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Nanoclays have evoked a great deal of attention lately for the preparation of novel nanocomposite materials for several applications. This is attributed to their lamellar structures, which are distinguished by having high in-plane strength and stiffness, as well as a high aspect ratio. Nanocomposites have exhibited an advanced gas and water barrier properties compared to the pristine polymers. Such advancement plays a major role in enhancing the coating industry, specifically for corrosion protection. One main factor attributing to coating failure is its inability to maintain low water and oxygen permeability thought its service life. The penetration of these elements through the coating leads to corrosion initiation under the coating. The addition of clay to polymeric coatings has great potential to improve the corrosion protection performance of the coatings. This chapter will present the recent advancement in the preparation and utilization of clay nanocomposites as enhanced coatings for corrosion protection.
Polymer-clay nanocomposites are formed through the union of two very different materials with organic and mineral pedigrees. The hybrid compositions, however, exhibit large increases in tensile strength, modulus, and heat distortion temperature as compared with the pristine polymer. The composites also have lower water sensitivity, reduced permeability to gases, and a similar thermal coefficient of expansion. All of these property improvements can be realized without a loss of clarity in the polymer. Further, it has been found that nanocomposites impart a level of flame retardance and UV resistance not present in the pure polymer. These improvements in performance properties at relatively low clay loading (typically 2 -10wt %) have stimulated intensive research in both industry and academia over the past decade. Polymer-Clay Nanocomposites presents the first comprehensive overview of the state of the art of these materials since they were first reported a decade ago. Covering both the theory and practical applications, this volume in the 'Wiley Series in Polymer Science' covers the key aspects of these important materials including: * Polymer-clay intercalates * The preparation and general properties of special practical and commercial significance (including strength, stiffness, toughness, permeability, fire retardation and chemical stability) * The elucidation of the structural and rheological factors influencing performance and processing properties Polymer-Clay Nanocomposites is an indispensable text for polymer scientists, composites formulators, materials engineers, resin producers, filters and additive producers as well as university lecturers, and organic and inorganic chemists working in this important and fascinating area.
Polymer-clay nanocomposites have flame-retardant, antimicrobial, anticorrosion and self-healing properties, they are biocompatible and environmentally benign. Edited by pioneers in the field, this book will explain the great potential of these materials and will bring together the combined physico-chemical, materials science and biological expertise to introduce the reader to the vibrant field of nanoclay materials. This book will provide an essential text for materials and polymers scientists in industry and academia.
Corrosion is an expensive and potentially dangerous problem in many industries. The potential application of different nanostructured materials in corrosion protection, prevention and control is a subject of increasing interest. Corrosion protection and control using nanomaterials explores the potential use of nanotechnology in corrosion control.The book is divided into two parts. Part one looks at the fundamentals of corrosion behaviour and the manufacture of nanocrystalline materials. Chapters discuss the impact of nanotechnology in reducing corrosion cost, and investigate the influence of various factors including thermodynamics, kinetics and grain size on the corrosion behaviour of nanocrystalline materials. There are also chapters on electrodeposition and the corrosion behaviour of electrodeposited nanocrystalline materials. Part two provides a series of case studies of applications of nanomaterials in corrosion control. Chapters review oxidation protection using nanocrystalline structures at various temperatures, sol- gel and self-healing nanocoatings and the use of nanoreservoirs and polymer nanocomposites in corrosion control.With its distinguished editors and international team of expert contributors, Corrosion protection and control using nanomaterials is an invaluable reference tool for researchers and engineers working with nanomaterials in a variety of industries including, aerospace, automotive and chemical engineering as well as academics studying the unique protection and control offered by nanomaterials against corrosion. Explores the potential use of nanotechnology and nanomaterials for corrosion prevention, protection and control Discusses the impact of nanotechnology in reducing corrosion cost and investigates various factors on the corrosion behaviour of nanocrystalline materials Provides a series of case studies and applications of nanomaterials for corrosion control
The field of polymer nanocomposites has become essential for engineering and military industries over the last few decades as it applies to computing, sensors, biomedical microelectronics, hard coating, and many other domains. Due to their outstanding mechanical and thermal features, polymer nanocomposite materials have recently been developed and now have a wide range of applications. Polymer Nanocomposites for Advanced Engineering and Military Applications provides emerging research on recent advances in the fabrication methods, properties, and applications of various nano-fillers including surface-modification methods and chemical functionalization. Featuring coverage on a broad range of topics such as barrier properties, biomedical microelectronics, and matrix processing, this book is ideally designed for engineers, industrialists, chemists, government officials, military professionals, practitioners, academicians, researchers, and students.
This Special Issue focuses on the current state-of-the-art of “Polymer Clay Nano-Composites” for biomedical, anticorrosion, antibacterial, and other applications. Clay–polymer composite nanomaterials represent an emerging area of research. Loading polymers with clay particles essentially enhances the composite strength features. Of particular interest are different nano-assembly methods, such as silane mono and multilayers, polyelectrolyte layer-by-layer assembly, and others. An important development was reached for tubular and fibrous clay nanoparticles, such as halloysite, sepiolite, and imogolite. Polymer clay nanoparticles can be prepared as sheets with 1-nm thickness and width of a few hundred nm (e.g., kaolin and montmorillonite). Fibrous clays significantly reinforce the nano-composites in the assembly with biopolymers and other green polymers, leading to functional hybrid bio nano-composites. The scope of this Special Issue comprehensively includes the synthesis and characterization of polymer clay nano-composites used for several applications, including nano-clay polymer composites and hybrid nano-assemblies.
Clay Nanoparticles: Properties and Applications sets out the major properties of clay nanoparticles and their technological applications. The first part of the book focuses on the characterization of nanoclays, including layered, fibrous and tubular clay minerals. The second part illustrates the current and potential applications of nanoclays within material science and biotechnology. These include the development of geopolymers and bionanocomposites based on sustainable polymers filled with ecocompatible nanoclay. The potential use of nanoclays as flame retardants is also discussed, along with the correlation between the properties and potential applications of several nanoclay types. In particular, the applications explored include nanoclays as drug delivery systems and for environmental protection. The book provides a complete and multidisciplinary exploration of nanoclays, highlighting a range of perspectives within current nanotechnology research. Assesses the advantages of using nanoclays instead of conventional clay materials in product design Describes the major characterization techniques – both experimental and computational – for nanoclays Explores new fabrication techniques based on pristine and modified clay nanoparticles that are being used both in materials science and biotechnology
Polymer-Based Nanoscale Materials for Surface Coatings presents the latest advances and emerging technologies in polymer-based nanomaterials for coatings, focusing on novel materials, characterization techniques, and cutting-edge applications. Sections present the fundamentals of surface preparation and nanocoatings, linking materials and properties, explaining the correlation between morphology, surface phenomena, and surface protection mechanism, and covering theory, modeling and simulation. Other presented topics cover characterization methods, with an emphasis on the latest developments in techniques and approaches. Aging and lifecycle assessment of coated surfaces and coatings are also discussed.Final sections explore advanced applications across a range of fields, including intelligent coatings for biomedical implants, self-healing coatings, syper-hydrophobicity, electroluminescence, sustainable edible coatings, marine antifouling, corrosion resistance, and photocatalytic coatings. Explains the fundamentals of coatings and surface protection, mechanisms, materials and properties, and modeling and simulation Presents detailed information on the latest characterization techniques to prepare nanoscale polymer coatings with enhanced properties Explores a broad range of state-of-the-art applications and considers aging and lifecycle assessments of coatings
Clay–Polymer Nanocomposites is a complete summary of the existing knowledge on this topic, from the basic concepts of synthesis and design to their applications in timely topics such as high-performance composites, environment, and energy issues. This book covers many aspects of synthesis such as in- situ polymerization within the interlamellar spacing of the clays or by reaction of pristine or pre-modified clays with reactive polymers and prepolymers. Indeed, nanocomposites can be prepared at industrial scale by melt mixing. Regardless the synthesis method, much is said in this book about the importance of theclay pre-modification step, which is demonstrated to be effective, on many occasions, in obtaining exfoliated nanocomposites. Clay–Polymer Nanocomposites reports the background to numerous characterization methods including solid state NMR, neutron scattering, diffraction and vibrational techniques as well as surface analytical methods, namely XPS, inverse gas chromatography and nitrogen adsorption to probe surface composition, wetting and textural/structural properties. Although not described in dedicated chapters, numerous X-ray diffraction patterns of clay–polymer nanocomposites and reference materials are displayed to account for the effects of intercalation and exfoliations of layered aluminosilicates. Finally, multiscale molecular simulation protocols are presenting for predicting morphologies and properties of nanostructured polymer systems with industrial relevance. As far as applications are concerned, Clay–Polymer Nanocomposites examines structural composites such as clay–epoxy and clay–biopolymers, the use of clay–polymer nanocomposites as reactive nanocomposite fillers, catalytic clay-(conductive) polymers and similar nanocomposites for the uptake of hazardous compounds or for controlled drug release, antibacterial applications, energy storage, and more. The most comprehensive coverage of the state of the art in clay–polymer nanocomposites, from synthesis and design to opportunities and applications Covers the various methods of characterization of clay–polymer nanocomposites - including spectroscopy, thermal analyses, and X-ray diffraction Includes a discussion of a range of application areas, including biomedicine, energy storage, biofouling resistance, and more
Corrosion Protection at the Nanoscale explores fundamental concepts on how metals can be protected at the nanoscale by using both nanomaterials-based solutions, including nanoalloys, noninhibitors and nanocoatings. It is an important reference resource for both materials scientists and engineers wanting to find ways to create an efficient corrosion prevention strategy. Nanostructure materials have been widely used in many products, such as print electronics, contact, interconnection, implant, nanosensors and display units to lessen the impact of corrosion. Traditional methods for protection of metals include various techniques, such as coatings, inhibitors, electrochemical methods (anodic and cathodic protections), metallurgical design are covered in this book. Nanomaterials-based protective methods can offer many advantages over their traditional counterparts, such as protection for early-stage, higher corrosion resistance, better corrosion control. This book also outlines these advantages and discusses the challenges of implementing nanomaterials as corrosion protection agents on a wide scale. Explains the main methods of detection, monitoring, testing, measurement and simulation of corrosion at the nanoscale Explores how metals can be protected at the nanoscale using nanotechnology and nanomaterials Discusses the major challenges of detecting and preventing corrosion at the nanoscale