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The Thermodynamics of Phase and Reaction Equilibria, Second Edition, provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g., partial molar Gibbs energy, fugacity, and activity), and shows how to apply these concepts to solve practical problems using numerous clear examples. Available computational software has made it possible for students to tackle realistic and challenging problems from industry. The second edition incorporates phase equilibrium problems dealing with nonideal mixtures containing more than two components and chemical reaction equilibrium problems involving multiple reactions. Computations are carried out with the help of Mathcad®. - Clear layout, coherent and logical organization of the content, and presentation suitable for self-study - Provides analytical equations in dimensionless form for the calculation of changes in internal energy, enthalpy, and entropy as well as departure functions and fugacity coefficients - All chapters have been updated primarily through new examples - Includes many well-organized problems (with answers), which are extensions of the examples enabling conceptual understanding for quantitative/real problem solving - Provides Mathcad worksheets and subroutines - Includes a new chapter linking thermodynamics with reaction engineering - A complete Instructor's Solutions Manual is available as a textbook resource
Phase Equilibria in Chemical Engineering is devoted to the thermodynamic basis and practical aspects of the calculation of equilibrium conditions of multiple phases that are pertinent to chemical engineering processes. Efforts have been made throughout the book to provide guidance to adequate theory and practice. The book begins with a long chapter on equations of state, since it is intimately bound up with the development of thermodynamics. Following material on basic thermodynamics and nonidealities in terms of fugacities and activities, individual chapters are devoted to equilibria primarily between pairs of phases. A few topics that do not fit into these categories and for which the state of the art is not yet developed quantitatively have been relegated to a separate chapter. The chapter on chemical equilibria is pertinent since many processes involve simultaneous chemical and phase equilibria. Also included are chapters on the evaluation of enthalpy and entropy changes of nonideal substances and mixtures, and on experimental methods. This book is intended as a reference and self-study as well as a textbook either for full courses in phase equilibria or as a supplement to related courses in the chemical engineering curriculum. Practicing engineers concerned with separation technology and process design also may find the book useful.
Application of compressed gases as solvents has found widespread interest within the scientific community. Its processes have industrial applications. Gas Extraction deals with the possibilities of supercritical gases as solvents for separation processes. The volume combines physico-chemical aspects with chemical engineering methods. The text generalizes as far as possible, and treats examples in detail. Gas Extraction covers, for the first time, the subject in textbook form. Most of the examples provide new results that will be helpful for practicing scientists, engineers, and students who want to make use of the techniques.
This volume will contain about 40 invited papers and over 200 contributed papers covering all aspects of high-pressure research in physics, chemistry, materials science and biology. It will serve as an exhaustive review of recent achievements in these areas and of the topics of major interest. The list of subjects include: 1) Electronic, optical, and transport properties of solids; 2) Phase transitions, structural properties, and lattice dynamics; 3) Crystal growth and material synthesis; 4) Organic synthesis and biological applications; 5) Geophysical sciences; 6) Instrumentation and metrology; 7) Superhard materials; 8) Ceramics and sintering; 9) Food processing; 10) Plasticity and hydroextrusion.Contributors include: N W Ashcroft (USA), V Blank (Russia), E M Cambell (USA), H G Drickamer (USA), W B Holzapfel (Germany), J Karpinski (Switzerland), H K Mao (USA), W J Nellis (USA), W Paul (USA), E G Ponyatovsky (Russia), A L Ruoff (USA), J S Schilling (USA), O Shimomura (Japan), I F Silvera (USA), B Sundquist (Sweden).
Using an applications perspective Thermodynamic Models for Industrial Applications provides a unified framework for the development of various thermodynamic models, ranging from the classical models to some of the most advanced ones. Among these are the Cubic Plus Association Equation of State (CPA EoS) and the Perturbed Chain Statistical Association Fluid Theory (PC-SAFT). These two advanced models are already in widespread use in industry and academia, especially within the oil and gas, chemical and polymer industries. Presenting both classical models such as the Cubic Equations of State and more advanced models such as the CPA, this book provides the critical starting point for choosing the most appropriate calculation method for accurate process simulations. Written by two of the developers of these models, Thermodynamic Models for Industrial Applications emphasizes model selection and model development and includes a useful “which model for which application” guide. It also covers industrial requirements as well as discusses the challenges of thermodynamics in the 21st Century.
Progress in International Research on Thermodynamic and Transport Properties covers the proceedings of the 1962 Second Symposium by the same title, held at Purdue University and the Thermophysical Properties Research Center. This symposium brings together theoretical and experimental research works on the thermodynamic and transport properties of gases, liquids, and solids. This text is organized into nine parts encompassing 68 chapters that cover topics from thixotropy to molecular orbital calculations. The first three parts review papers on theoretical, experimental, and computational studies of the various aspects of thermodynamic properties. These parts discuss the principles of phase equilibria, throttling, volume heat capacity, steam, volumetric behavior, enthalpy, and density. The subsequent part highlights the theoretical evaluations of transport properties, such as viscosity, diffusion, and conductivity, as well as the transport processes. These topics are followed by surveys of the theories in intermolecular forces and their applications. Other parts consider the measurement of thermal conductivity, viscosity, and radiation. The final parts examine the properties of ionized gases and non-Newtonian fluids. This book will prove useful to mechanical and chemical engineers.