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This book presents the novel concept of photo-switched biodegradation of bioplastics which is one of the important methods to overcome plastic waste issues in oceans. The different chapters discuss topics associated with a wide range of biorefinery plant cultivation, cell bioengineering in silico/wet, plastic design with photo-controlled biodegradation, photocatalysis design, evaluation of biodegradability, polymer toxicity, and plastic edibility. The book contributes to various Sustainable Development Goals such as SDG 14—Life Below Water; SDG 9—Industry, Innovation and Infrastructure; SDG 12—Responsible Consumption and Production; and SDG 15—Life on Land. It is a useful source for academic scientists in the fields of organic chemistry, photocatalysts, organic/inorganic composites, cell biology, plant biology, plastic processing, social control of wastes, environmental science, marine technology, and engineers. The book plays a big part in paradigm-changing innovation and transforms the petrochemical industry which has reached maturity, into a biochemical industry.
This book describes how man-made litter, primarily plastic, has spread into the remotest parts of the oceans and covers all aspects of this pollution problem from the impacts on wildlife and human health to socio-economic and political issues. Marine litter is a prime threat to marine wildlife, habitats and food webs worldwide. The book illustrates how advanced technologies from deep-sea research, microbiology and mathematic modelling as well as classic beach litter counts by volunteers contributed to the broad awareness of marine litter as a problem of global significance. The authors summarise more than five decades of marine litter research, which receives growing attention after the recent discovery of great oceanic garbage patches and the ubiquity of microscopic plastic particles in marine organisms and habitats. In 16 chapters, authors from all over the world have created a universal view on the diverse field of marine litter pollution, the biological impacts, dedicated research activities, and the various national and international legislative efforts to combat this environmental problem. They recommend future research directions necessary for a comprehensive understanding of this environmental issue and the development of efficient management strategies. This book addresses scientists, and it provides a solid knowledge base for policy makers, NGOs, and the broader public.
This book shows how the use of biodegradable plastics in agriculture can have a profound positive impact on plasticulture. Starting with an organic chemistry approach to biodegradable and compostable plastics, both natural and synthetic, it then analyzes the technological and agronomic aspects of existing bioplastics for protected cultivation (mulching, direct cover, low tunnels). It describes the new sprayable biodegradable mulching method, which is based on the use of waterborne polysaccharides and cellulosic fibers. A further chapter describes the research and technology of biodegradable plastics for different agricultural practices. It also includes chapters on life cycle assessment (LCA) of biodegradable plastics for agriculture, and existing and developing standards in the field. It is a valuable resource for agronomists, chemical and materials engineers, polymer technologists and scientists, as well as for a more general readership interested in the application of green chemistry principles to the vast world of crop production. Mario Malinconico is Research Director at the Institute of Polymers, Composites and Biomaterials, National Research Council, Italy. /p
Algae Based Polymers, Blends, and Composites: Chemistry, Biotechnology and Material Sciences offers considerable detail on the origin of algae, extraction of useful metabolites and major compounds from algal bio-mass, and the production and future prospects of sustainable polymers derived from algae, blends of algae, and algae based composites. Characterization methods and processing techniques for algae-based polymers and composites are discussed in detail, enabling researchers to apply the latest techniques to their own work. The conversion of bio-mass into high value chemicals, energy, and materials has ample financial and ecological importance, particularly in the era of declining petroleum reserves and global warming. Algae are an important source of biomass since they flourish rapidly and can be cultivated almost everywhere. At present the majority of naturally produced algal biomass is an unused resource and normally is left to decompose. Similarly, the use of this enormous underexploited biomass is mainly limited to food consumption and as bio-fertilizer. However, there is an opportunity here for materials scientists to explore its potential as a feedstock for the production of sustainable materials. - Provides detailed information on the extraction of useful compounds from algal biomass - Highlights the development of a range of polymers, blends, and composites - Includes coverage of characterization and processing techniques, enabling research scientists and engineers to apply the information to their own research and development - Discusses potential applications and future prospects of algae-based biopolymers, giving the latest insight into the future of these sustainable materials
Due to the possibility that petroleum supplies will be exhausted in the next decades to come, more and more attention has been paid to the production of bacterial pl- tics including polyhydroxyalkanoates (PHA), polylactic acid (PLA), poly(butylene succinate) (PBS), biopolyethylene (PE), poly(trimethylene terephthalate) (PTT), and poly(p-phenylene) (PPP). These are well-studied polymers containing at least one monomer synthesized via bacterial transformation. Among them, PHA, PLA and PBS are well known for their biodegradability, whereas PE, PTT and PPP are probably less biodegradable or are less studied in terms of their biodegradability. Over the past years, their properties and appli- tions have been studied in detail and products have been developed. Physical and chemical modifications to reduce their cost or to improve their properties have been conducted. PHA is the only biopolyester family completely synthesized by biological means. They have been investigated by microbiologists, molecular biologists, b- chemists, chemical engineers, chemists, polymer experts, and medical researchers for many years. PHA applications as bioplastics, fine chemicals, implant biomate- als, medicines, and biofuels have been developed. Companies have been est- lished for or involved in PHA related R&D as well as large scale production. It has become clear that PHA and its related technologies form an industrial value chain in fermentation, materials, feeds, and energy to medical fields.
In the past 25 years, plastic products have gained universal use not only in food, clothing and shelter, but also in the transportation, construction, medical and leisure industries. Whereas previously synthetic plastics were developed as durable substitute products, increasing concern for the global environment and solid waste management has resulted in an urgent demand for biodegradable plastics. The main topics of the Third International Scientific Workshop were as follows: 1. Biodegradation of polymers and plastics 2. Environmental degradation of plastics 3. Synthesis and properties of new biodegradable plastic materials 4. Biodegradation and morphologies of polymer blends 5. Development of biodegradation test methods 6. Governmental policy, regulation and standards.
Introduction to Bioplastics Engineering is a practical, user-friendly reference for plastics engineers working with biopolymers and biodegradable plastics that addresses topics that are required for the successful development of cohesive bioplastic products. While there has been considerable demand for the use of bioplastics in industry, processing these bioplastics is a big challenge. The book provides plastics engineers and researchers with a fundamental, practical understanding of the differences between bioplastics and biodegradable polymers, along with guidance on the different methods used to process bioplastics. The book also covers additives and modifiers for biopolymers and their effect on properties. Examples include commercial applications of bioplastics, current bioplastics being developed, and future trends in the industry. This enables engineers, researchers, technicians, and students to understand the decisive relationship between different processing techniques, morphology, mechanical properties, and the further applications of bio-based polymers. The book presents a true engineering approach for the industry on the processing of biopolymers and biodegradable plastics – discussing the ease of use of the polymer, mechanical and thermal properties, rate of biodegradation in particular environments, and pros and cons of particular bioplastics. - Enables engineers, researchers, technicians, and students to understand the decisive relationship between different processing techniques, morphology, mechanical properties, and the further applications of bio-based polymers. - Covers additives and modifiers for biopolymers and their effect on properties - Includes examples that illustrate the commercial applications of bioplastics, current bioplastics being developed, and future trends in the industry
Biodegradable polymers have experienced strong growth over the last three years and are set to make further inroads into markets traditionally dominated by conventional thermoplastics in future. Four main classes of biodegradable polymers are analysed in this report, polylactic acid (PLA), starch-based polymers, synthetic biodegradable polymers, such as aromatic aliphatic co-polyesters, and polyhydroxyalkanoates (PHA). The report analyses their key performance properties, applications development, market drivers and future prospects. Each product section also contains an estimate of market size by world region and end use market, plus forecasts to 2010. There is also an analysis of key suppliers and their products.
Over the few coming decades, bio-based and biodegradable plastics produced from sustainable bioresources should essentially substitute the prevalent synthetic plastics produced from exhaustible hydrocarbon fossils. To the greatest extend, this innovative trend has to apply to the packaging manufacturing area and especially to food packaging implementation. To supply the rapid production increment of biodegradable plastics, there must be provided the effective development of scientific-technical potential that promotes the comprehensive exploration of their structural, functional, and dynamic characteristics. In this regard, the transition from passive barrier materials preventing water and oxygen transport as well as bacteria infiltration to active functional packaging that ensures gas diffusion selectivity, antiseptics' and other modifiers' release should be based on the thorough study of biopolymer crystallinity, morphology, diffusivity, controlled biodegradability and life cycle assessment. This Special Issue accumulates the papers of international teams that devoted to scientific and industrial bases providing the biodegradable material development in the barrier and active packaging as well as in agricultural applications. We hope that book will bring great interest to the experts in the area of sustainable biopolymers.