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This vastly expanded 2nd edition contains all the new developments since 1985. It describes significant new phenolic resin chemistry, new applications with up-to-date developments, and includes detailed standardized test methods important for ISO 9001 ff certification.
The legacy of Leo Hendrik Baekeland and his development of phenol formal- hyde resins are recognized as the cornerstone of the Plastics Industry in the early twentieth century, and phenolic resins continue to ?ourish after a century of robust growth. On July 13, 1907, Baekeland ?led his “heat and pressure” patent related to the processing of phenol formaldehyde resins and identi?ed their unique utility in a plethora of applications. The year 2010 marks the Centennial Year of the prod- tion of phenolic resins by Leo Baekeland. In 1910, Baekeland formed Bakelite GmbH and launched the manufacture of phenolic resins in Erkner in May 1910. In October 1910, General Bakelite began producing resins in Perth Amboy, New Jersey. Lastly, Baekeland collaborated with Dr. Takamine to manufacture phenolic resins in Japan in 1911. These events were instrumental in establishing the Plastics Industry and in tracing the identity to the brilliance of Dr. Leo Baekeland. Phenolic resins remain as a versatile resin system featuring either a stable, thermoplastic novolak composition that cures with a latent source of formaldehyde (hexa) or a heat reactive and perishable resole composition that cures thermally or under acidic or special basic conditions. Phenolic resins are a very large volume resin system with a worldwide volume in excess of 5 million tons/year, and its growth is related to the gross national product (GNP) growth rate globally.
Phenolic resins, also known as phenol–formaldehyde resins, are synthetic polymers that are produced from the reaction of phenol or substituted phenol with formaldehyde at high temperatures. These are widely used in wood adhesives, molding compounds, and laminates. The resins are flame-retardant, demonstrate high heat resistance, high tensile strength, and low toxicity, and generate low smoke. In the report, the phenolic resins market is segmented on the basis of product type, application, and region. Phenolic Resin Market size estimated to reach at USD 19.13 billion in 2026. Alongside, the market is anticipated to grow at a CAGR of 5.4% during the forecast period. The global phenolic resins market has experienced a notable growth and it has been projected that the global market will see stable growth during the forecast period. The high mechanical strengths, low toxicity, heat resistance, low smoke and other several properties has made the phenolic resins to make their use in the applications such as in laminations, wood adhesives, molding compound, construction, automobile and others. Growing demand of these applications has increased the production of phenolic resins to meet the current market demand. Also, phenolic resins is used in flame retardant which is very crucial for automobiles and aircrafts. This book basically deals with general reaction of phenols with aldehydes, the resoles, curing stages of resoles, kinetics of a stage reaction, chemistry of curing reactions, kinetics of the curing reaction, the novolacs, decomposition products of resites, acid cured resites, composition of technical resites, mechanisms of rubber vulcanization with phenolic resins, thermosetting alloy adhesives, vinyl phenolic structural adhesives, nitrile phenolic structural adhesives, phenolic resins in contact adhesives, chloroprene phenolic contact adhesives, nitrile phenolic contact adhesives, phenolic resins in pressure sensitive adhesives, rubber reinforcing resins, resorcinol formaldehyde latex systems, phenolic resin chemistry, bio-based phenolic resins, flexibilization of phenolic resins, floral foam (Phenolic Foam) with resin manufacturing, lignin-based phenol formaldehyde (LPF) resins, phenol formaldehyde resin, alkaline phenol formaldehyde resin, furfuryl alcohol phenol urea formaldehyde resin, phenol formaldehyde resin (Shell Sand Resin), phenol formaldehyde resin (Cold Box Resin), effluent treatment plant, standards and legislation, marketing of thermoset resins, process flow sheet, sample plant layout and photographs of machinery with supplier’s contact details. A total guide of phenolic resins and entrepreneurial success in one of today's most lucrative resin industry. This book is one-stop guide to one of the fastest growing sectors, where opportunities abound for manufacturers, retailers, and entrepreneurs. This is the only complete handbook on Phenolic resins.
"The sciences as a whole are slowly but gradually drifting away from life and are only returning after adetour". Goethe Detours should be avoided. The picture we are presenting here of the current theory in phenolic resin chemistry and the technical application of phenolic resins is based on day-to-day experiences in research, pro4uction and marketing, however, with the background of economic relevance. This book, then, is not to be regarded as a systematic collection and evaluation of the literature, although the literature up to July, 1978 has generally been taken into consideration. The audience to which this book is directed is wide-ranging: chemists, engineers, marketing professionals and students. We show where the first fully synthetic polymers, phenolic resins, stand today and what their future iso Taking a look back over their development, one is only more deeply convinced that after a wide variety of adaptions, they still possess the tech nical and economic strengths which allow for their further market growth and with it, a full appreciation of their value. We would like to extend our gratitude to all friends and promotors, in particular to those who helped and encouraged us with advice and assistance. Andre Knop Walter Scheib Frankfurt, January 1979 Table of Contents Historical and Economic Development of Phenolic Resins 1. History . . . 1 1.1. 1.2. Market Position 5 References. . 8 Raw Materials . 10 2. 10 2.1. Phenols. . . 10 2.1.l. Physical Properties of Phenol .
Loaded with practical knowledge, Reactive Polymers Fundamentals and Applications: A Concise Guide to Industrial Polymers comprehensively presents the state-of-art of methods and materials for the formulation of polymeric resins. It is an indispensable tool for chemists, engineers, and manufacturers who use, formulate, and cure raw materials into final products. The text focuses on the chemical modification of properties during the final stage of part fabrication from plastics. Newer applications range from the small scale, such as dental fillings, to industrial processes for batch fabrication. The book covers resin groups in major use in industry and under active research and development.
Adhesives are indispensable. They are required pling agents, and other key ingredients. Special in myriad products-aircraft and abrasives, cars attention is given to such flourishing categories and cartons, shoes and safety glass, tape and as acrylics, anaerobics, cyanoacrylates, poly urethanes, epoxy resins, polyvinyl acetate, high tires. This Third Edition of Handbook of Ad hesives, like the 1962 and 1977 editions, seeks temperature adhesives, hot melts, silicones, and to provide the knowledge needed for optimum silanes. selection, preparation, and utilization of adhe The last 14 chapters, on adherends and bond sives and sealants. The information is detailed ing technology, involve the auto industry, air and explicit, with several hundred illustrative craft, electronics, the bonding of wood, formulations. textiles, rubber and plastics, construction, ab Expert information has been supplied in 47 rasives, pressure-sensitives, nonwovens, and chapters written by 70 industry specialists, pro sealants. Mechanical handling of two-compo fessors, and consultants. Five chapters on fun nent systems is examined. The concluding damentals provide the theoretical and economic chapter highlights the exciting progress that is underpinnings-why adhesives work, how they being made in the use of robotics to apply ad are selected, how the surface is prepared, how hesives, techniques already far advanced in au they are applied, how they are set, how the tomotive assembly. cured joint is tested.
This book deals with the organic chemistry of polymers which find technological use as adhesives, fibres, paints, plastics and rubbers. For the most part, only polymers which are of commercial significance are considered and the primary aim of the book is to relate theoretical aspects to industrial practice. The book is mainly intended for use by students in technical institutions and universities who are specializing in polymer science and by graduates who require an introduction to this field. Several excellent books have recently appeared dealing with the physical chemistry of polymers but the organic chemistry of polymers has not received so much attention. In recognition of this situation and because the two aspects of polymer chemistry are often taught separately, this book deals specifically with organic chemistry and topics of physical chemistry have been omitted. Also, in this way the book has been kept to a reasonable size. This is not to say that integration of the two areas of polymer science is undesirable; on the contrary, it is of the utmost importance that the inter-relationship should b~ appreciated. I wish to record my thanks to my colleagues with whom I have had many helpful discussions, particularly Mrs S. L. Radchenko. I also thank Miss E. Friesen for obtaining many books and articles on my behalf and Mr H. Harms for encouragement and assistance. I am also grateful to Mrs M. Stevens who skilfully prepared the manuscript. Department of Chemical and Metallurgical Technology, Ryerson Polytechnical Institute, K. J. S.