization. The following chapters are dedicated to a wide variety of applications, including history, modern processes, and typical formulations and performance. The selection and the usage of a polymer dispersion are not uniform around the world because of historical and regional differences of the technical developments and marketing demands. Leading scientists from industry contributed to this book ensuring that practical issues are emphasized.
A comprehensive and up to date survey of the science and technology of polymeric dispersions. The book discusses the kinetics and mechanisms of polymerization in dispersed media, examines the processes controlling particle morphology, presents both off-line and on-line methods for the characterization of polymer colloids, considers reactor engineering and control, and covers a wide variety of applications, such as latex paint formulations, encapsulation of inorganic particles, reactive latexes, adhesives, paper coating, and biomedical and pharmaceutical applications. Audience: A valuable resource for scientists and engineers, academic and industrial, who are involved in the manufacture or application of polymeric dispersions.
Polymeric Surfactants covers the structure and stability origins of these highly useful surfactants. Adsorption and solution properties in emulsions are discussed based on their underlying thermodynamics and kinetics. Research scientists and Ph.D. students investigating chemistry, chemical engineering and colloidal science will benefit from this text on polymeric surfactants and their value in preparation and stabilization of disperse systems.
Academic and industrial research around polymer-based colloids is huge. Edited by two world-renowned leaders in polymer science and engineering, this is a fundamental text for the field.
A dispersion is a system of unmixable phases in which one phase is continuous and at least one is finely distributed. Examples are found in many industrial applications, including emulsions, suspensions, foams, and geld. The control of their flow characteristics - rheology - is essential in their preparation, long-term physical stability and application. Filling the need for a practical, up-to-date book connecting the stability/instability of the dispersion to its rheological behavior, this title aids in understanding the principles of rheology and the techniques that can be applied. From the contents: * General Introduction * Interparticle Interactions and Their Combination * Principles of Viscoelastic Behavior * Rheology of Suspensions * Rheology of Emulsions * Rheology of Modifiers, Thickeners, and Gels * Use of Rheological Measurements for Assessment and Prediction of the Long-Term Physical Stability of Formulations (Creaming and Sedimentation)
Micro and Nanolignin in Aqueous Dispersions and Polymers: Interactions, Properties, and Applications presents the very latest research on lignin biorefinery treatments, production, chemistry, and refining, exploring a range of innovative applications of lignin and lignin-based composites at both the micro and the nanoscale. The book begins by presenting the latest developments in extraction methods and properties, with topics including methods for value-added microlignin, color characteristics, refining and functionalization, depolymerization for phenolic monomer production, and production of sulphur-free lignin nanoparticles. This is followed by in-depth sections focusing on the preparation of lignin for advanced applications at the microscale, then at the nanoscale, covering a range of areas such as construction, fiber manufacturing, food packaging, biomedicine, wood preservation, wastewater treatment, and agriculture. This valuable resource enables the reader to identify the high added value of a biomass residue and supports possible development and use for mass and niche high impact application sectors. This information is of interest to researchers, scientists, and advanced students, across bio-based polymers and bio-composites, polymer science and engineering, nanomaterials, chemistry, sustainable materials, materials science, and chemical engineering. Moreover, it is also addressed to the professionals that as well as those in an R&D industrial setting to are looking on ideas and perspectives on how to utilize bio-based materials in advanced industrial applications. Provides detailed information on extraction methods, properties, refining and functionalization processes Guides the reader through the preparation of lignin both at the micro and nanoscale, as a filler, a matrix, and in all-lignin composites Takes a design-for-application approach, opening the door to high value applications across a range of sectors
"Presents the latest research on the flow and structure of complex particulate sustemsions, the adsorption behavior of polymers, and the consolidation behavior and mechanical properties of films. Highlights recent advances in polymer functionality, conformation, and chemistry for biological, biomedical, and industrial applications."
The term latex covers emulsion polymers, polymer dispersions and polymer colloids. This review report provides a general overview of the emulsion polymerisation processes and explains how the resulting latices are used in industrial applications. The classes of emulsion polymers are surveyed and the commercial technologies and potential future uses discussed. An additional indexed section containing several hundred abstracts from the Polymer Library gives useful references for further reading.
Nanocomposite Structures and Dispersions summarizes the fundamentals and mechanistic approaches in preparation and characterization of colloidal nanoparticles and dispersions, providing the readers a systematic and coherent picture of the field. The book serves as an introduction to the interesting field of nanoscience based on polymer and metal colloidal nanoparticles, and also presents the basic knowledge of polymer colloids preparation. It places a special emphasis on polymer, inorganic and metal nanomaterials classified as nanoparticles, nanocrystals, nanorods, nanotubes, nanobelts, etc. deals with the chemistry of the reaction approaches by which polymer and metal particles are synthesized. The book explores both organic (synthetic and natural) and inorganic materials, as well as their hybrids. It describes in detail terms, definitions, theories, experiments, and techniques dealing with synthesis of polymer and metal particles. It also discusses a variety of synthetic approaches including emulsion, miniemulsion and microemulsion approaches, homogeneous and heterogeneous nucleation approaches under mild and high temperatures. There is also a chapter on modification and passivation of colloidal particles. This book would be of interest to chemical engineers, polymer chemists, organic chemists, colloid chemists, materials scientists and nanotechnologists. Although the text discusses nanoscience and nanotechnology from the viewpoint of a chemist, it would also appeal to those just entering the field and experts seeking information in other sub-fields. - Serves as a general introduction for those just entering the field and experts seeking information in other sub-fields - Variety of synthetic approaches is described including emulsion, miniemulsion and microemulsion approaches, hogeneous and heterogeneous nucleation approaches under mild and high temperatures - Focused on both the organic (synthetic and natural) and inorganic materials, and their hybrids
The progress in polymer science is revealed in the chapters of Polymer Science: A Comprehensive Reference, Ten Volume Set. In Volume 1, this is reflected in the improved understanding of the properties of polymers in solution, in bulk and in confined situations such as in thin films. Volume 2 addresses new characterization techniques, such as high resolution optical microscopy, scanning probe microscopy and other procedures for surface and interface characterization. Volume 3 presents the great progress achieved in precise synthetic polymerization techniques for vinyl monomers to control macromolecular architecture: the development of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization procedures, and atom transfer radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain transfer systems as the most often used controlled/living radical polymerization methods. Volume 4 is devoted to kinetics, mechanisms and applications of ring opening polymerization of heterocyclic monomers and cycloolefins (ROMP), as well as to various less common polymerization techniques. Polycondensation and non-chain polymerizations, including dendrimer synthesis and various "click" procedures, are covered in Volume 5. Volume 6 focuses on several aspects of controlled macromolecular architectures and soft nano-objects including hybrids and bioconjugates. Many of the achievements would have not been possible without new characterization techniques like AFM that allowed direct imaging of single molecules and nano-objects with a precision available only recently. An entirely new aspect in polymer science is based on the combination of bottom-up methods such as polymer synthesis and molecularly programmed self-assembly with top-down structuring such as lithography and surface templating, as presented in Volume 7. It encompasses polymer and nanoparticle assembly in bulk and under confined conditions or influenced by an external field, including thin films, inorganic-organic hybrids, or nanofibers. Volume 8 expands these concepts focusing on applications in advanced technologies, e.g. in electronic industry and centers on combination with top down approach and functional properties like conductivity. Another type of functionality that is of rapidly increasing importance in polymer science is introduced in volume 9. It deals with various aspects of polymers in biology and medicine, including the response of living cells and tissue to the contact with biofunctional particles and surfaces. The last volume is devoted to the scope and potential provided by environmentally benign and green polymers, as well as energy-related polymers. They discuss new technologies needed for a sustainable economy in our world of limited resources. Provides broad and in-depth coverage of all aspects of polymer science from synthesis/polymerization, properties, and characterization methods and techniques to nanostructures, sustainability and energy, and biomedical uses of polymers Provides a definitive source for those entering or researching in this area by integrating the multidisciplinary aspects of the science into one unique, up-to-date reference work Electronic version has complete cross-referencing and multi-media components Volume editors are world experts in their field (including a Nobel Prize winner)