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The papers in this book represent the proceedings for the International Conference on Oxygen Disorder Effects in High~Tc Superconductors, held April 18-21, 1989 at the International Centre for Theoretical Physics, Trieste, Italy. It was recognized very early in the field of ceramic superconductors that oxygen plays a crucial role as far as the physical properties of these ma terials are concerned. The preparation requires special heating and cooling cycles which allow proper uptake of oxygen, relationships were found between the oxygen concentration and the superconducting transition temperature in many of the compounds and quite recently it was recognized that many (if not all) of the compounds present oxygen ordering in the intercalating planes. Moreover, it seems that the presence of superconductivity is strongly correlated with the presence of orthorhombic phases although several groups have also claimed the presence of superconductivity in tetragonal phases. Whether oxygen ordering plays or not a crucial role for the superconductivity remains to be seen. However it is clear that the ordering of oxygens and their thermodynamic properties is an interesting subject on its own right. All these reasons led us to organize a Conference on Oxygen Disorder Effects in High-Tc Superconductors in attempt to identify unsolved problems and to have an open discussion of the presently known facts.
The focus of the workshop is the role of crystal lattices, i.e. atomic structure, phonons, lattice distortions, in the mechanism of high temperature superconductivity in oxides. In spite of the intense research effort during the last five years the mechanism of high temperature superconductivity still remains unknown. While earlier theories forcused primarily on the role of magnetic interaction, recent experimental results strongly suggest that anharmonic local atomic displacements, in particular those induced by charge carriers, are critically involved in creating high temperature superconductivity. In this workshop, experimentalists and theoreticians address this issue with the hope of stimulating real progress in this area.
The dynamic developments in high-temperature superconductivity over the last three years has augmented the importance of materials research not only for applications, but also for the understanding of underlying physical phenomena. The discovery of new superconductors has opened up new facets of High Tc research, and the perfection of already known materials has enabled reliable physical measurements to be carried out, providing a foundation for theoretical models. The papers in this volume present an overview of the recent developments in the field of High Tc-materials research. One of the highlights of this meeting was the plenary lecture by the Nobel laureate K. Alex Müller on the importance of the apical oxygen phenomena which are strongly connected with Tc changes.
The International Winter School on Electronic Properties of High-Temperature Superconductors, held between March 7-14, 1992, in Kirchberg, (Tyrol) Austria, was the sixth in a series of meetings to be held at this venue. Four of the earlier meetings were dedicated to issues in the field of conducting polymers, while the winter school held in 1990 was devoted to the new discipline of high-T c superconductivity. This year's meeting constituted a forum not only for the large number of scientists engaged in high-Tc research, but also for those involved in the new and exciting field of fullerenes. Many of the issues raised during the earlier winter schools on conducting polymers, and the last one on high-T c superconductivity, have taken on a new significance in the light of the discovery of superconducting C materials. 60 The Kirchberg meetings are organized in the style of a school where expe rienced scientists from universities, research laboratories and industry have the opportunity to discuss their most recent results, and where students and young scientists can learn about the present status of research and applications from some of the most eminent workers in their field. In common with the previous winter school on high-Tc superconductors, the of the cuprate superconductors. present one focused on the electronic properties In addition, consideration was given to related compounds which are relevant to the understanding of the electronic structure of the cuprates in the normal state, to other oxide superconductors and to fulleride superconductors.
A wide range of progress in materials development [single crystals, ceramics, thin films, wire and tapes] is reported in the 169 papers in this volume. The main focus of the papers is in attaining a better understanding of the relationship between microstructure and electrical properties. Invited papers cover topics such as the effects of substitution and doping; multilayers; nanostructure characterisation; electric field effects in High Tc Superconductors [HTS]; surface stability; critical currents; flux pinning and magnetooptic imaging of flux patterns; effects of irradiation induced defects; properties and preparation of materials; microwave properties and electronic devices. A clearly broadened basis for understanding processes and mechanisms in [HTS] is portrayed. Appreciable progress has been achieved in the reproducible manufacturing of high quality materials supported by very efficient methods in microstructural analysis. This essential improvement is reflected in the increased number of practical devices encouraging the use of HTS in applications for electronics and power engineering, all of which are reviewed in depth in this work.
Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.
Semiannual, with semiannual and annual indexes. References to all scientific and technical literature coming from DOE, its laboratories, energy centers, and contractors. Includes all works deriving from DOE, other related government-sponsored information, and foreign nonnuclear information. Arranged under 39 categories, e.g., Biomedical sciences, basic studies; Biomedical sciences, applied studies; Health and safety; and Fusion energy. Entry gives bibliographical information and abstract. Corporate, author, subject, report number indexes.
The recent discovery of high-temperature superconductivity in copper based oxides is an event of major importance not only with respect to the physical phenomenon itself but also because it definitely shows that solid state chemistry, and especially the crystal chemistry of oxides, has a crucial place in the synthesis and understanding of new materials for future appli cations. The numerous papers published in the field of high Tc supercon ductors in the last five years demonstrate that the great complexity of these materials necessitates a close collaboration between physicists and solid state chemists. This book is based to a large extent on our experience of the crystal chemistry of copper oxides, which we have been studying in the laboratory for more than twelve years, but it also summarizes the main results which have been obtained for these compounds in the last five years relating to their spectacular superconducting properties. We have focused on the struc ture, chemical bonding and nonstoichiometry of these materials, bearing in mind that redox reactions are the key to the optimization of their supercon ducting properties, owing to the importance of the mixed valence of copper and its Jahn-Teller effect. We have also drawn on studies of extended defects by high-resolution electron microscopy and on their creation by ir radiation effects.
Six papers by physicists from the Japan, India, Brazil and the US address some of the broad frontal issues of superconductivity, which include the mechanisms of high-temperature superconductivity, extra-high-temperature phenomena, the normal state pseudogap, the observations of the isotope effect in a host of different superconducting systems and their explanations, and the unusual features of strongly correlated electron systems like heavy fermions. Two extended papers explore the importance of positron annihilation and using electron spin resonance techniques to study superconducting materials. The treatments should be accessible to working scientists and engineers and to graduate students of physics, chemistry, materials science, solid-state electronics, and other disciplines.
In contrast to research on the fundamental mechanisms of High-Temperature Superconductivity, in recent years we have seen enormous developments in the fabrication and application of High-Tc-superconductors. The two volumes of High Temperature Superconductivity provide a survey of the state of the technology and engineering applications of these materials. They comprise extended original research papers and technical review articles written by physicists, chemists, materials scientists and engineers, all of them noted experts in their fields. The interdisciplinary and strictly application-oriented coverage should benefit graduate students and academic researchers in the mentioned areas as well as industrial experts. Volume 1 "Materials" focuses on major technical advancements in High-Tc materials processing for applications. Volume 2 "Engineering Applications" covers numerous application areas where High-Tc superconductors are making tremendous impact.