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Hardbound. This book gives a detailed description of the observed behaviour of photochemical oxidants, especially ozone, on the urban, regional, and global scales. The volume includes: basic introductions to the biochemistry and physics of biogenic and anthropogenic production of photochemical oxidant precursors; room-temperature rate coefficients for gas-phase reactions as an aid to intercomparison; the synthesis of recent observations of photochemical oxidants over all spatial and temporal scales of interest; and a large selection of examples from the real atmosphere.Throughout, the emphasis is on understanding topics under simplified or controlled conditions; this book will be of great value to photochemists, environmental chemists, and all those concerned with (atmospheric) pollution.
The Committee on Ozone-Forming Potential for Reformulated Gasoline was asked whether the existing body of scientific and technical information is sufficient to permit a robust evaluation and comparison of the emissions from motor vehicles using different reformulated gasolines based on their ozone-forming potentials and to assess the concomitant impact of that approach on air-quality benefits of the use of oxygenates within the RFG program. As part of its charge, the committee was asked to consider (1) the technical soundness of various approaches for evaluating and comparing the relative ozone-forming potentials of RFG blends, (2) technical aspects of various air-quality issues related to RFG assessment, and (3) the sensitivity of evaluations of the relative ozone-forming potentials to factors related to fuel properties and the variability of vehicle technologies and driving patterns.
Urban Climates is the first full synthesis of modern scientific and applied research on urban climates. The book begins with an outline of what constitutes an urban ecosystem. It develops a comprehensive terminology for the subject using scale and surface classification as key constructs. It explains the physical principles governing the creation of distinct urban climates, such as airflow around buildings, the heat island, precipitation modification and air pollution, and it then illustrates how this knowledge can be applied to moderate the undesirable consequences of urban development and help create more sustainable and resilient cities. With urban climate science now a fully-fledged field, this timely book fulfills the need to bring together the disparate parts of climate research on cities into a coherent framework. It is an ideal resource for students and researchers in fields such as climatology, urban hydrology, air quality, environmental engineering and urban design.
Here is the most comprehensive and up-to-date treatment of one of the hottest areas of chemical research. The treatment of fundamental kinetics and photochemistry will be highly useful to chemistry students and their instructors at the graduate level, as well as postdoctoral fellows entering this new, exciting, and well-funded field with a Ph.D. in a related discipline (e.g., analytical, organic, or physical chemistry, chemical physics, etc.). Chemistry of the Upper and Lower Atmosphere provides postgraduate researchers and teachers with a uniquely detailed, comprehensive, and authoritative resource. The text bridges the "gap" between the fundamental chemistry of the earth's atmosphere and "real world" examples of its application to the development of sound scientific risk assessments and associated risk management control strategies for both tropospheric and stratospheric pollutants. - Serves as a graduate textbook and "must have" reference for all atmospheric scientists - Provides more than 5000 references to the literature through the end of 1998 - Presents tables of new actinic flux data for the troposphere and stratospher (0-40km) - Summarizes kinetic and photochemical date for the troposphere and stratosphere - Features problems at the end of most chapters to enhance the book's use in teaching - Includes applications of the OZIPR box model with comprehensive chemistry for student use
Photochemistry of Air Pollution provides information pertinent to air pollution and atmospheric chemistry. This book discusses the photochemical reactions produced by sunlight may convert relatively harmless pollutants into substances that constitute a nuisance, create possible health hazard, and cause economic problem to humans. Organized into 10 chapters, this book starts with an overview of the problem of air pollution, particularly photochemical smog. This text then discusses the factors that collectively determine the amount and spectral distribution of the radiation entering a surface layer of the atmosphere. Other chapters compare the specific absorption rates of several absorbers that are present in the air during periods of photochemical smog, including oxygen, ozone, nitrogen dioxide, sulfur dioxide, ketones, peroxides, and particulate matter. The final chapter deals with the process of formation of the substances responsible for the physiological effects of eye irritation and plant damage. This book is a valuable resource for photochemists and air pollution scientists.
Revised and updated in 2000, Basic Physical Chemistry for the Atmospheric Sciences provides a clear, concise grounding in the basic chemical principles required for studies of atmospheres, oceans, and earth and planetary systems. Undergraduate and graduate students with little formal training in chemistry can work through the chapters and the numerous exercises within this book before accessing the standard texts in the atmospheric chemistry, geochemistry, and the environmental sciences. The book covers the fundamental concepts of chemical equilibria, chemical thermodynamics, chemical kinetics, solution chemistry, acid and base chemistry, oxidation-reduction reactions, and photochemistry. In a companion volume entitled Introduction to Atmospheric Chemistry (2000, Cambridge University Press) Peter Hobbs provides an introduction to atmospheric chemistry itself, including its applications to air pollution, acid rain, the ozone hole, and climate change. Together these two books provide an ideal introduction to atmospheric chemistry for a variety of disciplines.
Acid rain, photochemistry, long-range transport of pollutants, greenhouse gas emissions and aerosols have dominated tropospheric air pollution for the last 30 years of the 20th century. At the start of the 21st century, acid rain is subject to planned improvement in Europe and North America, but is still a growing problem in Asia. Tropospheric ozone is understood much better, but the problem is still with us, and desirable levels are difficult to achieve over continental Europe. The heterogeneous chemistry that is responsible for ozone depletion in the stratosphere is now reasonably clear, but there is on-going interest in the sources and sinks of CFC (chlorofluorocarbon) replacements in the troposphere. There is also increasing interest in indoor air quality, and the origin and health implications of atmospheric particles. Perhaps most important on a global perspective, intensive research has not yet determined the relationship between greenhouse gases, aerosols and surface temperature. The climactic implications of these are now more urgent than ever.This book, the first in the Developments in Environmental Science series, consists of a collection of authoritative reviews and essays on the science and application of air pollution research at the start of this new century.
Thoroughly restructured and updated with new findings and new features The Second Edition of this internationally acclaimed text presents the latest developments in atmospheric science. It continues to be the premier text for both a rigorous and a complete treatment of the chemistry of the atmosphere, covering such pivotal topics as: * Chemistry of the stratosphere and troposphere * Formation, growth, dynamics, and properties of aerosols * Meteorology of air pollution * Transport, diffusion, and removal of species in the atmosphere * Formation and chemistry of clouds * Interaction of atmospheric chemistry and climate * Radiative and climatic effects of gases and particles * Formulation of mathematical chemical/transport models of the atmosphere All chapters develop results based on fundamental principles, enabling the reader to build a solid understanding of the science underlying atmospheric processes. Among the new material are three new chapters: Atmospheric Radiation and Photochemistry, General Circulation of the Atmosphere, and Global Cycles. In addition, the chapters Stratospheric Chemistry, Tropospheric Chemistry, and Organic Atmospheric Aerosols have been rewritten to reflect the latest findings. Readers familiar with the First Edition will discover a text with new structures and new features that greatly aid learning. Many examples are set off in the text to help readers work through the application of concepts. Advanced material has been moved to appendices. Finally, many new problems, coded by degree of difficulty, have been added. A solutions manual is available. Thoroughly updated and restructured, the Second Edition of Atmospheric Chemistry and Physics is an ideal textbook for upper-level undergraduate and graduate students, as well as a reference for researchers in environmental engineering, meteorology, chemistry, and the atmospheric sciences. Click here to Download the Solutions Manual for Academic Adopters: http://www.wiley.com/WileyCDA/Section/id-292291.html
The presence of nanomaterials, whether designed for photochemistry or not, can have dramatic impacts on environmental, plant, and animal systems. In order to fully utilize nanomaterials for photochemical and other applications, it is necessary to design and manage them in a way that avoids undesirable or unexpected consequences. To provide a solid foundation, this book covers basic principles of photochemistry and fundamentals of nanomaterials and then provides insight into photochemical based nanomaterial applications and environmental behavior of nanomaterials.