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The role of external plasticisers is to increase the softness, flexibility and distensibility of polymer systems, particularly PVC. Additional effects such as the reduction of melt viscosity may be of prime importance in some cases. This report considers the whole subject of external plasticisers for polymers. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database provides useful references for further reading.
This book continues the tradition of the first two editions of the late W. S. Penn's original PVC Technology, and the extensively revised third (1971) edition prepared by myself and B. J. Lanham. In the present edition the original general format, and the arrange ment of chapters, have been largely preserved, but virtually nothing now remains of Penn's own text: a part of the contents is based on material from the 1971 TitowlLanham version (revised, updated and mainly rewritten): the rest is new, including, inter alia, several chapters specially contributed by experts from the plastics industry in the UK and Europe. The section listing international (ISO) and national (BS, ASTM and DIN) standards relevant to PVC, which was first intro duced (as Appendix 1) in the 1971 edition, proved a popularfeature: it has now been brought up to date and considerably extended. Two further appendices provide, respectively, comprehensive unit conver sion"tables (with additional information on some ofthe mostfrequently encountered units, and the SI units), and a list of many properties of interest in PVC materials, with definitions, typical numerical values, and references~to relevant standard test methods. For various reasons, work on this edition involved more than the usual quota of problems: I am truly grateful to the Publisher's Manag ing Editor, Mr G. B. Olley, for his understanding, patience, unfailing courtesy and friendly encouragement.
Polyvinyl chloride (PVC) has been around since the late part of the 19th century, although it was not produced commercially until the 1920s; it is the second largest consumed plastic material after polyethylene. PVC products can be rigid or flexible, opaque or transparent, coloured, and insulating or conducting. There is not just one PVC but a whole family of products tailor-made to suit the needs of each application. PVC is extremely cost effective in comparison to other plastics with a high degree of versatility in end-use and processing possibilities, as the reader will note from this book. It is durable, easily maintained, and can be produced in a large range of colours. As a result PVC finds use in an extensive range of applications in virtually all areas of human activity, including medical equipment, construction applications such as flexible roof membranes, pipes and window profiles, toys, automotive parts and electrical cabling. The PVC industry has also started to tackle some of its end-of-life issues. This practical guide provides comprehensive background on the resins and additives, their properties and processing characteristics, as well as discussion of product design and development issues. There have been, and still are, issues and perceptions over environmental and health acceptance covering vinyl chloride monomer, dioxins, phthalate plasticisers, and lead (and cadmium) based heat stabilisers and these are discussed in depth in this book. This book will be of interest to raw materials suppliers and processors or end-users of PVC, as well as anyone with a general interest in this versatile material: resins and additives properties and testing design issues processing, including post processing and assembly property enhancement sustainable development
The additive families are considered with an outline of the technical issues and the trends driving the markets. The main marketplaces for each additive type are discussed and the trends outlined. It contains an overview of the significant trends in the four largest plastics market sectors: packaging, construction, automotive and electrical and electronics. The report focuses on the important issues within Europe, with comment on the relevant trends in North America and Asia. The report provides discussion of the trends in material consumption and specific additive groups. It also includes brief company news and information for some of the leading additive suppliers.
In recent years there have been certain scare stories about the possible negative effects on human health from some of these materials. However, today, it is realised that it is often not the polymers themselves, but their monomers or the additives used that are responsible for these negative effects. And the reality is that a lot of polymers are used in medical applications without adverse effects on patients. Hence, the dividing line between whether something is toxic and harmful to health or not (and if it is, under what conditions) is a very critical issue and therefore, there needs to be a better understanding of these systems. This book presents the available information on the eternal triangle of plastics and rubber and health, to enable a better understanding of the facts.
This volume represents a continuation of the Polymer Science and Technology series edited by Dr. D. M. Brewis and Professor D. Briggs. The theme of the series is the production of a number of stand alone volumes on various areas of polymer science and technology. Each volume contains short articles by a variety of expert contributors outlining a particular topic and these articles are extensively cross referenced. References to related topics included in the volume are indicated by bold text in the articles, the bold text being the title of the relevant article. At the end of each article there is a list of bibliographic references where interested readers can obtain further detailed information on the subject of the article. This volume was produced at the invitation of Derek Brewis who asked me to edit a text which concentrated on the mechanical properties of polymers. There are already many excellent books on the mechanical properties of polymers, and a somewhat lesser number of volumes dealing with methods of carrying out mechanical tests on polymers. Some of these books are listed in Appendix 1. In this volume I have attempted to cover basic mechanical properties and test methods as well as the theory of polymer mechanical deformation and hope that the reader will find the approach useful.
Providing an overview of the nature, manufacture, structure, properties, processing and applications of commercially available plastics materials, this book includes chapters on material selection and special polymers.
Fibres, Films, Plastics and Rubbers: A Handbook of Common Polymers focuses on polymeric materials. The book first discusses a list of sections on individual polymers. Topics include olefin and vinyl-type, carbohydrate-type, synthetic condensation-type, organo-silicon, and inorganic polymers, as well as proteins. The text also looks at list of sections on specific properties and related information. The book then discusses polyethylenes, polypropylene, and polytetrafluoroethylene. The text also examines polystyrene. Concerns include the structure, chemistry, physics, fabrication, serviceability, and utilization of these materials. The text also focuses on indene and coumarone/indene resins; polyvinyl acetate and alcohol; polyvinyl formal, acetal, and butyral; and polyacrylates and polymethacrylates. The book then examines the structure, chemistry, physics, fabrication, serviceability, and utilization of polyvinyl chloride, polyvinylidene chloride, cellulose, and cellulose acetate. The book also discusses the structure, chemistry, physics, fabrication, serviceability, and utilization of cellulose nitrate, cellulose ethers, starch, and regenerated proteins. Same type of evaluation is also done to polyamides, epoxy resins, polyformaldehyde, natural rubber, and nitrile rubbers. The text is a valuable source of information for readers interested in polymeric materials.