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Particle Deposition and Aggregation: Measurement, Modelling and Simulation describes how particle deposition and aggregation can be measured, modeled, and simulated in a systematic manner. It brings together the necessary disciplines of colloid and surface chemistry, hydrodynamics, experimental methods, and computational methods to present a unified approach to this problem. The book is divided into four parts. Part I presents the theoretical principles governing deposition and aggregation phenomena, including a discussion of the forces that exist between particles and the hydrodynamic factors that control the movement of the particles and suspending fluid. Part II introduces methods for modeling the processes, first at a simple level (e.g. single particle-surface, single particle-single particle interactions in model flow conditions) and then describes the simulation protocols and computation tools which may be employed to describe more complex (multiple-particle interaction) systems. Part III summarizes the experimental methods of quantifying aggregating and depositing systems and concludes with a comparison of experimental results with those predicted using simple theoretical predictions. Part IV is largely based on illustrative examples to demonstrate the application of simulation and modeling methods to particle filtration, aggregation, and transport processes. This book should be useful to graduates working in process and environmental engineering research or industrial development at a postgraduate level, and to scientists who wish to extend their knowledge into more realistic process conditions in which the fluid hydrodynamics and other complicating factors must be accommodated.
Kinetics of Aggregation and Gelation
This book covers the rich phenomenology exhibited by fine powders when they are fluidized by a gas flow. Fine powder cohesiveness leads to poor flowability, clumping, difficulty in fluidizing, irregular avalanching behavior, etc. Despite all the inconveniences, fine powder processes pervade the chemical, pharmaceutical, agricultural and mining industries among others. The author in this book analyzes the mechanism by which interparticle adhesive forces are reduced by means of surface additives. Different techniques have been developed in the last years to assist fluidization by helping the gas flow to mobilize and break cohesive aggregates, which help to homogenize fluidization. As reviewed in this book, the use of these techniques may have a relevant impact on novel processes based on fluidized beds of fine powder and with relevant applications on leading edge technologies such as Atomic Layer Deposition on nanoparticles and CO2 capture by gas-fluidized beds of adsorbent powders. The study of fluidized beds has a marked interdisciplinary character. This book is thus intended for academic and industrial researchers in applied physics, mechanical, chemical, and environmental engineering, who are interested in the special characteristics of fine powders.
Nanomaterials - structures with characteristic dimensions between 1 and 100 nm -exhibit a variety of unique and tunable chemical and physical properties that have made engineered nanoparticles central components in an array of emerging technologies. The use of nanotechnology is increasing; however its potential adverse effects on human health are n
Transport Processes in Chemically Reacting Flow Systems discusses the role, in chemically reacting flow systems, of transport processes—particularly the transport of momentum, energy, and (chemical species) mass in fluids (gases and liquids). The principles developed and often illustrated here for combustion systems are important not only for the rational design and development of engineering equipment (e.g., chemical reactors, heat exchangers, mass exchangers) but also for scientific research involving coupled transport processes and chemical reaction in flow systems. The book begins with an introduction to transport processes in chemically reactive systems. Separate chapters cover momentum, energy, and mass transport. These chapters develop, state, and exploit useful quantitative ""analogies"" between these transport phenomena, including interrelationships that remain valid even in the presence of homogeneous or heterogeneous chemical reactions. A separate chapter covers the use of transport theory in the systematization and generalization of experimental data on chemically reacting systems. The principles and methods discussed are then applied to the preliminary design of a heat exchanger for extracting power from the products of combustion in a stationary (fossil-fuel-fired) power plant. The book has been written in such a way as to be accessible to students and practicing scientists whose background has until now been confined to physical chemistry, classical physics, and/or applied mathematics.
Specific ion effects are important in numerous fields of science and technology. This book summarizes the main ideas that came up over the years. It presents the efforts of theoreticians and supports it by the experimental results stemming from various techniques.
Bridging the gap between theory and practice, this text provides the reader with a comprehensive overview of industrial crystallization. Newcomers will learn all of the most important topics in industrial crystallization, from key concepts and basic theory to industrial practices. Topics covered include the characterization of a crystalline product and the basic process design for crystallization, as well as batch crystallization, measurement techniques, and details on precipitation, melt crystallization and polymorphism. Each chapter begins with an introduction explaining the importance of the topic, and is supported by homework problems and worked examples. Real world case studies are also provided, as well as new industry-relevant information, making this is an ideal resource for industry practitioners, students, and researchers in the fields of industrial crystallization, separation processes, particle synthesis, and particle technology.
Kinetics of Aggregation and Gelation presents the proceedings of the International Topical Conference on Kinetics of Aggregation and Gelation held on April 2-4, 1984 in Athens, Georgia. The purpose of the conference was to bring together international experts from a wide variety of backgrounds who are studying phenomena inherently similar to the formation of large clusters by the union of many separate, small elements, to present and exchange ideas on new theories and results of experimental and computer simulations. This book is divided into 57 chapters, each of which represents an oral presentation that is part of a unified whole. The book begins with a presentation on fractal concepts in aggregation and gelation, followed by presentations on topics such as aggregative fractals called ""squigs""; multi-particle fractal aggregation; theory of fractal growth processes; self-similar structures; and interface dynamics. Other chapters cover addition polymerization and related models; the kinetic gelation model; a new model of linear polymers; red cell aggregation kinetics; the Potts Model; aggregation of colloidal silica; the ballistic model of aggregation; stochastic dynamics simulation of particle aggregation; particle-cluster aggregation; kinetic clustering of clusters; computer simulations of domain growth; and perspectives in the kinetics of aggregation and gelation. This book will be of interest to practitioners in the fields of chemistry, theoretical physics, and materials engineering.
This book lays out a vision for a coherent framework for understanding complex systems. By developing the genuine idea of Brownian agents, the author combines concepts from informatics, such as multiagent systems, with approaches of statistical many-particle physics. It demonstrates that Brownian agent models can be successfully applied in many different contexts, ranging from physicochemical pattern formation to swarming in biological systems.
The rapidly developing field of nanomaterials has expanded in many commercial areas. More recent studies have begun to provide a foundation for understanding how nanomaterials influence cells and how they also can serve as methodological tools for studies in medicine and cell biology, including research into stem cells. Recent investigations have shown affects of nanomaterials on specific subcellular structures, such as the actin-based brush border network in cells with an increasing emphasis on the barrier function of epithelial tissues. While other studies have shown involvement of nanoparticles in specific cytoplasmic signal transduction events such as the rise in intracellular free calcium, a signaling event known to regulate many changes in cell architecture and function. In parallel, nanomaterials are increasingly used in medicine for drug delivery, treatment of cancer and an increasing number of new applications. This book investigates these areas and also includes new methods for assessment in cell biology and medicine.