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Understanding the origin of spatio-temporal order in open systems far from thermal equilibrium and the selection mechanisms of spatial struc tures and their symmetries is a major theme of present day research into the structures of continuous matter. The development of methods for pro ducing spatially ordered microstructures in solids by non-equilibrium methods opens the door to many technological applications. It is also be lieved that the key to laminar/turbulence transitions in fluids lies in the achievement of spatio-temporal order. Let us also emphasize the fact that the idea of self-organization in it self is at the origin of a reconceptualisation of science. Indeed, the appear ance of order which usually has been associated with equilibrium phase transitions appears to be characteristic of systems far from thermal equi librium. This phenomenon which was considered exceptional at first now the rule in driven systems. The chemical oscillations obtained appears to be in the Belousov-Zhabotinskii reaction were initially considered to be ther modynamically impossible and were rejected by a large number of chemists. Now these oscillations and related phenomena (waves, chaos, etc. ) are the subject of intensive research and new classes of chemical oscil lators have been recently discovered. Even living organisms have long been considered as the result of chance rather than necessity. Such points of view are now abandoned under the overwhelming influence of spatio-tem poral organization phenomena in various domains ranging from physics to biology via chemistry, nonlinear optics, and materials science .
This book deals with the methods and concepts of nonlinear dynamics, pattern formation, bifurcation theory, irreversible thermodynamics, and their application to advanced materials science problems. The focus is on the effect of dynamical instabilities on materials behavior and properties.The book is addressed to physicists, chemists, mathematicians and engineers who wish to work in this domain, or to learn about its latest advances. It is also aimed at bridging gaps between science and technology.
Engineering materials with desirable physical and technological properties requires understanding and predictive capability of materials behavior under varying external conditions, such as temperature and pressure. This immediately brings one face to face with the fundamental difficulty of establishing a connection between materials behavior at a microscopic level, where understanding is to be sought, and macroscopic behavior which needs to be predicted. Bridging the corresponding gap in length scales that separates the ends of this spectrum has been a goal intensely pursued by theoretical physicists, experimentalists, and metallurgists alike. Traditionally, the search for methods to bridge the length scale gap and to gain the needed predictive capability of materials properties has been conducted largely on a trial and error basis, guided by the skill of the metallurgist, large volumes of experimental data, and often ad hoc semi phenomenological models. This situation has persisted almost to this day, and it is only recently that significant changes have begun to take place. These changes have been brought about by a number of developments, some of long standing, others of more recent vintage.
Spatio-temporal patterns appear almost everywhere in nature, and their description and understanding still raise important and basic questions. However, if one looks back 20 or 30 years, definite progress has been made in the modeling of insta bilities, analysis of the dynamics in their vicinity, pattern formation and stability, quantitative experimental and numerical analysis of patterns, and so on. Universal behaviors of complex systems close to instabilities have been determined, leading to the wide interdisciplinarity of a field that is now referred to as nonlinear science or science of complexity, and in which initial concepts of dissipative structures or synergetics are deeply rooted. In pioneering domains related to hydrodynamics or chemical instabilities, the interactions between experimentalists and theoreticians, sometimes on a daily basis, have been a key to progress. Everyone in the field praises the role played by the interactions and permanent feedbacks between ex perimental, numerical, and analytical studies in the achievements obtained during these years. Many aspects of convective patterns in normal fluids, binary mixtures or liquid crystals are now understood and described in this framework. The generic pres ence of defects in extended systems is now well established and has induced new developments in the physics of laser with large Fresnel numbers. Last but not least, almost 40 years after his celebrated paper, Turing structures have finally been ob tained in real-life chemical reactors, triggering anew intense activity in the field of reaction-diffusion systems.
This volume collects the contributions! to the NATO Advanced Study Institute (ASI) held in Aussois (France) by March 25 - April 5, 1991. This NATO ASI was intended to present and illustrate recent advances in computer simulation techniques applied to the study of materials science problems. Introductory lectures have been devoted to classical simulations with special reference to recent technical improvements, in view of their application to complex systems (glasses, molecular systems . . . ). Several other lectures and seminars focused on the methods of elaboration of interatomic potentials and to a critical presentation of quantum simulation techniques. On the other hand, seminars and poster sessions offered the opportunity to discuss the results of a great variety of simulation studies dealing with materials and complex systems. We hope that these proceedings will be of some help for those interested in simulations of material properties. The scientific committee advises have been of crucial importance in determining the conference program. The directors of the ASI express their gratitude to the colleagues who have participated to the committee: Y. Adda, A. Bellemans, G. BIeris, J. Castaing, C. R. A. Catlow, G. Ciccotti, J. Friedel, M. Gillan, J. P. Hansen, M. L. Klein, G. Martin, S. Nose, L. Rull-Fernandez, J. Valleau, J. Villain. The main financial support has been provided by the NATO Scientific Affairs Division and the Commission of European Communities (plan Science).
The contents of this book correspond to Sessions VII and VIII of the International Workshop on Instabilities and Nonequilibrium Structures which took place in Viña del Mar, Chile, in December 1997 and December 1999, respectively. Part I is devoted to self-contained courses. Three courses are related to new developments in Bose-Einstein condensation: the first one by Robert Graham studies the classical dynamics of excitations of Bose condensates in anisotropic traps, the second by Marc Etienne Brachet refers to the bifurcations arising in attractive Bose-Einstein condensates and superfluid helium and the third course by André Verbeure is a pedagogical introduction to the subject with special emphasis on first principles and rigorous results. Part I is completed by two courses given by Michel Moreau: the first one on diffusion limited reactions of particles with fluctuating activity and the second on the phase boundary dynamics in a one dimensional nonequilibrium lattice gas. Part II includes a selection of invited seminars at both Workshops.
This volume contains a selection of the lectures given at the Fifth International Workshop on Instabilities and Nonequilibrium Structures, held in Santiago, Chile, in December 1993. The following general subjects are covered: instabilities and pattern formation, stochastic effects in nonlinear systems, nonequilibrium statistical mechanics and granular matter. Review articles on transitions between spatio-temporal patterns and nonlinear wave equations are also included. Audience: This book should appeal to physicists and mathematicians working in the areas of nonequilibrium systems, dynamical systems, pattern formation and partial differential equations. Chemists and biologists interested in self-organization and statistical mechanics should also be interested, as well as engineers working in fluid mechanics and materials science.
One of the most fascinating and intriguing aspects of natural phenomena is that complex systems may undergo symme try-breaking instabilities leading to pattern formation or coherent temporal behavior over macroscopic space and time scales. Therefore the understanding of why order may appear spontananeously in open systems far from equilibrium and which planforms are selected among a large manifold of possi bilities has become a major theme of research both theore- cally and experimentally. These studies, first related to fundamental questions, appear now to be of technological importance, especially for materials science problems. Effectively during the last years, the whole field of materials science experienced a complete renewal. By using techniques able to operate in strong nonequilibrium conditions and hence to escape from the constraints of equilibrium thermodynamics, totally new mate rials structures have been processed. Such techniques inclu de ion implantation, laser beam surface melting as well as electron beam heating. For example, ion implantation proces sing is able to create surfaces with compositions markedly different from the bulk, leading to materials having new electric, magnetic or chemical properties. In laser annea ling, after the tremendously rapid melting and recrystalliza tion of the sample surfaces, microstructures with superior resistance to friction, corrosion, ••• are frozen into place. Rapid solidification of alloys trigger the formation of quasi-crystalline structures. Ion beam mixing can modify the electrical properties of polymers or improve the adhesion of metallic films to ceramics.
Growth and Fonn is the title of a famous book written by D' Arcy Thomson at the beginning of the century. It relates a large number of problems of shapes of bodies either in the physical world or the biological realm. Keywords in this field are shapes, spirals, growth law, gravity field, surface tension, scaling laws, diffusion and mechanical efficiency. This field is the source of a considerable amount of work, even today, and this conference was a place where some of this work was discussed. Except for a few contributions with biophysical inspiration, the main part of the conference was devoted to physical problems related to growth and fonn and especially to the problem of the motion of interfaces under various nonequilibrium conditions. Even with this restriction, this field is huge, from the more applied area (combustion, metallurgy) to the more fundamental (singularities in the complex plane, solvability conditions). One day, at dinner time, in a restaurant with a good view of the corsica sea, W. Kurz from Lausanne told us about teleferique cables and the kind of material which was necessary to build them. Considering the important abyss between this kind of concept and for instance, the huge fonnalism involving Green functions used to find operating points for dendritic growth, we immediatelty had the giggles for five minutes. This large domain was the occasion to confront many scientists from different areas (physicists, applied mathematicians, specialists of combustion, metallurgists and geologists).
This book presents the state of the art in applied and industrial mathematics, updating the earlier Kluwer publication Applied and Industrial Mathematics, Venice-1, 1989. The current work includes a selection of main invited papers as well as conference contributions from a number of leading scientists working in the areas of applied mathematics, industrial mathematics applied analysis, numerical mathematics, mathematical physics and applied probability. Audience: This volume will be of interest to researchers and advanced graduate students whose work involves mathematical modelling and industrial mathematics, numerics and computation, mathematics of science, mathematical physics, mathematical analysis in general and partial differential equations in particular.