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This report presents a cost analysis of Polylactic Acid (PLA) production starting from raw sugar The first section of the examined processis similar to Cargill process for lactic acid production, while the second section is similar to the NatureWorks process for polymerization of lactic acid. In this process, raw sugar (sucrose) is diluted and sucrose is hydrolyzed into glucose and fructose (invert sugars). The invert sugars are then fermented to produce lactic acid. Lactic Acid recovery from the fermentation broth is done by trialkylamine solvent extraction in the presence of carbon dioxide. An 88 wt% Lactic Acid solution in water is generated and further polymerized to form Polylactic Acid. This report was developed based essentially on the following reference(s): (1) US Patent 6472559, issued to Cargill in 2002 (2) US Patent 8674056, issued to NatureWorks in 2014 (3) EP Patent 1247808, issued to Cargill in 2003 Keywords: Dextrose, 2-Hydroxypropanoic Acid, Anaerobic Fermentation, Trialkyl Amine, Sodium Carbonate, Lactide, 2-Hydroxypropanoic Acid, Dow, Biodegradable Polymer
This report presents a cost analysis of Bio-Adipic Acid production from raw sugar using a fermentation process. The process examined is similar to BioAmber process. In this process, raw sugar (sucrose) is diluted and sucrose is hydrolyzed into glucose and fructose (invert sugars). The invert sugars are then fermented to produce Adipic Acid. This report was developed based essentially on the following reference(s): US Patent 20110269993, issued to BioAmber in 2011 Keywords: Bioadipic Acid, Hydrolysis, Dextrose, Hexanedioic Acid, Dicarboxylic Acid, Sucrose Inversion, Green Adipic Acid, Renewable Feedstock
This report presents a cost analysis of Propanol production from glycerol. In this process, crude glycerol (80 wt% glycerol content) is used as feedstock. This report was developed based essentially on the following reference(s): Keywords: Glycerin, Propyl Alcohol, Biodiesel, Quattor, Petrobras
This report presents a cost analysis of Polyisoprene production starting from raw sugar. The process examined is similar to Danisco/Goodyear process integrated with a typical solution polymerization process. In this process, raw sugar (sucrose) is diluted and sucrose is hydrolyzed into glucose and fructose (invert sugars). The invert sugars are then fed to an aerobic fermentation step to produce Isoprene, which is then polymerized to Polyisoprene. This report was developed based essentially on the following reference(s): Keywords: Dextrose, Genencor, DuPont, 2-Methyl-1,3-butadiene, Direct Fermentation, Synthetic Rubber, Goodyear, Goodrich, Snamprogetti, Ziegler Catalyst
This report presents a cost analysis of Polyethylene Furanoate (PEF) production starting from raw sugar and monoethylene glycol (MEG). The process examined is similar to the Avantium YXY process, followed by a process that copolymerizes FDCA and MEG. In this process, a raw sugar (sucrose) is inverted to glucose and fructose. The glucose is isomerized to fructose. Then, fructose is converted to methoxy methyl furan (MMF) intermediate, which is oxidized to FDCA. This process generates methyl acetate and methyl levulinate as by-products. The FDCA generated and MEG are polymerized to PEF in two polymerization steps in order to obtain Bottle-Grade PEF. This report was developed based essentially on the following reference(s): (1) US Patent 8519167, issued to Furanix Technologies B.V. in 2013 (2) US Patent 20160024039, issued to Furanix Technologies B.V. in 2016 (3) WO Patent 2015137807, issued to Furanix Technologies in 2015 Keywords: Polyethylene Furanoate, PEF, Green FDCA, Hydroxyl Methyl Furfural, HMF, Purified Terephthalic Acid, Polyethylene 2,5-Furandicarboxylate, MEG
This report presents a cost analysis of Lactic Acid production from raw sugar using a low pH fermentation process. The process examined is similar to Cargill process. In this process, raw sugar (sucrose) is diluted and sucrose is hydrolyzed into glucose and fructose (invert sugars). The invert sugars are then fermented to produce lactic acid. The process generates an 88 wt% lactic acid solution in water as final product. This report was developed based essentially on the following reference(s): (1) US Patent 20060094093, issued to Cargill in 2006 (2) US Patent 7736514, issued to BASF in 2010 Keywords: Dextrose, 2-Hydroxypropanoic Acid, Anaerobic Fermentation, Cell Recycle, Acid Tolerant Bacteria
This report presents a cost analysis of Lactic Acid production from raw sugar using a fermentation process. The process examined is similar to Corbion process. In this process, the fermentation broth is acidified in order to recover Lactic Acid and the product purification is realized by the use of a solvent. The process generates an 88 wt% Lactic Acid solution in water as final product. This report was developed based essentially on the following reference(s): (1) EP Patent 1220827, issued to Purac (now Corbion) in 2006 (2) US Patent 6747173, issued to Purac (now Corbion) in 2004 Keywords: Dextrose, 2-Hydroxypropanoic Acid, Anaerobic Fermentation, Calcium Carbonate, Sulfuric Acid
This report presents a cost analysis of Lactic Acid production from raw sugar using a fermentation process. The process examined is similar to Cargill process. In this process, Lactic Acid recovery from the fermentation broth is realized by trialkylamine solvent extraction in the presence of carbon dioxide. The final product is Food Grade Lactic Acid solution containing 88 wt% of Lactic Acid. This report was developed based essentially on the following reference(s): (1) US Patent 6472559, issued to Cargill in 2002 (2) "Hydrocarboxylic Acids", Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition Keywords: Dextrose, 2-Hydroxypropanoic Acid, Anaerobic Fermentation, Trialkyl Amine, Sodium Carbonate
This report presents a cost analysis of Polylactic Acid (PLA) production starting from corn The first section of the examined process is similar to Cargill process for lactic acid production, while the second section is similar to the NatureWorks process for polymerization of lactic acid. In this process, shelled corn is passed through a wet milling process to form corn starch, which, in turn, is hydrolyzed to dextrose, the feed for the fermentation process that generates lactic acid . Lactic Acid recovery from the fermentation broth is carried out via trialkylamine solvent extraction in the presence of carbon dioxide. A L-Lactic Acid solution in water is formed and further polymerized to form Polylactic Acid. The conversion of corn into dextrose forms some residues that are sold as by-product. This report was developed based essentially on the following reference(s): (1) US Patent 6472559, issued to Cargill in 2002 (2) US Patent 8674056, issued to NatureWorks in 2014 (3) EP Patent 1247808, issued to Cargill in 2003 Keywords: Corn, Corn Starch, 2-Hydroxypropanoic Acid, Anaerobic Fermentation, Trialkyl Amine, Sodium Carbonate, Lactide, 2-Hydroxypropanoic Acid, Dow, Biodegradable Polymer
This report presents a cost analysis of Invert Sugar Syrup production from raw sugar (sucrose) using a sucrose inversion process. The process examined is similar to European Sugar Holdings S.A.R.L. process. In this process, raw sugar (sucrose) is diluted and sucrose is hydrolyzed into glucose and fructose (invert sugar). This inversion reaction occurs in an ion-exchange resin bed. This report was developed based essentially on the following reference(s): US Patent 8404109, issued to European Sugar Holdings in 2013 Keywords: Liquid Sugar, Liquid Invert, Dextrose, Cation-Exchange, IX