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Volume 6 in the well-establish series Advances in Electrochemical Science and Engineering covers - among others - such important topics as time dependent modulation techniques and computer modeling by continuum and non-continuum methods. As in all previous volumes, the editors have succeeded in selecting highly topical areas of electrochemical research and in presenting authors who are leaders in their fields. The result is a compelling set of reviews which serves equally well as an excellent and up-to-date source of information for experienced researchers active in the field as well as an introduction for newcomers. From reviews of previous volumes: 'This is an essential book for researchers in electrochemistry; it covers areas of both fundamental and practical importance, with reviews of high quality. The material is very well presented and the choice of topics reflects a balanced editorial policy that is welcomed.' The Analyst
Reviews the science and engineering of high-temperature corrosion and provides guidelines for selecting the best materials for an array of system processes High-temperature corrosion (HTC) is a widespread problem in an array of industries, including power generation, aerospace, automotive, and mineral and chemical processing, to name a few. This book provides engineers, physicists, and chemists with a balanced presentation of all relevant basic science and engineering aspects of high-temperature corrosion. It covers most HTC types, including oxidation, sulfidation, nitridation, molten salts, fuel-ash corrosion, H2S/H2 corrosion, molten fluoride/HF corrosion, and carburization. It also provides corrosion data essential for making the appropriate choices of candidate materials for high-temperature service in process conditions. A form of corrosion that does not require the presence of liquids, high-temperature corrosion occurs due to the interaction at high temperatures of gases, liquids, or solids with materials. HTC is a subject is of increasing importance in many areas of science and engineering, and students, researchers, and engineers need to be aware of the nature of the processes that occur in high-temperature materials and equipment in common use today, especially in the chemical, gas, petroleum, electric power, metal manufacturing, automotive, and nuclear industries. Provides engineers and scientists with the essential data needed to make the most informed decisions on materials selection Includes up-to-date information accompanied by more than 1,000 references, 80% of which from within the past fifteen years Includes details on systems of critical engineering importance, especially the corrosion induced by low-energy radionuclides Includes practical guidelines for testing and research in HTC, along with both the European and International Standards for high-temperature corrosion engineering Offering balanced, in-depth coverage of the fundamental science behind and engineering of HTC, High Temperature Corrosion: Fundamentals and Engineering is a valuable resource for academic researchers, students, and professionals in the material sciences, solid state physics, solid state chemistry, electrochemistry, metallurgy, and mechanical, chemical, and structural engineers.
This volume of Modern Aspects of Electrochemistry contains six chapters. The first four chapters are about phenomena of interest at the microscopic level and the last two are on phenomena at the macroscopic level. In the first chapter, Uosaki and Kita review various theoretical models that have been presented to describe the phenomena that occur at an electrolyte/ semiconductor interface under illumination. In the second chapter, Orazem and Newman discuss the same phenomena from a different point of view. In Chapter 3, Bogus lavsky presents state-of-the-art considerations of transmembrane potentials and other aspects of active transport in biological systems. Next, Burke and Lyons present a survey of both the theoretical and the experimental work that has been done on hydrous oxide films on several metals. The last two chapters cover the topics of the production of chlorine and caustic and the phenomena of electrolytic gas evol ution. In Chapter 5, Hine et al. describe the engineering aspects of the three processes used in the chi or-alkali industry, and in Chapter 6, Sides reviews the macroscopic phenomena of nucleation, growth, and detachment of bubbles, and the effect of bubbles on the conduc tivity of and mass transfer in electrolytes.
Passivity of Metals and Semiconductors covers the proceedings of the Fifth International Symposium on Passivity, held in Bombannes, France on May30 - June3, 1983. The said symposium is concerned with passivity of metallic materials, localized corrosion, experimental techniques, and classical techniques such as optical techniques and electron spectroscopy. The book is divided into five sections. Section I deals with the concepts involved in the composition-transport phenomena and covers topics such as the transport of oxygen and water in oxide layers; the kinetics of oxidation of silicon; and the oxidation rate laws of metals that form nonstoichiometric oxides. Section II covers related techniques and their specific applications such as study of passivity of iron by in situ methods; optical methods in the study of passive films; and the analysis of multiple layer surface films by modulated reflection spectroscopy. Section III tackles amorphous metals - their passivity, their depassivation and repassivation in localized corrosion, and a comparison of models for localized breakdown of passivity. Part IV discusses the photoelectrochemistry of semiconductors; Part V tackles passivation and localized corrosion of stainless steels. The text is recommended for organic chemists, metallurgists, and engineers who would like to know more about the passivity of metals and their applications in different fields.
Combustion science in general and combustion chemistry in particular, have seen a resurgence of interest in recent years due to the importance of energy and pollution problems in modern society. Leading authorities in combustion science and related fields have contributed to this volume which reviews elementary reactions in combustion systems, dynamics of molecules, wave propagation in chemical reactions, chemistry of fuel rich combustion and modelling and simulation of combustion processes involving detailed chemistry and new developments in laser diagnostics.