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An examination of the fundamental nature of polyelectrolytes, static and dynamic properties of salt-free and salt-added solutions, and interactions with other charged and neutral species at interfaces with applications to industry and medicine. It applies the Metropolis Monte Carlo simulation to calculate counterion distributions, electric potentia
The Advances in Chemical Physics series provides the chemical physics field with a forum for critical, authoritative evaluations of advances in every area of the discipline. This volume explores topics from Thermodynamic Properties of Polyelectrolyte Solutions to ion-binding of polyelectrolytes. The book features: The only series of volumes available that presents the cutting edge of research in chemical physics Contributions from experts in this field of research Representative cross-section of research that questions established thinking on chemical solutions An editorial framework that makes the book an excellent supplement to an advanced graduate class in physical chemistry or chemical physics
This book contains a number of articles inspired by the NATO Advanced Study Institute on 'Charged and Reactive Polymers l' held in France in June 1972. This general title indicates simply the intention of a series. The meeting dealt mainly with the fundamental problems of the physical chemistry of polyelectrolytes in solution. Some of the articles reproduce the lectures exactly as they were delivered. Some others have been modified to a greater or lesser extent, and this as a result of improvements or new inspiration arising from comments and discussions. In previous larger conferences on macromolecules, polyelectrolytes constituted only a marginal problem and few were the individual communications or short was the time al10tted to this subject. In other meetings of a biophysical character the uses of the techniques of charged macromolecules have been exposed with less attention given to the theories or to the creation or interpretation of these techniques. AU of us felt that the time had come to enumerate and to evaluate this increasing science of polyelectrolytes which has become of major interest. During the whole period of the Institute physical chemists discussed their mutual problems for more than a week, and of ten far into the night! One of the advantages of such an Institute is to enable the Directors and the mem bers of the Scientific Committee to establish a logical order in the lectures; this order has been respected in the present edition.
This book offers a valuable reference source to graduate and post graduate students, engineering students, research scholars polymer engineers from industry. The book provides the reader with current developments of theoretical models describing the thermodynamics polyelectrolytes as well as experimental findings. A particular emphasis is put on the rheological description of polyelectrolyte solutions and hydrogels.
An examination of the fundamental nature of polyelectrolytes, static and dynamic properties of salt-free and salt-added solutions, and interactions with other charged and neutral species at interfaces with applications to industry and medicine. It applies the Metropolis Monte Carlo simulation to calculate counterion distributions, electric potentials, and fluctuation of counterion polarization for model DNA fragments.
This lab manual guides chemists through demonstrations of synergistic effects between polyelectrolytes and nanoparticles. After a short introduction into the field of polyelectrolytes and polyelectrolyte characterization, the book discusses the role of polyelectrolytes in the process of nanoparticle formation. The book also explains methods for characterization of the polyelectrolyte-modified nanoparticles.
The Advances in Chemical Physics series provides the chemical physics field with a forum for critical, authoritative evaluations of advances in every area of the discipline. • This is the only series of volumes available that presents the cutting edge of research in chemical physics. • Includes contributions from experts in this field of research. • Contains a representative cross-section of research that questions established thinking on chemical solutions • Structured with an editorial framework that makes the book an excellent supplement to an advanced graduate class in physical chemistry or chemical physics
It is difficult to imagine how our highly evolved technological society would function, or how life would even exist on our planet, if polymers did not exist. The intensive study of polymeric systems, which has been under way for several decades, has recently yielded new insights into the properties of assemblies of these complex molecules and the physical principles that govern their behavior. These developments have included new concepts to describe aspects of the many body behavior in these systems, microscopic analyses that bring our understanding of these systems much closer to our understanding of simple liquids and solids, and the discovery of novel chemistry that these molecules can catalyze. This special topic volume of Advances in Chemical Physics surveys a number of these recent accomplishments. Supplemented with more than 250 illustrations, it provides a significant, up-to-date selection of papers by inter-nationally recognized researchers. Topics include: * Theory of Polyelectrolyte Solutions * Star Polymers: Experiment, Theory, and Simulation * Tethered Polymer Layers * Living Polymers * Transport and Kinetics in Electroactive Polymers Self-contained, authoritative, and timely, Polymeric Systems makes the cutting edge of polymer research available to scientists in every branch of chemical physics. Contributors to POLYMERIC SYSTEMS JEAN-LOUIS BARRAT, Département de Physique des Matériaux, Université Claude Bernard-Lyon l, France A. BAUMGÄRTNER, Institut für Festkörperforschung, Germany M. A. CARIGNANO, Department of Chemistry, Purdue University, West Lafayette, Indiana LEWIS J. FETTERS, Corporate Research Science Laboratories, Exxon Research and Engineering Company, Annandale, New Jersey SANDRA C. GREER, Department of Chemical Engineering, University of Maryland at College Park GARY S. GREST, Corporate Research Science Laboratories, Exxon Research and Engineering Company, Annandale, New Jersey JOHN S. HUANG, Corporate Research Science Laboratories, Exxon Research and Engineering Company, Annandale, New Jersey JEAN-FRANÇOIS JOANNY, Institut Charles Sadron, France MICHAEL E. G. LYONS, Electroactive Polymer Research Group, Physical Chemistry Laboratory, University of Dublin, Ireland M. MUTHUKUMAR, Department of Polymer Science, University of Massachusetts, Amherst, Massachusetts DIETER RICHTER, Institut für Festkörperforschung, Germany I. SZLEIFER, Department of Chemistry, Purdue University, West Lafayette, Indiana
This book contains a number of articles inspired by the NATO Advanced Study Institute on 'Charged and Reactive Polymers l' held in France in June 1972. This general title indicates simply the intention of a series. The meeting dealt mainly with the fundamental problems of the physical chemistry of polyelectrolytes in solution. Some of the articles reproduce the lectures exactly as they were delivered. Some others have been modified to a greater or lesser extent, and this as a result of improvements or new inspiration arising from comments and discussions. In previous larger conferences on macromolecules, polyelectrolytes constituted only a marginal problem and few were the individual communications or short was the time al10tted to this subject. In other meetings of a biophysical character the uses of the techniques of charged macromolecules have been exposed with less attention given to the theories or to the creation or interpretation of these techniques. AU of us felt that the time had come to enumerate and to evaluate this increasing science of polyelectrolytes which has become of major interest. During the whole period of the Institute physical chemists discussed their mutual problems for more than a week, and of ten far into the night! One of the advantages of such an Institute is to enable the Directors and the mem bers of the Scientific Committee to establish a logical order in the lectures; this order has been respected in the present edition.
Polyelectrolytes and their Applications is the second volume in the series 'Charged and Reactive Polymers'. The important areas of polyelectrolyte applications, i.e., biomedicine, water purification, petroleum recovery and drag reduction, are pre sented along with discussions of the fundamental principles of polyelectrolyte chem istry and physics. This book should be of interest to scientists such as physicians, biochemists, polymer chemists and chemical engineers involved in applications of these materials. The first part of the book is devoted to the basic properties of polyelectrolytes in general, namely to the factors influencing the chain conformation of charged polymers in solution and to their counterion selectivity. It also contains methods of synthesis and new concepts of charge stabilized polymer colloids and of polyelectrolyte ca talysis. The second part describes recent information on the properties and biological effects of already well-known natural polyelectrolytes such as heparin and DNA and recently developed polymers such as pyran and polyionenes. The effects of poly anions and polycations on normal and transformed cells as well as on acetylcholine receptors follow. This part is of particular interest to scientists involved in biological research.