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Corrosion, Volume 1: Metal/Environment Reactions is concerned with the subject of corrosion, with emphasis on the control of the environmental interactions of metals and alloys used as materials of construction. Corrosion is treated as a synthesis of corrosion science and corrosion engineering. This volume is comprised of nine chapters; the first of which provides an overview of the principles of corrosion and oxidation, with emphasis on the electrochemical mechanism of corrosion and how the kinetics of cathodic and anodic partial reactions control the rate of overall corrosion reaction. Attention then turns to the effects of environmental factors such as concentration, velocity, and temperature based on the assumption that either the anodic or cathodic reaction, but not both, is rate-controlling. The corrosion of ferrous and non-ferrous metals and alloys, as well as rarer and noble metals, is considered. The reader is also introduced to high-temperature corrosion and mechanical factors that affect corrosion. This book concludes with topics of electrochemistry and metallurgy relevant to corrosion, including the nature of the electrified interface between the metal and the solution; charge transfer across the interface under equilibrium and non-equilibrium conditions; overpotential and the rate of an electrode reaction; and the hydrogen evolution reaction and hydrogen absorption by ferrous alloys. This book will be of value to students as well as workers and engineers in the field of corrosion.
Volume II of the High Speed Aerodynamics and Jet Propulsion series. This volume includes treatments of all aspects of combustion necessary to the development of jet and rocket engines. Originally published in 1956. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.
The properties of materials at high temperature play a vital role in their processing and practical use. The real properties of materials at elevated temperatures are very often governed by defects in their structure. Lattice defects may consist of point defects like vacancies, interstitial atoms or substituted atoms. These classes are discussed in general and specifically for oxides, nitrides, carbides and sulfides. Defect aggregates, shear structures and adaptive structures are also described. Special attention is paid to hydrogen defects which seem to play an important role in several materials.Defects in solids lead to transport properties such as diffusion and conductivity. These themes are thoroughly treated in this book, with examples from various materials being provided. Special attention is paid to the transport properties of grain boundaries. In high temperature corrosion and other types of oxidation, the diffusion of atoms through the reaction products is often the rate limiting step of the reaction. This book takes the reader from the theoretical treatment of defects to applications in high temperature corrosion. Reactions between metals and pure oxygen lead to the formation of oxides on the surface, and the reaction rates may often be related to the diffusion coefficients of the oxide. However, in practical use alloys are subjected to other severe gaseous atmospheres which may often lead to accelerated attack on the material. The severest condition, namely where a salt deposit is combined with oxidizing gases, is called hot corrosion. This and other types of corrosion are also covered. Finally, a chapter is devoted to the prevention of corrosive attack on materials by the addition of rare earth metals.The book has been published in honour of Professor Per Kofstad on the occasion of his 60th birthday. Professor Kofstad has for many years been active in the field of high temperature chemistry in all its aspects, from basic and theoretical work to its application in high temperature corrosion of metals and alloys. The various chapters have been contributed by his friends and colleagues, all of whom are international experts in the field.
This book deals with the fundamental description of the thermodynamics and kinetics of high temperature oxidation of sulphidation of metals and intermetallic compounds. It is a comprehensive account of a large amount of new work in the field including modelling, analysis and a range of experimental methods. The text deals with both basic materials, and some current high temperature structural materials.
A straightforward treatment describing the oxidation processes of metals and alloys at elevated temperatures. This 2006 second edition retains the fundamental theory but incorporates advances made in understanding degradation phenomena. The first half provides an authoritative introduction to the basic principles, covering thermodynamics and mechanisms of high temperature corrosion of metals and alloys. The latter half extends the discussion to oxidation processes in complex systems, from reactions in mixed environments to protective techniques, including coatings and atmosphere control. The authors provide a logical and expert treatment of the subject, producing a revised edition that will be a comprehensive guide to material scientists and engineers requiring an understanding of this elementary process.
The problem of stress corrosion cracking (SCC), which causes sudden failure of metals and other materials subjected to stress in corrosive environment(s), has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Stress corrosion cracking reviews the fundamentals of the phenomenon as well as examining stress corrosion behaviour in specific materials and particular industries.The book is divided into four parts. Part one covers the mechanisms of SCC and hydrogen embrittlement, while the focus of part two is on methods of testing for SCC in metals. Chapters in part three each review the phenomenon with reference to a specific material, with a variety of metals, alloys and composites discussed, including steels, titanium alloys and polymer composites. In part four, the effect of SCC in various industries is examined, with chapters covering subjects such as aerospace engineering, nuclear reactors, utilities and pipelines.With its distinguished editors and international team of contributors, Stress corrosion cracking is an essential reference for engineers and designers working with metals, alloys and polymers, and will be an invaluable tool for any industries in which metallic components are exposed to tension, corrosive environments at ambient and high temperatures. - Examines the mechanisms of stress corrosion cracking (SCC) presenting recognising testing methods and materials resistant to SCC - Assesses the effect of SCC on particular metals featuring steel, stainless steel, nickel-based alloys, magnesium alloys, copper-based alloys and welds in steels - Reviews the monitoring and management of SCC and the affect of SCC in different industries such as petrochemical and aerospace
Includes the institute's Proceedings.