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This book deals with the processes behind cycles of the phosphate and nitrogen compounds in sediment and the phosphate equilibria between the sediment and the overlying water. In most waters, excessive concentrations of these compounds causes eutrophication: rapid, choking growth of algae. The chapters of this book probe the chemicals involved in considerable detail, and offer the complete understanding needed to remediate or prevent pollution problems.
This book deals with the processes behind cycles of the phosphate and nitrogen compounds in sediment and the phosphate equilibria between the sediment and the overlying water. In most waters, excessive concentrations of these compounds causes eutrophication: rapid, choking growth of algae. The chapters of this book probe the chemicals involved in considerable detail, and offer the complete understanding needed to remediate or prevent pollution problems.
Phosphorus, an essential nutrient, is removed from the oceans only through burial with marine sediments. Organic phosphorus (Porg) constitutes an important fraction (ca. 25%) of total-P in marine sediments. However, given the inherent lability of primary Porg biochemicals, it is a puzzle that any Porg is preserved in marine sediments. The goal of this thesis was to address this apparent paradox by linking bulk and molecular-level Porg information. A newly-developed sequential extraction method, which isolates sedimentary Porg reservoirs based on solubility, was used in concert with 31P nuclear magnetic resonance spectroscopy (31P-NMR) to quantify Porg functional group concentrations. The coupled extraction/31P-NMR method was applied to three sediment cores from the Santa Barbara Basin, and the first-ever high-resolution depth profiles of molecular-level Porg distribution during diagenesis were generated. These depth profiles were used to consider regulation of Porg distribution by biomass abundance, chemical structure, and physical protection mechanisms. Biomass cannot account for more than a few percent of sedimentary Porg. No evidence for direct structural control on remineralization of Porg was found. Instead, sorptive protection appears to be an important mechanism for Porg preservation, and structure may act as a secondary control due to preferential sorption of specific Porg compound classes.
This volume is of great importance to humans and other living organisms. The study of water quality draws information from a variety of disciplines including chemistry, biology, mathematics, physics, engineering, and resource management. University training in water quality is often limited to specialized courses in engineering, ecology, and fisheries curricula. This book also offers a basic understanding of water quality to professionals who are not formally trained in the subject. The revised third edition updates and expands the discussion, and incorporates additional figures and illustrative problems. Improvements include a new chapter on basic chemistry, a more comprehensive chapter on hydrology, and an updated chapter on regulations and standards. Because it employs only first-year college-level chemistry and very basic physics, the book is well-suited as the foundation for a general introductory course in water quality. It is equally useful as a guide for self-study and an in-depth resource for general readers.