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The Sixth Edition of this classic work comprises the most comprehensive and current guide to infrared and Raman spectra of inorganic, organometallic, bioinorganic, and coordination compounds. From fundamental theories of vibrational spectroscopy to applications in a variety of compound types, this has been extensively updated. New topics include the theoretical calculations of vibrational frequencies (DFT method), chemical synthesis by matrix co-condensation reactions, time-resolved Raman spectroscopy, and more. This volume is a core reference for chemists and medical professionals working with infrared or Raman spectroscopies and an excellent textbook for graduate courses.
In the first part of this voLume the oxide hydrates incLuding the hydroxides and hydroxide oxides of MOIII to MoVJare described. (The anhydrous moLybdenum oxides can be found in the voLume "MoLybdän" Erg.-Bd. B 1,1975.) The compounds Mo0 ·nHp with n=1 and 2 are 3 investigated in detail. They are true oxide hydrates and not "molybdic acids". For complete ness the hydrogen insertion compounds H with O.
The 193-nm photolysis of the NCO radical has been investigated. NCO was generated from the reaction of CN + O2, where the CN was produced by 193-nm photolysis of C2N2 close to the nozzle of a pulsed jet. A second 193-nm photon dissociated the NCO radical during the same laser pulse. At this photon energy both the N-CO and the NC-O bonds may break. N(2D, 2P) and CO products have been detected using vacuum ultraviolet laser induced fluorescence. A direct measurement of the N(2D):N(2P) branching ratio yielded an upper limit of 72 +/- 18. The CO vibrational distribution was modeled with prior distributions for each of the contributing channels with co-products N(4S, 2D and 2P). Combination of the results from the prior model and the direct measurement yielded a branching ratio of N(4S): N(2D): N(2P) of (5.1 +/- 1.8):(93.6 +/- 4.8):(1.3 +/- 0.3). For the N(2D) + CO product channel, the average energy disposal into product relative translation (7%) and CO vibration (24%) was determined, leaving 69% of the available energy to appear as CO rotation. This observation suggests that the geometry of the dissociating state of NCO is likely to be bent.