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With an approach that stresses the fundamental solid state behaviour of minerals, this 1995 text surveys the physics and chemistry of earth materials.
Presents cross-referenced essays on basic topics related to planetology and Earth from space; each essay includes an annotated bibliography.
Deep Earth: Physics and Chemistry of the Lower Mantle and Core highlights recent advances and the latest views of the deep Earth from theoretical, experimental, and observational approaches and offers insight into future research directions on the deep Earth. In recent years, we have just reached a stage where we can perform measurements at the conditions of the center part of the Earth using state-of-the-art techniques, and many reports on the physical and chemical properties of the deep Earth have come out very recently. Novel theoretical models have been complementary to this breakthrough. These new inputs enable us to compare directly with results of precise geophysical and geochemical observations. This volume highlights the recent significant advancements in our understanding of the deep Earth that have occurred as a result, including contributions from mineral/rock physics, geophysics, and geochemistry that relate to the topics of: I. Thermal structure of the lower mantle and core II. Structure, anisotropy, and plasticity of deep Earth materials III. Physical properties of the deep interior IV. Chemistry and phase relations in the lower mantle and core V. Volatiles in the deep Earth The volume will be a valuable resource for researchers and students who study the Earth's interior. The topics of this volume are multidisciplinary, and therefore will be useful to students from a wide variety of fields in the Earth Sciences.
This work introduces into the chemistry, materials science and technology of Rare Earth Elements. The chapters by experienced lecturers describe comprehensively the recent studies of their characteristics, properties and applications in functional materials. Due to the broad range of covered topics as hydrogen storage materials, LEDs or permanent magnets this work gives an up-to-date presentation of this fascinating research.
Earth Materials Earth materials encompass the minerals, rocks, soil and water that constitute our planet and the physical, chemical and biological processes that produce them. Since the expansion of computer technology in the last two decades of the twentieth century, many universities have compressed or eliminated individual course offerings such as mineralogy, optical mineralogy, igneous petrology, sedimentology and metamorphic petrology and replaced them with Earth materials courses. Earth materials courses have become an essential curricular component in the fields of geology, geoscience, Earth science, and many related areas of study. This textbook is designed to address the needs of a one- or two-semester Earth materials course, as well as individuals who want or need an expanded background in minerals, rocks, soils and water resources. Earth Materials, Second Edition, provides: Comprehensive descriptive analysis of Earth materials Color graphics and insightful text in a logical integrated format Field examples and regional relationships with graphics that illustrate concepts discussed Examples of how concepts discussed can be used to address real world issues Contemporary references from current scientific journals related to developments in Earth materials research Summative discussions of how Earth materials are interrelated with other science and non-science fields of study Additional resources, including detailed descriptions of major rock-forming minerals and keys for identifying minerals using macroscopic and/or optical methods, are available online at www.wiley.com/go/hefferan/earthmaterials Earth Materials, Second Edition, is an innovative, visually appealing, informative and readable textbook that addresses the full spectrum of Earth materials.
Among the numerous applications of the rare-earth elements, the field of catalysis accounts for a large number. Catalysis represents approximately 20% of the total market sales of rare earths worldwide. As a matter of fact two main applications have been prominent in the last decades: zeolite stabilization for fluid cracking catalysts, and automotive post-combustion catalytic treatment. The oldest use of rare earths in catalysis deals with the structural and chemical stabilization of the zeolites for petroleum cracking applications. For a long time this has been an area of application for non-separated rare earths. The addition of several percent of rare earths in the pores of the zeolite results in a strong surface acidity, which is essential for an efficient conversion of high-weight molecules into lighter species, like low-octane fuel, even in the very aggressive conditions of the petroleum industry. The popular demand for high-quality air in spite of the traffic congestion in large cities resulted in larger and larger constraints in the emission exhaust from cars. Thus highly efficient catalysts have had to be designed, and due to the combination of its redox properties and very good thermal stability, cerium oxide has been since the beginning, early in the 1980s, a major component of the three-way catalysts (TWC) now used in all modern gasoline cars. The future of rare earths in catalysis is probably bright. The fact that approximately 400 patents are applied for yearly in the area since 1992 is an illustration of a very active area. Usage of rare earths in catalysis is expected to grow due to their highly specific properties. Instead of the physical properties used in electronic applications, one deals now with redox properties, water and thermal stability, coordination numbers and so forth. The rare earths are so specific in these properties that their use can hardly be avoided, not only for the beauty of academic studies but also for the development of industrial applications with immediate influence on everyday life. Careful control of the synthesis conditions and the definition of optimum composition in each case are the keys to the preparation of highly performing compounds for catalytic applications. They must actually be considered as high performance products with functional properties, and not just chemical species. Chapters devoted primarily to catalysis have been published in earlier volumes of the Handbook. In this volume several more are added. The first is an extension of the earlier chapter 43, on interactions at surfaces of metals and alloys, to reactions such as hydrogenation, methanation, ammonia synthesis, saturated hydrocarbon reactions, dehydrogenation of hydrogenated materials, hydrodesulfurization, and carbon monoxide oxidation. The second chapter reports on the wide variety of catalyzed reactions involving metals and alloys in the innovated form of metal overlayers or bimetallic compounds with some transition metals produced from ammonia solutions. This is followed by a chapter on catalysis with mixed oxides usually having perovskite or perovskite-related structures. Then follows a comprehensive discussion on the background and current role of cerium oxide and associated materials for post-treatment of exhaust gases for pollution control. These three-way catalysts (TWC) are designed to render harmless the CO, NOx, and unburned hydrocarbons from internal combustion engines. The next chapter considers the wide field of zeolite catalysts containing rare earths from their historic use in petroleum refining in the 1960s to other petrochemical and fine chemical applications today. The final chapter documents the use of the triflates (the trifluoro-methane-sulfonyl group which is a hard Lewis acid in both aqueous and organic solutions) as versatile catalysts in carbon-carbon bond-forming reactions. Their stability in the presence of water, in spite of their being hard Lewis acids, enhances their growing usefulness.
An understanding of rocks and the minerals that comprise them lies at the core of every geologist’s education. As more curricula combine mineralogy and petrology into a single course, Raymond and Johnson have responded with a concise introduction to the study of Earth materials. The authors have written at a level that won’t intimidate students encountering fundamental concepts for the first time, yet with enough rigor that they’ll be well prepared for future study. A broad approach to the subject that incorporates fluids and soils will appeal to instructors who teach engineering and environmental science students as well as future geoscientists. Abundant illustrations reinforce all of the ideas in the text. Many images are presented in color, with additional color images available at waveland.com/Raymond-Johnson. Problems appear throughout the book, encouraging a deeper understanding for students. Helpful appendices make it easy for instructors to assign further exercises in rock and mineral identification as well as optical mineralogy and petrography.
This book contains chapters on deep Earth materials, compositional models, and geophysical studies of material circulation which together provide an invaluable synthesis of deep Earth research.
Key concepts in mineralogy and petrology are explained alongside beautiful full-color illustrations, in this concisely written textbook.